Controlling fragmentation of chemically strengthened glass

Patent metadata

Field	Value
Publication number	US-9738560-B2
Application number	US-201615163260-A
Country	US
Kind code	B2
Filing date	May 24, 2016
Priority date	Nov 17, 2014
Publication date	Aug 22, 2017
Grant date	Aug 22, 2017

Abstract

A method of manufacturing a glass substrate to control the fragmentation characteristics by etching and filling trenches in the glass substrate is disclosed. An etching pattern may be determined. The etching pattern may outline where trenches will be etched into a surface of the glass substrate. The etching pattern may be configured so that the glass substrate, when fractured, has a smaller fragmentation size than chemically strengthened glass that has not been etched. A mask may be created in accordance with the etching pattern, and the mask may be applied to a surface of the glass substrate. The surface of the glass substrate may then be etched to create trenches. A filler material may be deposited into the trenches.

First claim

What is claimed is:

1. A method of manufacturing a glass substrate to control fragmentation characteristics of the glass substrate, the method comprising:
determining an etching pattern, the etching pattern being configured to control a fragmentation size of a glass substrate by modifying a stress field within the glass substrate to create an inhomogeneous stress field;
masking a first surface of the glass substrate according to the etching pattern, the glass substrate being chemically strengthened glass, the glass substrate having an exterior region and an interior region, wherein the exterior region has residual compressive stresses and the interior region has residual tensile stresses;
etching an unmasked portion of the first surface to produce a plurality of trenches in the first surface; and
filling the plurality of trenches with a filler material to generate the inhomogeneous stress field in the glass substrate.

2. The method of claim 1 , wherein determining the etching pattern includes:
determining a desired fragmentation size of the glass substrate, the desired fragmentation size of the glass substrate being less than 250 micrometers, the desired fragmentation size being an average of a width of a plurality of fragments created when the glass substrate fractures; and
selecting the etching pattern based on the desired fragmentation size, wherein the etching pattern defines locations of the plurality of trenches in the glass substrate.

3. The method of claim 1 , the method further comprising bonding the glass substrate to a second glass substrate.

4. The method of claim 1 , wherein filling the plurality of trenches with the filler material to generate the inhomogeneous stress field in the glass substrate includes:
filling the plurality of trenches with a metal filler, the metal filler being at a temperature sufficient to cause the metal to bond with the glass substrate at the boundaries of the trenches; and
cooling the metal filler.

5. The method of claim 1 , wherein the filler material is a composition of aluminum and nickel, the filler material having a metal filament inserted therein, the method further comprising:
determining that the chemical reaction should be initiated; and
running a current through the metal filament, wherein the current is large enough to cause the metal filament to heat up to a temperature sufficient to initiate a chemical reaction between the aluminum and the nickel.

6. The method of claim 1 , wherein determining the etching pattern includes:
choosing the filler material;
determining a desired fragmentation size of the glass substrate; and
selecting, based on the chosen filler material and the desired fragmentation size, the etching pattern from a plurality of etching patterns, wherein the etching pattern defines locations of the plurality of trenches in the glass substrate, the selected etching pattern being configured to cause the glass substrate to fracture such that an average of a width of a plurality of fragments created when the glass substrate fractures is less than or equal to the desired fragmentation size.

7. The method of claim 1 , wherein the chemically strengthened glass was strengthened using a potassium and sodium (K/Na) ion exchange process, wherein trenches of the plurality of trenches are spaced approximately 20 micrometers apart, wherein each trench of the plurality of trenches is approximately 15 micrometers across, and wherein the filler material is aluminum.

8. A method of manufacturing a glass substrate to control fragmentation characteristics of the glass substrate, the method comprising:
determining a deposit pattern, the deposit pattern being configured to control a fragmentation size of a glass substrate, the glass substrate being chemically strengthened glass, the glass substrate having an exterior region and an interior region, wherein the exterior region has residual compressive stresses and the interior region has residual tensile stresses;
depositing a layer of metal on top of a first surface of the glass substrate;
patterning, using a photolithography process, the layer of metal according to the deposit pattern to create an inhomogeneous stress field within the substrate.

9. The method of claim 8 , the method further comprising bonding the glass substrate to a second glass substrate.

10. The method of claim 8 , wherein determining a deposit pattern comprises:
determining a desired fragmentation size of the glass substrate; and
selecting, based on the desired fragmentation size, the deposit pattern from a plurality of deposit patterns, wherein the deposit pattern establishes which parts of the first surface of the glass substrate will have a layer of metal deposited on top.

11. A method of manufacturing a glass substrate to control fragmentation characteristics of the glass substrate, the method comprising:
determining a irradiation pattern, the irradiation pattern being configured to control a fragmentation size of a glass substrate, the glass substrate being chemically strengthened glass, the glass substrate having an exterior region and an interior region, wherein the exterior region has residual compressive stresses and the interior region has residual tensile stresses;
applying a first mask to a first surface of the glass substrate according to the irradiation pattern; and
irradiating the glass substrate using an ion beam, wherein the ion beam is configured to emit ions towards the first surface of the glass substrate.

12. The method of claim 11 , the method further comprising:
applying a second mask to a second surface of the glass substrate according to irradiation pattern, wherein the second surface is substantially orthogonal to the first surface; and
irradiating the glass substrate using the ion beam by emitting ions towards the second surface of the glass substrate.

13. The method of claim 11 , the method further comprising:
changing an angle between the first surface and a central incidence axis of the ion beam; and
irradiating the glass substrate a second time using the ion beam.

14. The method of claim 11 wherein the irradiation pattern is configured to cause the ion beam irradiation to create a path of damaged glass in the glass substrate.

15. The method of claim 14 , wherein the path of damaged glass runs from a first point in the interior region of the glass substrate to a second point in the exterior region of the glass substrate, and wherein the irradiating the glass substrate using an ion beam comprises:
irradiating the glass substrate using the ion beam with a first energy to create a first damaged region at a first depth;
changing the energy of the ion beam from the first energy to a second energy; and
irradiating the glass substrate using the ion beam with a second energy to create a second damaged region at a second depth, wherein the first and second damaged regions form a path from the first point to the second point.

16. The method of claim 11 , the method further comprising bonding the glass substrate to a second glass substrate.

17. The method of claim 11 , wherein the irradiation pattern includes one or more disconnected features.

18. The method of claim 11 , wherein the irradiating the glass substrate using an ion beam comprises raster-scanning the ion beam over a portion of the first surface of the glass substrate.

19. The method of claim 11 , wherein determining an irradiation pattern comprises:
determining a desired fragmentation size of the glass substrate; and
selecting, based on the desired fra

Assignees

• IBM

Inventors

• Cabral Jr Cyril
• Doany Fuad E
• Fritz Gregory M
• Gordon Michael S
• Huang Qiang
• Lewandowski Eric P
• Liu Xiao Hu
• Rodbell Kenneth P
• Shaw Thomas M

Classifications

• C03C2218/328

  Partly or completely removing a coating · CPC title

• C03C2217/252

  Al · CPC title

• C03C2218/34

  Masking · CPC title

• C03C27/06

  Joining glass to glass by processes other than fusing (fusing C03B23/20; units for use as elements for closing wall or like openings and comprising two or more parallel glass panes in spaced relationship, the panes being permanently secured together E06B3/66) · CPC title

• C03C17/34

  with at least two coatings having different compositions (C03C17/44 takes precedence) · CPC title