Process and equipment for producing pure lithium-containing solution

Patent metadata

Field	Value
Publication number	US-9725787-B2
Application number	US-201314402178-A
Country	US
Kind code	B2
Filing date	Jun 4, 2013
Priority date	Jun 5, 2012
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

The invention relates to a process for producing a lithium-containing solution from a lithium-containing raw-material solution, by: a) precipitating a first part of magnesium and calcium from the lithium-containing raw-material solution, b) extracting a second part of calcium and magnesium from the lithium-containing solution by liquid-liquid extraction, a resultant product being a lithium-containing solution. The invention also relates to equipment for producing a lithium-containing solution from a lithium-containing raw-material solution, including a precipitation unit to remove a first part of magnesium and calcium and an extraction unit to receive the lithium-containing raw-material solution and to remove therefrom a second part of calcium and magnesium by liquid-liquid extraction, and control unit to control the operation of the precipitation unit.

First claim

The invention claimed is:

1. A process for producing a lithium-containing solution from a raw-material brine solution, the process comprising:
a) a precipitation step, in which a first part of magnesium and calcium is removed from the raw-material brine solution by precipitation resulting in a first lithium-containing solution, and
b) an extraction step, in which a second part of calcium and magnesium is removed from the first lithium-containing solution by liquid-liquid extraction, a resultant product being a second lithium-containing solution.

2. The process of claim 1 , wherein the raw-material brine solution is a solution derived from a naturally occurring brine.

3. The process of claim 1 , wherein the first part of magnesium and calcium contained in the raw-material brine solution is removed by using sodium carbonate as a precipitant.

4. The process of claim 1 , wherein the first part of magnesium and calcium contained in the raw-material brine solution is removed by using calcium hydroxide as a precipitant.

5. The process of claim 1 , wherein the first part of the calcium and magnesium to be removed is 50 to 95% by weight of the total amount of calcium and magnesium in the raw-material brine solution.

6. The process of claim 1 , comprising:
assaying the composition of the raw-material brine solution prior to precipitation,
determining, on the basis of said composition of the raw-material brine solution, the amount of a precipitant that removes from the raw-material brine solution a predetermined first part of magnesium and calcium, and
dispensing said determined amount of precipitant into a precipitation unit.

7. The process of claim 1 , comprising:
assaying a composition of a feed into the precipitation step and/or the composition of the solution in the precipitation,
determining, on the basis of said composition, the amount of a precipitant that removes from the raw-material brine solution said first part of magnesium and calcium, and
dispensing said determined amount of precipitant into a precipitation unit.

8. The process of claim 1 , wherein the composition of a precipitation-stage solution is measured during the precipitation step, and the precipitation step is discontinued when the composition of the precipitation-stage solution achieves a set value.

9. The process of claim 8 , wherein the set value is achieved when the total content of calcium and magnesium in the precipitation-stage solution is 50 to 95% by weight lower than the total content of calcium and magnesium in the raw-material brine solution.

10. The process of claim 8 , wherein the precipitation step is continued until the total content of magnesium and calcium in the precipitation-stage solution is dropped 50 to 95% by weight of the corresponding content in the raw-material brine solution.

11. The process of claim 8 , wherein the precipitation step is continued until the lithium content in the precipitation-stage solution is reduced at most 10% by weight of the corresponding content in the raw-material brine solution.

12. The process of claim 1 , wherein the second part of calcium and magnesium is 5 to 50% by weight of the total amount of the calcium and magnesium in the entire raw-material brine solution.

13. The process of claim 1 , wherein an organic extractant is used in the extraction step.

14. The process of claim 1 , wherein a dialkyl phosphoric acid is selected from the group consisting of di-2-ethyl hexyl phosphoric acid, dialkyl phosphonic acid, dialkyl phosphinic acid, and a mixture thereof is used in the extraction step.

15. The process of claim 1 , wherein the extraction step includes a stripping step of calcium and magnesium, and a hydrochloric-acid-containing aqueous solution is used as a stripping solution, which hydrochloric-acid-containing aqueous solution containing calcium and magnesium, obtained after the stripping step, is conveyed back to an earlier process step.

16. The process of claim 1 , which further includes at least one pre-treatment step of the raw-material brine solution selected from the group consisting of the steps of evaporation of the raw-material brine solution, dissolution of calcium and magnesium carbonates in the raw-material brine solution, and removal of boron from the raw-material brine solution.

17. The process of claim 1 , wherein sodium carbonate is added to the second lithium-containing solution to precipitate lithium carbonate.

Assignees

• Outotec Finland Oy

Inventors

• Laitala Hannu
• Karonen Janne
• Haavanlammi Liisa

Classifications

• C01D15/00

  Lithium compounds · CPC title

• C01D15/08 Primary

  Carbonates; Bicarbonates · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C22B26/12 Primary

  Obtaining lithium · CPC title

• Y02P10/234

  Cross-Sectional Technologies · mapped topic