Swellable metal material with silica
US-11885195-B2 · Jan 30, 2024 · US
US9758433B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9758433-B2 |
| Application number | US-201213546830-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 11, 2012 |
| Priority date | Jul 11, 2012 |
| Publication date | Sep 12, 2017 |
| Grant date | Sep 12, 2017 |
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A grout used in horizontal directional drilling including a silica material present in an amount of from about 50% to about 70%, bentonite present in an amount of from about 20% to about 30%, a carbon source present in an amount of from about 5% to about 15%, an inorganic alkaline material present in an amount of from about 0% to about 3%, a fluid loss additive present in an amount of from about 0% to about 1%, a polymeric dispersant present in an amount of from about 0% to about 1%, and a polymeric flow enhancer present in an amount of from about 0% to about 0.5%, all by weight of the grout composition. Methods utilizing the grout include placing conduit in a hole, forming the grout slurry, and placing the grout slurry adjacent to the conduct.
Opening claim text (preview).
What is claimed is: 1. A method of installing a conduit in a hole in the earth, comprising the steps of: (a) placing the conduit in at least one hole in the earth, wherein the hole is horizontal, sub-horizontal, or directional drilled; (b) mixing a grout composition with water to form a grout slurry having a thermal conductivity greater than about 0.4 Btu/hr-ft-° F., wherein the grout composition comprises a silica material present in an amount of from about 50% to about 70%, bentonite present in an amount of from about 20% to about 30%, a carbon source present in an amount of from about 5% to about 15%, an inorganic alkaline material, wherein the inorganic alkaline material is present in an amount up to about 3%, a polymeric dispersant, wherein the polymeric dispersant is present in an amount of from about 0% to about 1%, and a polymeric flow enhancer, wherein the polymeric flow enhancer is present in an amount up to about 1%, all by weight of the grout composition, wherein the silica material is at least one of silica flour, condensed silica fume, rice hull ash, and combinations thereof, wherein the grout slurry has a viscosity of less than about 300 cp at a grout composition present in the grout slurry of less than or equal to about 55% by weight of the grout slurry; and (c) placing the grout slurry in the hole adjacent to the conduit. 2. The method of claim 1 , wherein the grout composition is a one-sack product. 3. The method of claim 1 , wherein the conduit comprises a heat transfer loop for transferring heat between the earth and a heat transfer fluid flowing through the loop. 4. The method of claim 1 , wherein the grout slurry is placed into the hole using a pump. 5. The method of claim 1 , wherein the pump is a centrifugal pump. 6. The method of claim 1 , wherein the pump is a piston pump. 7. The method of claim 1 , wherein the grout composition further comprises up to about 0.5% of a fluid loss additive by weight of the grout composition. 8. The method of claim 1 , wherein the fluid loss additive comprises polyanionic cellulose. 9. The method of claim 1 , wherein the silica material comprises silica flour. 10. The method of claim 1 , wherein the carbon source comprises flaked graphite. 11. The method of claim 1 , wherein an amount of the grout composition present in the grout slurry is in a range of from about 35% to about 55% by weight of the grout slurry. 12. The method of claim 1 , wherein the grout slurry has a thermal conductivity greater than about 1.0 Btu/hr-ft-° F. 13. The method of claim 1 , wherein the grout slurry has a thermal conductivity greater than about 1.2 Btu/hr-ft-° F. 14. The method of claim 1 , wherein the grout slurry has a thermal conductivity greater than about 1.4 Btu/hr-ft-° F. 15. The method of claim 1 , wherein the polymeric dispersant is present and comprises 2-acrylamido-2-acrylamido-2-methylpropanesulfonic acid (AMPS). 16. The method of claim 1 , wherein the polymeric flow enhancer comprises partially hydrated polyacrylamides (PHPA). 17. The method of claim 1 , wherein the grout composition comprises a silica material present in an amount of from about 50% to about 70%, bentonite present in an amount of from about 20% to about 30%, a carbon source present in an amount of from about 5% to about 15%, an inorganic alkaline material present in an amount of up to about 3%, a fluid loss additive present in an amount of from about 0% to about 1%, a polymeric dispersant present in an amount of from about 0% to about 1%, and a polymeric flow enhancer present in an amount of up to about 0.3% all by weight of the grout composition. 18. The method of claim 1 , wherein the grout slurry has a viscosity of less than about 225 cp at a grout composition present in the grout slurry of less than or equal to about 48% solids by weight of the grout slurry. 19. The method of claim 1 , wherein the grout composition comprises a silica material present in an amount of about 65%, bentonite present in an amount of about 24%, a carbon source present in an amount of about 10%, sodium carbonate present in an amount of about 0.75%, a fluid loss additive present in an amount of about 0.1%, a polymeric dispersant present in an amount of about 0.1%, and a polymeric flow enhancer present in an amount of about 0.1%, all by weight of the grout composition.
Carbon · CPC title
containing carbon in the anion, e.g. carbonates · CPC title
Dispersants · CPC title
Nitrogen containing polymers, e.g. polyacrylamides, polyacrylonitriles · CPC title
Quartz; Sand · CPC title
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