Phosphor and light-emitting equipment using phosphor

Patent metadata

Field	Value
Publication number	US-9738829-B2
Application number	US-201514736487-A
Country	US
Kind code	B2
Filing date	Jun 11, 2015
Priority date	Nov 26, 2003
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

Phosphors include a CaAlSiN 3 family crystal phase, wherein the CaAlSiN 3 family crystal phase comprises at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb.

First claim

What is claimed is:

1. A phosphor, comprising a CaAlSiN 3 family crystal phase, wherein:
the CaAlSiN 3 family crystal phase has a crystal structure belonging to the Cmc2 1 space group; and
the CaAlSiN 3 family crystal phase comprises:
at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb;
at least one divalent element selected from the group consisting of Mg, Ca, Sr, and Ba;
at least one trivalent element selected from the group consisting of B, Al, Ga, In, Sc, Y, La, Gd, and Lu; and
at least one tetravalent element selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf.

2. The phosphor according to claim 1 , wherein the CaAlSiN 3 family crystal phase comprises an inorganic compound having an X-ray diffraction pattern exhibiting at least ten peaks present in the X-ray diffraction pattern of CaAlSiN 3 .

3. The phosphor according to claim 2 , wherein the CaAlSiN 3 family crystal phase comprises an inorganic compound having lattice constants that differ from lattice constants of CaAlSiN 3 due to replacement of at least one constituent element of CaAlSiN 3 with at least one other element.

4. The phosphor according to claim 1 , wherein the CaAlSiN 3 family crystal phase comprises at least Eu, Ca, Sr, Al, Si, and N.

5. The phosphor according to claim 1 , wherein the CaAlSiN 3 family crystal phase comprises at least O and N.

6. The phosphor according to claim 4 , wherein the CaAlSiN 3 family crystal phase comprises at least O and N.

7. The phosphor according to claim 5 , wherein the CaAlSiN 3 family crystal phase comprises O and N in amounts satisfying:
0.5≦(number of atoms of N)/{(number of atoms of N)+(number of atoms of O)}≦1.

8. The phosphor according to claim 6 , wherein the CaAlSiN 3 family crystal phase comprises O and N in amounts satisfying:
0.5≦(number of atoms of N)/{(number of atoms of N)+(number of atoms of O)}≦1.

9. The phosphor according to claim 4 , wherein the CaAlSiN 3 family crystal phase comprises Ca and Sr in amounts satisfying:
0.02≦(number of atoms of Ca)/{(number of atoms of Ca)+(number of atoms of Sr)}<1.

10. The phosphor according to claim 6 , wherein the CaAlSiN 3 family crystal phase comprises Ca and Sr in amounts satisfying:
0.02≦(number of atoms of Ca)/{(number of atoms of Ca)+(number of atoms of Sr)}<1.

11. The phosphor according to claim 1 , wherein the CaAlSiN 3 family crystal phase has a composition given by:
M a A b D c E d X e
wherein:
M is at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb;
A is at least one element selected from the group consisting of Mg, Ca, Sr, and Ba;
D is at least one element selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf;
E is at least one element selected from the group consisting of B, Al, Ga, In, Sc, Y, La, Gd, and Lu;
X is at least one element selected from the group consisting of O, N, and F;
a+b= 1;
0.00001≦ a≦ 0.1;

0.5≦ c≦ 1.8;

0.5≦ d≦ 1.8;

0.8×(⅔+4/3× c+d )≦ e ; and

e≦ 1.2×(⅔+4/3× c+d ).

12. The phosphor according to claim 1 , wherein, when irradiated by an excitation source, the phosphor emits light having a peak emission intensity at a wavelength of from 570 nm to 700 nm.

13. The phosphor according to claim 4 , wherein, when irradiated by an excitation source, the phosphor emits light having a peak emission intensity at a wavelength of from 570 nm to 700 nm.

14. The phosphor according to claim 9 , wherein, when irradiated by an excitation source, the phosphor emits light having a peak emission intensity at a wavelength of from 570 nm to 700 nm.

15. The phosphor according to claim 11 , wherein, when irradiated by an excitation source, the phosphor emits light having a peak emission intensity at a wavelength of from 570 nm to 700 nm.

16. The phosphor according to claim 1 , wherein, when irradiated by an excitation source, the phosphor emits light having a color satisfying:
0.45≦ x≦ 0.7

as a value of (x, y) on the CIE chromaticity coordinates.

17. The phosphor according to claim 4 , wherein, when irradiated by an excitation source, the phosphor emits light having a color satisfying:
0.45≦ x≦ 0.7

as a value of (x, y) on the CIE chromaticity coordinates.

18. The phosphor according to claim 9 , wherein, when irradiated by an excitation source, the phosphor emits light having a color satisfying:
0.45≦ x≦ 0.7

as a value of (x, y) on the CIE chromaticity coordinates.

19. The phosphor according to claim 11 , wherein, when irradiated by an excitation source, the phosphor emits light having a color satisfying:
0.45≦ x≦ 0.7

as a value of (x, y) on the CIE chromaticity coordinates.

20. A phosphor, comprising a solid solution crystal phase, wherein:
the solid solution crystal phase is a CaAlSiN 3 family crystal phase having a crystal structure belonging to the Cmc2 1 space group; and
the CaAlSiN 3 family crystal phase comprises:
at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu;
at least one divalent element selected from the group consisting of Mg, Ca, Sr, and Ba;
at least one trivalent element selected from the group consisting of B, Al, Ga, In, Sc, Y, La, Gd, and Lu; and
at least one tetravalent element selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf.

21. A phosphor, comprising an inorganic compound, wherein:
the inorganic compound comprises M, A, D, E, and X;
M is at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb;
A is at least one element selected from the group consisting of divalent metal elements other than M;
D is at least one element selected from the group consisting of tetravalent metal elements;
E is at least one element selected from the group consisting of trivalent metal elements;
X is at least one element selected from the group consisting of 0, N, and F; and
the inorganic compound comprises a CaAlSiN 3 family crystal phase having a crystal structure belonging to the Cmc2 1 space group.

22. The phosphor according to claim 21 , wherein the inorganic compound has lattice constants that differ from lattice constants of CaAlSiN 3 due to replacement of at least one constituent element of CaAlSiN 3 with at least one other element.

23. The phosphor according to claim 21 , wherein the inorganic compound comprises Sr.

24. The phosphor according to claim 23 , wherein the inorganic compound comprises Ca and Sr in amounts satisfying:
0.02≦(number of atoms of Ca)/{(number of atoms of Ca)+(number of atoms of Sr)}<1.

Assignees

• Mitsubishi Chem Corp
• Nat Inst For Materials Science
• Nichia Corp
• Citizen Electronics

Inventors

• Hirosaki Naoto
• Ueda Kyota
• Yamamoto Hajime

Classifications

• H10W90/756

  between a chip and a stacked lead frame, conducting package substrate or heat sink · CPC title

• H10W74/00

  Encapsulations, e.g. protective coatings · CPC title

• H10W72/884

  Die-attach connectors and bond wires · CPC title

• C04B35/58

  based on borides, nitrides, {i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides} or silicides {(containing free binder metal C22C29/00)} · CPC title

• C04B35/597

  based on silicon oxynitride, {e.g. SIALONS} · CPC title