Hexagonal ferrite powder and magnetic recording medium

Patent metadata

Field	Value
Publication number	US-9741382-B2
Application number	US-201514673282-A
Country	US
Kind code	B2
Filing date	Mar 30, 2015
Priority date	Mar 31, 2014
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

An aspect of the present invention relates to hexagonal ferrite powder, which comprises equal to or more than 70% on a particle number basis of isotropic hexagonal ferrite particles satisfying equation (1):

major axis length/minor axis length<2.0  (1),

having an average particle size of equal to or greater than 10.0 nm but equal to or less than 35.0 nm, and having a saturation magnetization of equal to or greater than 30 A·m 2 /kg.

First claim

What is claimed is:

1. Hexagonal ferrite powder, which comprises equal to or more than 81% but equal to or less than 93% on a particle number basis of isotropic hexagonal ferrite particles satisfying equation (1), the balance being either isotropic hexagonal ferrite particles which do not satisfy equation (1) or anisotropic hexagonal ferrite particles:
major axis length/minor axis length<2.0  (1),

having an average particle size of equal to or greater than 10.0 nm but equal to or less than 35.0 nm, and having a saturation magnetization of equal to or greater than 30 A·m 2 /kg.

2. The hexagonal ferrite powder according to claim 1 , which has a coercive force of equal to or greater than 159 kA/m but equal to or less than 318 kA/m.

3. The hexagonal ferrite powder according to claim 1 , which has thermal stability satisfying equation (A):
60≦ KuV/kT   (A)

wherein, in equation (A), Ku denotes an anisotropy constant, V denotes an activation volume, k denotes Boltzmann constant, and T denotes absolute temperature.

4. The hexagonal ferrite powder according to claim 1 , which has a switching field distribution of equal to or less than 0.8.

5. The hexagonal ferrite powder according to claim 1 , which has an average particle size of equal to or greater than 20.0 nm but equal to or less than 30.0 nm.

6. The hexagonal ferrite powder according to claim 1 , wherein the average particle size of the isotropic particles satisfying equation (1) is equal to or greater than 10.0 nm but equal to or less than 30.0 nm.

7. The hexagonal ferrite powder according to claim 1 , wherein the average particle size of the isotropic particles satisfying equation (1) is equal to or greater than 15.0 nm but equal to or less than 25.0 nm.

8. The hexagonal ferrite powder according to claim 1 , wherein the coefficient of variation in the average particle size of the isotropic particles satisfying equation (1) is equal to or less than 30%.

9. The hexagonal ferrite powder according to claim 1 , which is ferromagnetic powder for magnetic recording.

10. The hexagonal ferrite powder according to claim 1 , which has a switching field distribution of equal to or less than 0.8.

11. The hexagonal ferrite powder according to claim 1 , wherein the average particle size of the hexagonal ferrite powder is equal to or greater than 10.0 nm but equal to or less than 27.0 nm.

12. A magnetic recording medium according to claim 10 , wherein the average particle size of the hexagonal ferrite powder is equal to or greater than 10.0 nm but equal to or less than 27.0 nm.

13. A magnetic recording medium according to claim 12 , wherein the saturation magnetization of the hexagonal ferrite powder is equal to or greater than 35 A·m 2 /kg.

14. A magnetic recording medium, which comprises a magnetic layer comprising ferromagnetic powder and binder on a nonmagnetic support, wherein the ferromagnetic powder is hexagonal ferrite powder comprising equal to or more than 81% but equal to or less than 93% on a particle number basis of isotropic hexagonal ferrite particles satisfying equation (1), the balance being either isotropic hexagonal ferrite particles which do not satisfy equation (1) or anisotropic hexagonal ferrite particles:
major axis length/minor axis length<2.0  (1),

having an average particle size of equal to or greater than 10.0 nm but equal to or less than 35.0 nm, and having a saturation magnetization of equal to or greater than 30 A·m 2 /kg.

15. The magnetic recording medium according to claim 14 , wherein the hexagonal ferrite powder has a coercive force of equal to or greater than 159 kA/m but equal to or less than 318 kA/m.

16. The magnetic recording medium according to claim 14 , wherein the hexagonal ferrite powder has thermal stability satisfying equation (A):
60≦ KuV/kT   (A)

wherein, in equation (A), Ku denotes an anisotropy constant, V denotes an activation volume, k denotes Boltzmann constant, and T denotes absolute temperature.

17. The magnetic recording medium according to claim 14 , wherein the hexagonal ferrite powder has an average particle size of equal to or greater than 20.0 nm but equal to or less than 30.0 nm.

18. The magnetic recording medium according to claim 14 , wherein the average particle size of the isotropic particles satisfying equation (1) is equal to or greater than 10.0 nm but equal to or less than 30.0 nm.

19. The magnetic recording medium according to claim 14 , wherein the average particle size of the isotropic particles satisfying equation (1) is equal to or greater than 15.0 nm but equal to or less than 25.0 nm.

20. The magnetic recording medium according to claim 14 , wherein the coefficient of variation in the average particle size of the isotropic particles satisfying equation (1) in the hexagonal ferrite powder is equal to or less than 30%.

21. The hexagonal ferrite powder according to claim 11 , wherein the saturation magnetization of the hexagonal ferrite powder is equal to or greater than 35 A·m 2 /kg.

Assignees

• Fujifilm Corp

Inventors

• Hosoya Yoichi

Classifications

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01P2004/54

  Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension · CPC title

• H01F1/11

  in the form of particles {(for magnetic record carriers G11B5/70626)} · CPC title

• C01P2006/42

  Magnetic properties · CPC title