Method and apparatus for producing carbonate

Patent metadata

Field	Value
Publication number	US-2019263670-A1
Application number	US-201616308075-A
Country	US
Kind code	A1
Filing date	Jun 7, 2016
Priority date	Jun 7, 2016
Publication date	Aug 29, 2019
Grant date	—

Abstract

An apparatus for preparing carbonate according to an embodiment of the present invention includes a reactor in which carbonation gas reacts with a solution to be carbonated; a first nozzle located at one side of the reactor, and discharging the solution to be carbonated into the reactor, a second nozzle located adjacent to the first nozzle, and spraying the carbonation gas into the path through which the solution to be carbonated is discharged to form a mist composed of the solution to be carbonated and the carbonation gas, and a recovery unit located at a lower end of the reactor, and recovering a carbonate salt from the slurry formed in the reactor.

First claim

1 . An apparatus for preparing carbonate comprising:
a reactor in which carbonation gas reacts with a solution to be carbonated; a first nozzle located at one side of the reactor, and discharging the solution to be carbonated into the reactor, a second nozzle located adjacent to the first nozzle, and spraying the carbonation gas into the path through which the solution to be carbonated is discharged to form a mist composed of the solution to be carbonated and the carbonation gas, and a recovery unit located at a lower end of the reactor, and recovering a carbonate salt from the slurry formed in the reactor.

2 . The apparatus for preparing carbonate of claim 1 ,
wherein the recovery unit comprises a filtration unit for filtering the carbonate salt from the slurry.

3 . The apparatus for preparing carbonate of claim 2 ,
wherein the recovery unit comprises a drying unit for drying the filtered carbonate salt.

4 . The apparatus for preparing carbonate of claim 2 ,
wherein the recovery unit comprises a plurality of filtration units, wherein the recovery unit comprises a draw-out unit connecting the reactor and the plurality of filtration units, and a valve installed in a flow path connecting the draw-out unit and each of the filtration units.

5 . The apparatus for preparing carbonate of claim 4 ,
wherein the recovery unit comprises a control unit connected to the valve, wherein the control unit controls the valve to control the throughput of the plurality of filtration units.

6 . The apparatus for preparing carbonate of claim 1 , comprising:
a carbonation gas circulating unit for recovering the carbonation gas discharged from the second nozzle and recirculating the carbonation gas to the second nozzle.

7 . The apparatus for preparing carbonate of claim 1 , comprising:
a solution to be carbonated circulating unit for recovering the solution to be carbonated from the slurry from which is filtered the carbonate salt, and recirculating the solution to be carbonated to the first nozzle.

8 . The apparatus for preparing carbonate of claim 1 ,
wherein the second nozzle is a plurality.

9 . The apparatus for preparing carbonate of claim 1 ,
wherein the first nozzle and the second nozzle form an angle of 10 DEG to 70 DEG in a vertical direction of a flow direction of the solution to be carbonated.

10 . The apparatus for preparing carbonate of claim 9 ,
wherein the first nozzle and the second nozzle form an angle of 30 DEG to 50 DEG in a vertical direction of a flow direction of the solution to be carbonated.

11 . The apparatus for preparing carbonate of claim 1 ,
wherein the first nozzle is located on the upper side of the reactor, and the second nozzle is installed below the first nozzle.

12 . The apparatus for preparing carbonate of claim 1 ,
wherein the second nozzle discharges the carbonation gas at a pressure of 1.5 bar to 2.5 bar.

13 . The apparatus for preparing carbonate of claim 1 ,
wherein, the second nozzle is installed for discharging the carbonation gas to a pass through which is away from a center portion of the solution to be carbonated to be discharged, on a perpendicular plane of a direction in which the solution to be carbonated is discharged.

14 . A method for preparing carbonate, comprising:
discharging a solution to be carbonated from a first nozzle; forming a mist composed of the solution to be carbonated and a carbonated gas by discharging a carbonation gas from a second nozzle to a path through which the solution to be carbonated is discharged; forming a slurry having carbonate by reacting a cation of the solution to be carbonated with the carbonation gas in the mist; and recovering the carbonate from the slurry.

15 . The method for preparing carbonate of claim 14 ,
wherein, the solution to be carbonated comprises a calcium ion, a magnesium ion or a lithium ion as a cation.

16 . The method for preparing carbonate of claim 14 , wherein a pH of the solution to be carbonated is pH 10 or more.

17 . The method for preparing carbonate of claim 14 ,
wherein, the discharge path of the solution to be carbonated and the discharge path of the carbonation gas form an angle of 10° to 70° in the vertical direction to the flow direction of the solution to be carbonated.

18 . The method for preparing carbonate of claim 17 ,
wherein, the discharge path of the solution to be carbonated and the discharge path of the carbonation gas form an angle of 30° to 50° in the vertical direction to the flow direction of the solution to be carbonated.

19 . The method for preparing carbonate of claim 14 ,
wherein, the carbonation gas is discharged in a direction away from a central portion of the solution to be carbonation to be discharged on a perpendicular plane of a direction in which the solution to be carbonated is discharged.

20 . The method for preparing carbonate of claim 14 ,
wherein, a droplet size of the solution to be carbonated in the mist is 10 nm to 50 μm.

21 . The method for preparing carbonate of claim 14 ,
wherein, the carbonation gas is discharged from the second nozzle at a pressure of 1.5 bar to 2 bar.

22 . The method for preparing carbonate of claim 14 ,
wherein, the step of recovering the carbonate comprises filtering the solution to be carbonated containing the carbonate to recover the carbonate.

23 . The method for preparing carbonate of claim 22 ,
wherein, the step of recovering the carbonate comprises drying the filtered carbonate.

24 . (canceled)

25 . (canceled)

26 . (canceled)

Assignees

• Res Inst Ind Science & Tech

Inventors

• Jung Woo Chul
• Lee Sang Gil
• Park Kwang Seok
• Park Sung Kook
• Kim Ki Young
• Wi Jin Yeop
• Lee Hyun Woo
• Park Woon Kyoung
• Lee Myung Gyu

Classifications

• B01J19/26 Primary

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• C01D15/08 Primary

  Carbonates; Bicarbonates · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01B32/60

  Preparation of carbonates or bicarbonates in general (of percarbonates C01B15/10; of specific carbonates or bicarbonates according to the cation C01B-C01G) · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title