Fuel cell comprising a proton-exchange membrane, having an increased service life

Patent metadata

Field	Value
Publication number	US-9735442-B2
Application number	US-201214008609-A
Country	US
Kind code	B2
Filing date	Mar 29, 2012
Priority date	Mar 31, 2011
Publication date	Aug 15, 2017
Grant date	Aug 15, 2017

Abstract

A fuel cell includes a proton-exchange membrane, and a cathode and anode fixed on its opposite sides. The anode delimits a flow conduit between a molecular-oxygen inlet area and a water outlet area. The cathode includes a support for catalyst material. The support has first and second materials to which catalyst is fixed, the first material being a graphitized material. The second material has a resistance to corrosion by oxygen that is greater than that of the first material. A quantity of the second material at the inlet area is greater than a quantity of the second material at the water outlet. The cathode comprises a first layer including the first material and a second layer including the second material. A thickness of the second layer decreases between the molecular-oxygen inlet area and the water outlet area.

First claim

The invention claimed is:

1. A manufacture comprising a fuel cell, said fuel cell comprising a proton-exchange membrane, a cathode fixed on a first side of said proton-exchange membrane, and an anode fixed on a second side of said proton-exchange membrane, wherein said anode delimits a flow conduit between a molecular-oxygen inlet area and a water outlet area, wherein said cathode consists of a first catalyst layer and a second catalyst layer, wherein said first catalyst layer includes a first material, wherein said second catalyst layer includes a second material, wherein said first material comprises a graphitized material, wherein said second material has a resistance to corrosion by oxygen that is greater than a resistance to corrosion by oxygen of said first material, wherein a thickness of said first catalyst layer decreases from said water outlet area to said molecular-oxygen inlet area, wherein a thickness of said first catalyst layer at said water outlet area is less than a thickness of said first catalyst layer at said molecular-oxygen inlet area, wherein a thickness of said second catalyst layer decreases from said molecular-oxygen inlet area to said water outlet area, and wherein a thickness of said first catalyst layer at said molecular-oxygen inlet area is greater than a thickness of said second catalyst layer at said water outlet area.

2. The manufacture of claim 1 , wherein a concentration of said second material at said molecular-oxygen inlet area is greater than 10% by mass.

3. The manufacture of claim 1 , wherein a concentration of said second material at said molecular-oxygen inlet area is greater, by at least 50%, than a concentration of said second material at said water outlet area.

4. The manufacture of claim 1 , wherein said second material comprises fullerene.

5. The manufacture of claim 1 , wherein said second material comprises doped titanium dioxide.

6. The manufacture of claim 1 , wherein said second material comprises doped stannic oxide.

7. The manufacture of claim 1 , wherein said anode delimits a flow conduit between a molecular-hydrogen inlet area and molecular-hydrogen outlet area, and wherein said molecular-hydrogen outlet area is disposed to face said molecular-oxygen inlet area across said proton-exchange membrane.

8. The manufacture of claim 1 , wherein said proton-exchange membrane, has a thickness at said inlet area that is at least 40% greater than a thickness thereof at said outlet area.

9. The manufacture of claim 1 , wherein said first catalyst layer has a homogeneous concentration of graphitized material.

10. The manufacture of claim 1 , further comprising a catalyst-material support, wherein said catalyst-material support comprises a layer that comprises an oxide of tin.

11. The manufacture of claim 1 , wherein said cathode comprises layers that vary in thickness between said inlet area and said outlet area, and wherein a superimposition of said layers has a constant thickness between said inlet area and said water outlet area.

12. The manufacture of claim 1 , wherein said cathode comprises layers that change thickness continuously between said inlet area and said outlet area.

13. The manufacture of claim 1 , further comprising a first guiding plate, a second guiding plate, a first gas diffusion layer, and a second gas diffusion layer, wherein said first guiding plate has a face that is oriented towards said proton-exchange membrane, wherein said second guiding plate has a face that is oriented towards said proton-exchange membrane, wherein said first gas diffusion layer is positioned between said first guiding plate and said anode, wherein said second gas diffusion layer is positioned between said cathode and said second guiding plate, and wherein said face of said first guiding plate faces said face of said second guiding plate.

14. The manufacture of claim 1 , wherein said proton-exchange membrane has a variable thickness between said inlet area and said outlet area.

15. The manufacture of claim 1 , wherein said proton-exchange membrane has a thickness at said inlet area that is greater than a thickness thereof at said outlet area.

16. The manufacture of claim 1 , wherein said material that is more resistant to corrosion by oxygen than said graphitized material comprises an oxide of titanium.

17. The manufacture of claim 1 , further comprising fullerene disposed in a catalyst-material support outside of said first catalyst layer.

18. The manufacture of claim 1 , wherein said first catalyst layer has a thickness that decreases continuously from said inlet area and said water outlet area and wherein said second catalyst layer has a thickness that increases continuously from said inlet area and said water outlet area.

19. The manufacture of claim 1 , wherein said anode delimits a flow conduit between an inlet area for receiving molecules of hydrogen and for discharging molecules of hydrogen, wherein said inlet and outlet areas are disposed such that a line between them passes through said proton-exchange membrane.

20. The manufacture of claim 1 , wherein said proton-exchange membrane has a resistance to proton flow at said outlet area and a resistance to proton flow at said inlet area, and wherein said resistance to proton flow at said outlet area is less than said resistance to proton flow at said inlet area.

Assignees

• Vincent Remi
• Escribano Sylvie
• Franco Alejandro
• Guetaz Laure
• Krosnicki Guillaume
• Commissariat L Energie Atomique Et Aux Energies Alternatives

Inventors

• Vincent Remi
• Escribano Sylvie
• Franco Alejandro
• Guetaz Laure
• Krosnicki Guillaume

Classifications

• H01M4/9083

  on carbon or graphite · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• H01M4/8636 Primary

  with a gradient in another property than porosity (H01M4/861 takes precedence) · CPC title

• H01M8/1007

  with both reactants being gaseous or vaporised (H01M8/12 takes precedence) · CPC title

• H01M2004/8689

  Positive electrodes · CPC title