Flow batteries having an electrode with a density gradient and methods for production and use thereof

Patent metadata

Field	Value
Publication number	US-10109879-B2
Application number	US-201615167926-A
Country	US
Kind code	B2
Filing date	May 27, 2016
Priority date	May 27, 2016
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

Electrochemical cells, such as those present within flow batteries, can have at least one electrode with a density gradient in which the density increases outwardly from a separator. Such electrodes can decrease contact resistance and lessen the incidence of parasitic reactions in the electrochemical cell. Flow batteries containing the electrochemical cells can include: a first half-cell containing a first electrode, a second half-cell containing a second electrode, and a separator disposed between the first half-cell and the second half-cell. At least one of the first electrode and the second electrode has a density gradient such that a density of at least one of the first electrode and the second electrode increases outwardly from the separator.

First claim

What is claimed is the following:

1. A flow battery comprising:
a first half-cell containing a first electrode;
a second half-cell containing a second electrode; and
a separator disposed between the first half-cell and the second half-cell;
wherein at least one of the first electrode and the second electrode has a density gradient such that a density of at least one of the first electrode and the second electrode increases outwardly from the separator, such that the density of the at least one of the first electrode and the second electrode increases from the separator to a bipolar plate of the flow battery.

2. The flow battery of claim 1 , wherein the density gradient is a continuous gradient.

3. The flow battery of claim 1 , wherein the density gradient is a stepped gradient.

4. The flow battery of claim 1 , wherein at least one of the first electrode and the second electrode comprises a conductive additive deposited selectively upon the first electrode, the second electrode, or both the first and second electrodes at a face opposite the separator.

5. The flow battery of claim 4 , wherein the conductive additive comprises amorphous carbon, graphite, carbon nanotubes, graphene, or any combination thereof.

6. The flow battery of claim 1 , wherein at least one of the first electrode and the second electrode comprises a carbon cloth.

7. The flow battery of claim 6 , wherein the carbon cloth comprises a conductive additive deposited selectively upon the first electrode, the second electrode, or both the first and second electrodes at a face opposite the separator.

8. The flow battery of claim 7 , wherein the conductive additive comprises amorphous carbon, graphite, carbon nanotubes, graphene, or any combination thereof.

9. The flow battery of claim 1 , wherein at least one of the first electrode and the second electrode comprises a first carbon cloth having a first density and a second carbon cloth having a second density;
wherein the first density is lower than the second density, and the first carbon cloth is sandwiched between the separator and the second carbon cloth.

10. The flow battery of claim 1 , wherein both the first electrode and the second electrode have a density gradient.

11. The flow battery of claim 1 , wherein the bipolar plate further comprises:
a first bipolar plate contacting the first electrode and a second bipolar plate contacting the second electrode.

12. The flow battery of claim 11 , wherein the first bipolar plate and the second bipolar plate each contain a plurality of flow channels, the plurality of flow channels being configured to deliver a first electrolyte solution to the first electrode and a second electrolyte solution to the second electrode.

13. A method comprising:
providing a conductive material having a density gradient; and
forming an electrochemical cell comprising:
a first half-cell containing a first electrode;
a second half-cell containing a second electrode; and
a separator disposed between the first half-cell and the second half-cell;
wherein at least one of the first electrode and the second electrode comprises the conductive material having the density gradient, and a density of at least one of the first electrode and the second electrode increases outwardly from the separator, such that the density of the at least one of the first electrode and the second electrode increases from the separator to a bipolar plate of the flow battery.

14. The method of claim 13 , further comprising:
introducing the density gradient into the conductive material by selectively depositing a conductive additive onto a first face of the conductive material.

15. The method of claim 14 , wherein the conductive additive is deposited onto the first face of the conductive material by chemical vapor deposition.

16. The method of claim 14 , wherein the conductive additive comprises amorphous carbon, graphite, carbon nanotubes, graphene, or any combination thereof.

17. The method of claim 14 , wherein the conductive additive is deposited onto the first face of the conductive material by applying a solvent dispersion of the conductive additive onto the conductive material.

18. The method of claim 14 , wherein at least one of the first electrode and the second electrode comprises a carbon cloth.

19. The method of claim 13 , further comprising:
introducing the density gradient into the conductive material by selectively removing at least a portion of the conductive material from a first face of the conductive material.

20. The method of claim 19 , wherein the conductive material is removed from the first face of the conductive material by a process selected from the group consisting of laser ablation, chemical etching, needling, and any combination thereof.

21. The method of claim 13 , further comprising:
introducing the density gradient into the conductive material by placing at least one layer of a first conductive material upon at least one layer of a second conductive material to form a layered conductive material, the first conductive material and the second conductive material having different densities;
wherein the first conductive material is sandwiched between the separator and the second conductive material.

22. The method of claim 21 , wherein the first conductive material and the second conductive material comprise carbon cloths having different densities.

23. The method of claim 13 , wherein both the first electrode and the second electrode have a density gradient.

24. The method of claim 13 , wherein the electrochemical cell is located within a flow battery.

25. The method of claim 13 , wherein a first bipolar plate contacts the first electrode and a second bipolar plate contacts the second electrode.

26. The method of claim 25 , further comprising:
connecting a plurality of the electrochemical cells in series with one another in an electrochemical stack.

27. A method comprising:
providing a flow battery having an electrochemical cell comprising:
a first half-cell containing a first electrode;
a second half-cell containing a second electrode; and
a separator disposed between the first half-cell and the second half-cell;
wherein at least one of the first electrode and the second electrode comprises a conductive material having a density gradient, and a density of at least one of the first electrode and the second electrode increases outwardly from the separator, such that the density of the at least one of the first electrode and the second electrode increases from the separator to a bipolar plate of the flow battery; and
circulating a first electrolyte solution through the first half-cell and a second electrolyte solution through the second half-cell;
wherein convective flow of at least one of the first electrolyte solution and the second electrolyte solution occurs preferentially in a low-density region of the first electrode or the second electrode proximate the separator.

28. The method of claim 27 , wherein a first bipolar plate contacts the first electrode and a second bipolar plate contacts the second electrode, and the first electrolyte solution and the second electrolyte solution are circulated through a plurality of flow channels within the first bipolar plate and the second bipolar plate.

29. The method of claim 27 , wherein both the first electrode and the second elec

Assignees

• Lockheed Martin Advanced Energy Storage Llc
• Lockheed Martin Energy Llc

Inventors

• Loretz Jeremy
• Puranam Srivatsava Venkataranga
• Vanbenschoten Helen Elizabeth

Classifications

• H01M4/96

  Carbon-based electrodes · CPC title

• H01M8/0258

  characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant · CPC title

• H01M4/861

  with a gradient in the porosity · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M4/8673

  Electrically conductive fillers · CPC title