Electroconductive material superior in resistance to fretting corrosion for connection component

Patent metadata

Field	Value
Publication number	US-9748683-B2
Application number	US-201414210749-A
Country	US
Kind code	B2
Filing date	Mar 14, 2014
Priority date	Mar 29, 2013
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

An electroconductive material includes a Cu or Cu alloy base member, a Cu—Sn alloy coating layer, and a Sn coating layer. The Cu—Sn alloy coating layer has a Cu content of 20 to 70 atomic %, and an average thickness of 0.2 to 3.0 μm. The Sn coating layer has an average thickness of 0.2 to 5.0 μm. A surface of the electroconductive material has an arithmetic average roughness Ra of at least 0.15 μm in at least one direction along the surface and 3.0 μm or less in all directions along the surface. The Cu—Sn alloy coating layer is partially exposed at the surface of the electroconductive material. An area ratio of the Cu—Sn alloy coating layer exposed at the surface of the electroconductive material is 3 to 75%. An average crystal grain size on a surface of the Cu—Sn alloy coating layer is less than 2 μm.

First claim

The invention claimed is:

1. An electroconductive material, comprising:
a base member comprising a sheet or strip of copper or copper alloy;
a Cu—Sn alloy coating layer; and
a Sn coating layer;
wherein:
at least a portion of the Cu—Sn alloy coating layer is between the base member and the Sn coating layer;
the Cu—Sn alloy coating layer has a Cu content of 20 to 70 atomic %:
the Cu—Sn alloy coating layer has an average thickness of 0.2 to 3.0 μm;
the Sn coating layer has an average thickness of 0.2 to 5.0 μm;
a surface of the electroconductive material has an arithmetic average roughness Ra of at least 0.15 μm in at least one direction along the surface;
the surface of the electroconductive material has an arithmetic average roughness Ra of 3.0 μm or less in all directions along the surface;
the Cu—Sn alloy coating layer is partially exposed at the surface of the electroconductive material;
an area ratio of the Cu—Sn alloy coating layer exposed at the surface of the electroconductive material is 3 to 75%; and
an average crystal grain size on a surface of the Cu—Sn alloy coating layer is more than 0.51 μm and less than 1 μm.

2. The electroconductive material of claim 1 , further comprising a Cu coating layer between the base member and the Cu—Sn alloy coating layer.

3. The electroconductive material of claim 1 , further comprising a Ni coating layer between the base member and the Cu—Sn alloy coating layer.

4. The electroconductive material of claim 3 , further comprising a Cu coating layer between the Ni coating layer and the Cu—Sn alloy coating layer.

5. The electroconductive material of claim 1 , wherein a surface of the base member comprises asperities distributed at an average interval of 0.01 to 0.5 mm in at least one direction along the surface.

6. The electroconductive material of claim 5 , further comprising a Cu coating layer between the base member and the Cu—Sn alloy coating layer.

7. The electroconductive material of claim 5 , further comprising a Ni coating layer between the base member and the Cu—Sn alloy coating layer.

8. The electroconductive material of claim 7 , further comprising a Cu coating layer between the Ni coating layer and the Cu—Sn alloy coating layer.

9. The electroconductive material of claim 1 , wherein a thickness of the regions of the Cu—Sn alloy coating layer exposed at the surface of the electroconductive material is at least 0.2 μm.

10. The electroconductive material of claim 9 , further comprising a Cu coating layer between the base member and the Cu—Sn alloy coating layer.

11. The electroconductive material of claim 9 , further comprising a Ni coating layer between the base member and the Cu—Sn alloy coating layer.

12. The electroconductive material of claim 11 , further comprising a Cu coating layer between the Ni coating layer and the Cu—Sn alloy coating layer.

13. The electroconductive material of claim 1 , wherein:
the electroconductive material is manufactured by a method comprising subjecting a workpiece to a reflow treatment;
the workpiece is heated at a rate of at least 15° C. per second during the reflow treatment; and
the workpiece is held at a temperature of 400 to 650° C. for a period of 5 to 30 seconds during the reflow treatment.

14. A connection component, comprising:
a male terminal; and
a female terminal;
wherein at least one of the male terminal and the female terminal comprises the electroconductive material of claim 1 .

15. A method of manufacturing the electroconductive material of claim 1 , comprising:
preparing a workpiece by:
roughening a surface of a base member comprising a sheet or strip of copper or copper alloy;
applying a Cu layer to the base member; and
applying a Sn layer to the Cu layer; and

subjecting the workpiece to a reflow treatment;
wherein:
the workpiece is heated at a rate of at least 15° C. per second during the reflow treatment; and
the workpiece is held at a temperature of 400 to 650° C. for a period of 5 to 30 seconds during the reflow treatment.

16. The method of claim 15 , wherein:
the base member is roughened so that a surface of the base member has an arithmetic average roughness Ra to 0.3 μm or more in one or more directions; and
the base member is roughened so that a surface of the base member has an arithmetic average roughness Ra to 4.0 μm or less in all directions.

17. The method of claim 15 , wherein:
the Cu layer is formed by plating; and
the Cu layer is formed to have an average thickness of 0.1 to 1.5 μm.

18. The method of claim 15 , wherein:
the Sn layer is formed by plating; and
the Sn layer is formed to have an average thickness of 0.4 to 8.0 μm.

19. The method of claim 15 , further comprising applying a Ni layer to the base member before applying the Cu layer.

20. The method of claim 19 , wherein:
the Ni layer is formed by plating; and
the Ni layer is formed to have an average thickness of 3 μm or less.

21. The method of claim 15 , wherein the workpiece is heated at a rate of at least 20° C. per second during the reflow treatment.

22. The method of claim 15 , wherein the workpiece is held at a temperature of 450 to 600° C. for a period of 5 to 30 seconds during the reflow treatment.

Assignees

• Kobe Steel Ltd

Inventors

• Tsuru Masahiro

Classifications

• C25D5/34

  Pretreatment of metallic surfaces to be electroplated · CPC title

• C23C30/00

  Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process (C23C26/00, C23C28/00 take precedence) · CPC title

• C25D5/50

  by heat-treatment · CPC title

• C25D5/10

  Electroplating with more than one layer of the same or of different metals (for bearings C25D7/10) · CPC title

• H01R13/03 Primary

  characterised by the material, e.g. plating, or coating materials · CPC title