Conductive polymer composite and substrate

Patent metadata

Field	Value
Publication number	US-9752045-B2
Application number	US-201615225221-A
Country	US
Kind code	B2
Filing date	Aug 1, 2016
Priority date	Aug 25, 2015
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The present invention provides a conductive polymer composite including: (A) a π-conjugated polymer, and (B) a dopant polymer which contains a repeating unit “a” shown by the following general formula (1) and having a weight-average molecular weight in the range of 1,000 to 500,000. There can be provided a conductive polymer composite which has excellent filterability and film-formability by spin coating, and can form a conductive film having high transparency and excellent flatness.

wherein R 1 represents a hydrogen atom or a methyl group; R 2 represents any of a single bond, an ester group, and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms, the hydrocarbon group optionally containing an ether group, an ester group, or both; “Z” represents any of a single bond, a phenylene group, a naphthylene group, an ether group, and an ester group; and “a” is a number satisfying 0<a≦1.0.

First claim

What is claimed is:

1. A conductive polymer composite comprising:
(A) a π-conjugated polymer, and
(B) a dopant polymer which contains a repeating unit shown by the following general formula (1) and having a weight-average molecular weight in the range of 1,000 to 500,000,

wherein R 1 represents a hydrogen atom or a methyl group; R 2 represents any of a single bond, an ester group, and a linear, branched, or cyclic hydrocarbon group having 1 to 12 carbon atoms, the hydrocarbon group optionally containing either or both of an ether group and an ester group; “Z” represents any of a single bond, a phenylene group, a naphthylene group, an ether group, and an ester group; and “a” is a number satisfying 0<a≦1.0.

2. The conductive polymer composite according to claim 1 , wherein the repeating unit shown by the general formula (1) in the component (B) includes one or more kinds selected from repeating units respectively shown by the following general formulae (1-1) to (1-4),

wherein R 1 has the same meaning as defined above; and a1, a2, a3, and a4 are each a number satisfying 0≦a1≦1.0, 0≦a2≦1.0, 0≦a3≦1.0, 0≦a4≦1.0, and 0<a1+a2+a3+a4≦1.0.

3. The conductive polymer composite according to claim 2 , wherein the component (B) further contains a repeating unit shown by the following general formula (2),

wherein “b” is a number satisfying 0<b<1.0.

4. The conductive polymer composite according to claim 3 , wherein the component (B) is a block copolymer.

5. The conductive polymer composite according to claim 2 , wherein the component (B) is a block copolymer.

6. The conductive polymer composite according to claim 2 , wherein the component (A) is a polymer formed by polymerization of one or more precursor monomers selected from the group consisting of pyrrole, thiophene, selenophene, tellurophene, aniline, a polycyclic aromatic compound, and a derivative thereof.

7. The conductive polymer composite according to claim 2 , wherein the conductive polymer composite has dispersibility in water or in an organic solvent.

8. A substrate having a conductive film formed thereon, wherein the conductive film is formed from the conductive polymer composite according to claim 2 .

9. The conductive polymer composite according to claim 1 , wherein the component (B) further contains a repeating unit shown by the following general formula (2),

wherein “b” is a number satisfying 0<b<1.0.

10. The conductive polymer composite according to claim 9 , wherein the component (B) is a block copolymer.

11. The conductive polymer composite according to claim 9 , wherein the component (A) is a polymer formed by polymerization of one or more precursor monomers selected from the group consisting of pyrrole, thiophene, selenophene, tellurophene, aniline, a polycyclic aromatic compound, and a derivative thereof.

12. The conductive polymer composite according to claim 9 , wherein the conductive polymer composite has dispersibility in water or in an organic solvent.

13. A substrate having a conductive film formed thereon, wherein the conductive film is formed from the conductive polymer composite according to claim 9 .

14. The conductive polymer composite according to claim 1 , wherein the component (B) is a block copolymer.

15. The conductive polymer composite according to claim 14 , wherein the component (A) is a polymer formed by polymerization of one or more precursor monomers selected from the group consisting of pyrrole, thiophene, selenophene, tellurophene, aniline, a polycyclic aromatic compound, and a derivative thereof.

16. The conductive polymer composite according to claim 14 , wherein the conductive polymer composite has dispersibility in water or in an organic solvent.

17. The conductive polymer composite according to claim 1 , wherein the component (A) is a polymer formed by polymerization of one or more precursor monomers selected from the group consisting of pyrrole, thiophene, selenophene, tellurophene, aniline, a polycyclic aromatic compound, and a derivative thereof.

18. The conductive polymer composite according to claim 1 , wherein the conductive polymer composite has dispersibility in water or in an organic solvent.

19. A substrate having a conductive film formed thereon, wherein the conductive film is formed from the conductive polymer composite according to claim 1 .

20. The substrate according to claim 19 , wherein the conductive film functions as a transparent electrode layer.

Assignees

• Shinetsu Chemical Co

Inventors

• Hatakeyama Jun
• Nagasawa Takayuki
• Hasegawa Koji

Classifications

• C08F212/20

  Fluorine · CPC title

• C08F212/24

  Phenols or alcohols · CPC title

• C08F212/30

  Sulfur · CPC title

• C08F212/22

  Oxygen · CPC title

• C09D7/65

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title