Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines
US-10119093-B2 · Nov 6, 2018 · US
US9534185B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9534185-B2 |
| Application number | US-201313852324-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 28, 2013 |
| Priority date | Mar 29, 2012 |
| Publication date | Jan 3, 2017 |
| Grant date | Jan 3, 2017 |
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Trunk piston marine engine lubrication, when the engine is fueled by heavy fuel oil, is effected by a composition of TBN in the range of 20 to 60 comprising a major amount of an oil of lubricating viscosity containing 50 mass % or more of a Group 1 basestock, and respective minor amounts of a calcium alkyl salicylate detergent system providing 40 to 90 mmol of calcium alkyl salicylate per kg of the composition, and 1 to 7 mass %, based on the mass of the composition, of an oil-soluble polyalkenyl-substituted carboxylic acid anhydride, wherein the or at least one polyalkenyl group is derived from a polyalkene having a number average molecular weight of from 200 to 3,000. Asphaltene precipitation in the lubricant, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.
Opening claim text (preview).
What is claimed is: 1. A trunk piston marine engine lubricating oil composition having a TBN in the range of 20 to 60 mg KOH/g, for improving asphaltene handling in use thereof, in operation of the engine when fuelled by a heavy fuel oil, which composition comprises or is made by admixing an oil of lubricating viscosity, in a major amount, containing 50 mass % or more of a Group I basestock, and in respective minor amounts: (A) a calcium alkyl salicylate detergent system providing 40 to 90 mmol of calcium alkyl salicylate per kg of the composition, as determined by titration; and (B) 1 to 7 mass % active ingredient, based on the mass of the composition, of a polyalkenyl-substituted succinic acid or succinic anhydride, wherein the polyalkenyl group is derived from a polyalkene having a number average molecular weight of from 350 to 950. 2. The composition as claimed in claim 1 wherein the oil of lubricating viscosity contains more than 60 mass % of a Group I basestock. 3. The composition as claimed in claim 1 where (B) is a polyisobutene succinic acid or anhydride. 4. The composition as claimed in claim 1 wherein at least one calcium alkyl salicylate detergent of (A) is C 9 to C 30 alkyl-substituted. 5. The composition as claimed in claim 1 with a heavy fuel oil content. 6. A method of operating a trunk piston medium-speed compression-ignited marine engine comprising (i) fuelling the engine with a heavy fuel oil; and (ii) lubricating the crankcase of the engine with a composition as claimed in claim 1 . 7. A method of dispersing asphaltenes in a trunk piston marine lubricating oil composition during its lubrication of surfaces of the combustion chamber of a medium-speed compression-ignited marine engine and operation of the engine, which method comprises: (i) providing a composition as claimed in claim 1 ; (ii) providing the composition in the combustion chamber; (iii) providing heavy fuel oil in the combustion chamber; and (iv) combusting the heavy fuel oil in the combustion chamber.
Resistance to extreme temperature · CPC title
Base number [TBN] · CPC title
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Detergent property or dispersant property · CPC title
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