Ferromagnetic hexagonal ferrite powder, method of manufacturing the same, and magnetic recording medium

Patent metadata

Field	Value
Publication number	US-9502066-B2
Application number	US-201414499679-A
Country	US
Kind code	B2
Filing date	Sep 29, 2014
Priority date	Sep 30, 2013
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

An aspect of the present invention relates to ferromagnetic hexagonal ferrite powder, the average particle size of which is equal to or less than 20 nm, and which comprises, on a particle number basis, equal to or more than 50% of ellipsoid hexagonal ferrite powders satisfying relation (1): 1.2<major axis length/minor axis length<2.0 . . . (1).

First claim

What is claimed is:

1. A method of manufacturing ferromagnetic hexagonal ferrite powder, which comprises:
mixing an iron salt and a divalent metal salt in a base-containing water-based solution to prepare a hexagonal ferrite precursor; and
continuously feeding a water-based mixed flow containing an organic modifier and the hexagonal ferrite precursor that has been prepared to a reaction flow passage while heating to equal to or higher than 300° C. and applying a pressure of equal to or higher than 20 MPa to convert the hexagonal ferrite precursor to hexagonal ferrite particles, to provide ferromagnetic hexagonal ferrite powder, the average particle size of which is equal to or less than 20 nm, and which comprises, on a particle number basis, equal to or more than 50% of ellipsoid hexagonal ferrite powders satisfying relation (1):
1.2<major axis length/minor axis length<2.0 . . .   (1).

2. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , wherein an average particle size of the ferromagnetic hexagonal ferrite powder provided ranges from 5 nm to 20 nm.

3. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , wherein the ferromagnetic hexagonal ferrite powder provided comprises, on a particle number basis, equal to or less than 45% of spherical hexagonal ferrite particles satisfying relation (2):
major axis length/minor axis length≦1.2 . . .   (2).

4. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , wherein the ferromagnetic hexagonal ferrite powder provided comprises, on a particle number basis, equal to or less than 5% of acicular hexagonal ferrite particles satisfying relation (3):
major axis length/minor axis length≧2.0 . . .   (3).

5. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , wherein the water-based mixed flow that is continuously fed into a reaction flow passage is a water-based mixed flow that is obtained by:
mixing a water-based solution comprising the hexagonal ferrite precursor that has been prepared with a solution comprising an organic modifier and then
adding the solution that has been obtained by the mixing to a liquid feed passage into which water that has been heated and pressurized is being continuously fed.

6. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , wherein the water-based mixed flow that is continuously fed into a reaction flow passage is a water-based mixed flow that is obtained by:
sequentially adding a water-based solution comprising the hexagonal ferrite precursor that has been prepared and a solution comprising an organic modifier to a liquid feed passage to which water that has been heated and pressurized is being continuously fed.

7. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , which comprises preparing the water-based solution comprising the hexagonal ferrite precursor by causing a liquid feed passage to which a solution comprising a divalent metal salt and an iron salt is being fed to converge with a liquid feed passage to which a base-containing water-based solution is being fed to mix the two solutions.

8. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , wherein the organic modifier is selected from the group consisting of carboxylic acids and salts of carboxylic acids.

9. The method of manufacturing ferromagnetic hexagonal ferrite powder according to claim 1 , wherein the base-containing water-based solution is a water-based solution comprising a base in a quantity such that a molar ratio of the base to a combined quantity of the iron salt and the divalent metal salt is equal to or less than 5.

Assignees

• Fujifilm Corp

Inventors

• Hosoya Yoichi

Classifications

• G11B5/70678 Primary

  Ferrites · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01P2006/42

  Magnetic properties · CPC title

• C01P2004/10

  extending in one dimension, e.g. needle-like · CPC title