Lubricant compositions for improved engine performance

Patent metadata

Field	Value
Publication number	US-9725673-B2
Application number	US-73146210-A
Country	US
Kind code	B2
Filing date	Mar 25, 2010
Priority date	Mar 25, 2010
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

The disclosure provides a lubricant composition for lubricating an engine, a method for operating an engine and an additive concentrate. The lubricant composition includes a base oil of lubricating viscosity; one or more metal dialkyldithiophosphates having more than 75 mole percent of alkyl groups derived from 4-methyl-2-pentanol, and from about 0.1 to about 2.0 percent by weight of detergent derived from an alkyl phenol or sulfurized alkyl phenol based on a total weight of the lubricant composition. An amount of the one or more metal dialkyldithiophosphate in the lubricant composition ranges from about 0.01 to about 0.10 percent by weight phosphorus based on a total weight of the lubricant composition. The lubricant composition has a total a total base number (TBN) of about 5.0 to about 10.0.

First claim

What is claimed is:

1. A lubricant composition for lubricating a spark ignition engine comprising:
from 50 wt. % to 95 wt. % of a Group II base oil of lubricating viscosity based on a total weight of the lubricant composition,
one or more zinc dialkyldithiophosphates having more than 75 mole percent of alkyl groups derived from 4-methyl-2-pentanol; and
from about 0.1 to 1.0 percent by weight of a first metal-containing detergent derived from an alkyl phenol or sulfurized alkyl phenol based on a total weight of the lubricant composition,

wherein the lubricant composition comprises an amount of the one or more zinc dialkyldithiophosphates to provide from about 0.01 to about 0.10 percent by weight phosphorus based on a total weight of the lubricant composition, and wherein the lubricant composition has a total a total base number (TBN) of 6.5 to 10.0.

2. The lubricant composition of claim 1 , wherein the one or more zinc dialkyldithiophosphates have 100 mole percent of the alkyl groups derived from 4-methyl-2-pentanol.

3. The lubricant composition of claim 1 , further comprising an overbased alkali or alkaline earth metal second detergent in an amount ranging from 0.2 to 2.0 weight percent based on a total weight of the lubricant composition, wherein the second detergent is not derived from an alkyl phenol or sulfurized alkyl phenol.

4. The lubricant composition of claim 1 , wherein the lubricant composition comprises from about 0.3 to about 0.6 percent by weight of the first detergent derived from the alkyl phenol or sulfurized alkyl phenol based on a total weight of the lubricant composition.

5. A method for reducing engine deposits as determined by a IIIG engine test comprising:
formulating a lubricant composition comprising from 50 wt. % to 95 wt. % of a Group II base oil of lubricating viscosity based on a total weight of the lubricant composition, and an effective amount of synergistic additive comprising (i) one or more zinc dialkyldithiophosphates having more than 75 mole percent of alkyl groups derived from 4-methyl-2-pentanol, and (ii) from about 0.1 to 1.0 weight percent of a first metal-containing detergent derived from an alkyl phenol or sulfurized alkyl phenol, based on a total weight of the lubricant composition, wherein the lubricant composition has a total a total base number (TBN) of 6.5 to 10.0, and wherein the effective amount is an amount sufficient to pass a IIIG engine test; and
operating an engine on the lubricant composition.

6. The method of claim 5 , wherein the engine comprises an internal combustion engine.

7. The method of claim 5 , wherein the one or more zinc dialkyldithiophosphates have 100 mole percent of the alkyl groups derived from 4-methyl-2-pentanol.

8. The method of claim 5 , wherein the one or more zinc dialkyldithiophosphates are present in the lubricant composition in an amount to provide from about 0.01 to about 0.10 percent by weight phosphorus based on a total weight of the lubricant composition.

9. The method of claim 5 , wherein the lubricant composition comprises from about 0.3 to about 0.6 percent by weight of the first metal-containing detergent derived from the alkyl phenol or sulfurized alkyl phenol based on a total weight of the lubricant composition.

10. A synergistic additive package for a lubricating oil composition comprising:
(i) one or more zinc dialkyldithiophosphates having more than 75 mole percent of alkyl groups derived from 4-methyl-2-pentanol in an amount sufficient to provide 0.01 to about 0.1 percent by weight phosphorus to a fully formulated lubricant composition; and
(ii) a metal-containing detergent derived from an alkyl phenol or sulfurized alkyl phenol, wherein a weight ratio of (i) to (ii) in the additive package ranges from 0.1:1 to 12:1;
(iii) an overbased alkali or alkaline earth metal sulfonate detergent in an amount sufficient to provide from about 0.2 to about 2.0 weight percent of overbased alkali or alkaline earth metal sulfonate to a fully formulated lubricant composition, based on a total weight of the fully formulated lubricant composition,

wherein the amount of overbased sulfonate detergent is sufficient to provide the fully formulated lubricant composition with a total base number (TBN) of 6.5 to 8.5.

11. The additive package of claim 10 , wherein the one or more zinc dialkyldithiophosphates have 100 mole percent of alkyl groups derived from 4-methy-2-pentanol.

12. The additive package of claim 10 , wherein a weight ratio of (i) to (ii) in the additive package ranges from about 2.0:1 to about 3:1.

Assignees

• Griffin Paul G
• Styer Jeremy P
• Afton Chemical Corp

Inventors

• Griffin Paul G
• Styer Jeremy P

Classifications

• C10M2201/085

  Phosphorus oxides, acids or salts · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title

• C10M2223/045

  Metal containing thio derivatives · CPC title