Transition metal dichalcogenide aerogels and methods of preparation and use

Patent metadata

Field	Value
Publication number	US-9725332-B2
Application number	US-201414522577-A
Country	US
Kind code	B2
Filing date	Oct 23, 2014
Priority date	Oct 24, 2013
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

Methods of forming transition metal dichalcogenide aerogels are provided. Some methods include adding at least one solvent to one or more two-dimensional transition metal dichalcogenide sheets to form a transition metal dichalcogenide solution and freeze drying the transition metal dichalcogenide solution to form frozen transition metal dichalcogenide. The methods also include heating the frozen transition metal dichalcogenide to form a transition metal dichalcogenide aerogel.

First claim

The invention claimed is:

1. A method of forming a transition metal dichalcogenide aerogel, the method comprising:
adding a cleaving agent to a transition metal dichalcogenide mixture to form one or more two-dimensional transition metal dichalcogenide sheets;
adding at least one solvent to the one or more two-dimensional transition metal dichalcogenide sheets to form a transition metal dichalcogenide solution;
freeze drying the transition metal dichalcogenide solution to form a frozen transition metal dichalcogenide; and
heating the frozen transition metal dichalcogenide to form the transition metal dichalcogenide aerogel.

2. The method of claim 1 , wherein adding the at least one solvent to the one or more two-dimensional transition metal dichalcogenide sheets comprises adding the at least one solvent to molybdenum disulphide (MoS 2 ), tungsten disulphide (WS 2 ), titanium disulphide (TiS 2 ), tantalum (IV) sulphide (TaS 2 ), zirconium disulphide (ZrS 2 ), bismuth telluride (Bi 2 Te 3 ), bismuth selenide (Bi 2 Se 3 ), titanium nitride chloride (TiNCl), antimony telluride (Sb 2 Te 3 ), melonite (NiTe 2 ), or combinations thereof.

3. The method of claim 1 , wherein adding at least one solvent to the one or more two-dimensional transition metal dichalcogenide sheets comprises adding the at least one solvent to MX 2 , where M is Mo, W, Bi, Sb, Ti, Pt, Nb, Ta, Ni, Zr, Hf, V, Ta, and Pd, and X is S, Se, Te, and NCl.

4. The method of claim 1 , further comprising sonicating the transition metal dichalcogenide solution prior to freeze drying the solution.

5. The method of claim 4 , wherein the sonicating is carried out for about 30 minutes to about 45 minutes, at a power of about 170 Watts (W) and a duty cycle of about 180 s/cycle.

6. The method of claim 1 , wherein adding the at least one solvent comprises adding ethanol, methanol, isopropyl alcohol, or combinations thereof.

7. The method of claim 6 , wherein adding the at least one solvent comprises adding the at least one solvent in a concentration of about 10% to about 15%.

8. The method of claim 1 , wherein heating the frozen transition metal dichalcogenide is carried out in an inert atmosphere at a temperature of about 175° C. to about 250° C. for about 20 minutes to about 45 minutes.

9. The method of claim 1 , wherein freeze drying the transition metal dichalcogenide solution comprises freezing the solution using ice bath and salt, lyophilization, or combinations thereof.

10. The method of claim 1 , further comprising forming the transition metal dichalcogenide mixture by reacting a transition metal dichalcogenide with a cross-linking agent and an activating agent.

11. The method of claim 1 , further comprising adding at least one inorganic oxide to the two-dimensional transition metal dichalcogenide sheets prior to freeze drying the transition metal dichalcogenide solution.

12. The method of claim 11 , wherein adding the at least one inorganic oxide comprises adding boric oxide, barium oxide (BaO), praseodymium oxide (Pr 2 O 3 ), lanthanide oxide (Ln 2 O 3 ), manganese dioxide (MnO 2 ), or combinations thereof.

13. An aerogel made by the method of claim 1 .

Assignees

• Empire Technology Dev Llc

Inventors

• Thevasahayam Arockiadoss

Classifications

• C01P2006/12

  Surface area · CPC title

• C01P2002/20

  Two-dimensional structures · CPC title

• C01P2006/40

  Electric properties · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title

• C01P2004/20

  extending in two dimensions, e.g. plate-like · CPC title