Operation method for dezincification plant

Patent metadata

Field	Value
Publication number	US-9751035-B2
Application number	US-201314760066-A
Country	US
Kind code	B2
Filing date	Dec 10, 2013
Priority date	Jan 10, 2013
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

At the beginning of a dezincification plant used in a dezincification step in a hydrometallurgical method for nickel, a decrease throughout the dezincification plant is controlled to prevent a decrease in production volume and a cake layer is formed on a filter cloth provided to a filter device inside the dezincification plant. At the beginning of dezincification plant, a slurry containing a formed zinc sulfide is supplied to a filter for filtration and separation, an adjustment is performed in which the flow rate of the slurry is increased to reach a target flow rate in a time T 2 which satisfies the following relational expression 3×T 1 ≦T 2 ≦5×T 1 , where T 1 represents the time between starting a slurry supply and attaining the target flow rate in the case of transferring the slurry at the maximum liquid transfer capacity of a pump configured to transfer the slurry.

First claim

The invention claimed is:

1. An operation method for a dezincification plant, the method comprising:
leaching a nickel oxide ore containing zinc, nickel and cobalt;
neutralizing of the leachate of the nickel oxide ore containing zinc, nickel and cobalt to obtain a post-neutralization solution;
applying a sulfurization treatment to the post-neutralization solution to form a zinc, sulfide; and
separating and removing the zinc sulfide,
wherein, when, upon start-up of the dezincification plant, a slurry containing the zinc sulfide formed by adding a sulfurizing agent to the post-neutralization solution is supplied to a filter for filtration and separation, an adjustment is performed in such a manner that a flow rate of the slurry supplied to the filter is increased in stages to reach a target slurry flow rate in a time T 2 , which satisfies the following relational expression (i),
3× T 1≦ T 2≦5× T 1  (i)

where T 1 represents a minimum time between starting a slurry supply and attaining the target slurry flow rate in the case of transferring the slurry at a maximum liquid transfer capacity of a pump configured to transfer the slurry.

2. The operation method for the dezincification plant according to claim 1 , wherein each of the stages has a step of increasing a slurry flow rate and a step of maintaining a slurry flow rate.

3. The operation method for the dezincification plant according to claim 2 , wherein, in the step of increasing the slurry flow rate in each of the stages, said slurry flow rate is increased by transferring the slurry at the maximum liquid transfer capacity of the pump.

4. The operation method for the dezincification plant according to claim 1 , wherein the slurry flow rate is adjusted so as to be increased in three stages to six stages.

5. An operation method for a dezincification plant, the method including a hydrometallurgical method for a nickel oxide ore comprising:
a leaching step wherein sulfuric acid is added to a slurry of the nickel oxide ore to perform leaching under high temperature and high pressure;
a solid-liquid separation step wherein multistage washing is applied to the slurry to separate a residue therefrom, whereby a leachate containing an impurity element together with nickel and cobalt is obtained;
a neutralization step wherein a pH of the leachate is adjusted to separate a neutralized precipitate containing the impurity element therefrom, whereby a post-neutralization solution containing zinc together with nickel and cobalt is obtained;
a dezincification step wherein a sulfurization treatment is applied to the post-neutralization solution to form a zinc sulfide, and said zinc sulfide is separated therefrom to obtain a mother liquor for nickel recovery which contains nickel and cobalt; and
a nickel recovery step wherein a sulfurization treatment is applied to the mother liquor for nickel recovery to form a mixed sulfide containing nickel and cobalt,
wherein, when, upon start-up of the dezincification plant, a slurry containing the zinc sulfide formed by adding a sulfurizing agent to the post-neutralization solution is supplied to a filter for filtration and separation,
an adjustment is performed in such a manner that a flow rate of the slurry supplied to the filter is increased in stages to reach a target slurry flow rate in a time T 2 , which satisfies the following relational expression (i),
3× T 1≦ T 2≦5× T 1  (i)

where T 1 represents a minimum time between starting a slurry supply and attaining the target slurry flow rate in the case of transferring the slurry at a maximum liquid transfer capacity of a pump configured to transfer the slurry.

Assignees

• Sumitomo Metal Mining Co
• Sumitomo Wiring Systems

Inventors

• Mitsui Hiroyuki
• Matsubara Satoshi
• Nakai Osamu

Classifications

• B01D37/04 Primary

  Controlling the filtration · CPC title

• C22B23/0461 Primary

  by chemical methods · CPC title

• C22B23/043

  Sulfurated acids or salts thereof · CPC title

• C22B1/00

  Preliminary treatment of ores or scrap · CPC title

• C01G9/08

  Sulfides · CPC title