Phase-transfer catalytic colour fixation processing method for textile

Patent metadata

Field	Value
Publication number	US-9739010-B2
Application number	US-201314915771-A
Country	US
Kind code	B2
Filing date	Sep 3, 2013
Priority date	Sep 3, 2013
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

A phase-transfer catalytic color fixation processing method for textile includes the following steps: (1) dry-dyeing a textile with disperse reactive dyes in supercritical carbon dioxide fluid under waterless condition; (2) putting the textile in a phase-transfer catalytic fixation device, taking phase-transfer catalyst as the carrier of circulated supercritical carbon dioxide fluid, transporting the ionized fixing catalytic alkaline substance from aqueous phase to hydrophobic supercritical carbon dioxide fluid phase, getting full contact with functional groups on fibers, resulting in the fixing catalytic reaction with disperse reactive dyes.

First claim

What is claimed is:

1. A phase-transfer catalytic colour fixation processing method for textile, characterized in that it comprises the following steps:
(1) dry-dyeing a textile with disperse reactive dyes in supercritical carbon dioxide fluid under waterless condition;
(2) putting the textile in a phase-transfer catalytic fixation device, taking phase-transfer catalyst as the carrier of circulated supercritical carbon dioxide fluid, transporting the ionized fixing catalytic alkaline substance from aqueous phase to hydrophobic supercritical carbon dioxide fluid phase, getting full contact with functional groups on fibres, resulting in the fixing catalytic reaction with disperse reactive dyes,
Wherein said ionized fixing catalytic alkaline substance is sodium hydroxide, sodium carbonate, sodium phosphate, or substances that can produce hydroxyl by hydrolysis or thermal decomposition in the environment with a small amount of water, the concentration of said fixing catalytic alkaline substance is 0.1 g/L˜20g/L, and said phase-transfer catalyst is perfluorooctyl quaternary ammonium salt, or quaternary ammonium salt with C 12 ˜C 18 aliphatic chain or aryl group.

2. The phase-transfer catalytic colour fixation processing method according to claim 1 , wherein the active group of said disperse reactive dyes is selected from vinyl sulfone, ethenyl, triazine, nicotinic acid, or their derivatives.

3. The phase-transfer catalytic colour fixation processing method according to claim 1 , wherein the processing conditions of dry-dyeing on textile in said supercritical carbon dioxide fluid with anhydrous condition are, the system pressure is 8.0˜30.0 MPa, temperature ranging at 40° C.˜100° C., and processing time is 30˜180 min.

4. The phase-transfer catalytic colour fixation processing method according to claim 1 , wherein the conditions of catalytic fixation reaction are, temperature ranging at 60° C.˜160° C., the pressure is 8.0˜30.0 MPa, time of reaction is 20˜180 min.

5. The phase-transfer catalytic colour fixation processing method according to claim 1 , wherein said phase-transfer catalytic fixation device consists of a supercritical carbon dioxide fluid system, a fixing liquid storage tank and a fixing reactor, said fixing liquid storage tank is below said fixing reactor and sealed connected by connecting device, said fixing liquid storage tank has a cylindrical cavity, in which fluid distributor is set, said fluid distributor is composed of several interconnected pipes which bending down with the nozzles downward, and one of the pipes is used as circulated fluid inlet, connected with said supercritical carbon dioxide fluid system, and the rest pipes are used as circulated fluid outlets, said fixing reactor has a cylindrical cavity, with a circulated fluid outlet on the top and connected with said supercritical carbon dioxide fluid system; a porous filter is installed at the bottom of the reactor, and the lower part of a fluid diversion cover is horn shaped, covering at the top of the porous filter, and the top port of the fluid diversion cover is connected with the opposed port of textile winding shaft, said textile winding shaft is a cylindrical hollow shaft, whose top port is closed and holes are set on the cylinder.

Assignees

• Univ Soochow

Inventors

• Long Jiajie
• Xu Hongmei
• Cui Chuanglong
• Chen Feng
• Wei Xiaochen

Classifications

• D06P1/66

  containing quaternary ammonium groups · CPC title

• D06P1/94

  using dyes dissolved in solvents which are in the supercritical state · CPC title

• D06P1/6735

  of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341 · CPC title

• D06P1/16

  using dispersed, e.g. acetate, dyestuffs · CPC title

• D06P1/38

  using reactive dyes · CPC title