Organic electroluminescence device and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-9722201-B2
Application number	US-201514967548-A
Country	US
Kind code	B2
Filing date	Dec 14, 2015
Priority date	Aug 31, 2001
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

Provided are an organic electroluminescence device capable of enhancing reflectance of an anode, thereby resulting in improved light-emitting efficiency and a method of manufacturing the same. An anode ( 12 ), a thin film layer for hole injection ( 13 ), an insulating layer ( 14 ), an organic layer ( 15 ) including a luminescent layer ( 15 C) and a cathode ( 16 ) including a semi-transparent electrode ( 16 A) are laminated in order on a substrate ( 11 ). The anode ( 12 ) comprises silver which is a metal with high reflectance or an alloy including silver, and the thin film layer for hole injection ( 13 ) comprises chromium oxide or the like. Light generated in the luminescent layer ( 15 C) is multiply reflected between the anode ( 12 ) and the semi-transparent electrode ( 16 A) to be emitted from the cathode ( 16 ). As the reflectance of the anode ( 12 ) is enhanced, the light generated in the luminescent layer ( 15 C) can be efficiently emitted. An alloy comprised in the anode ( 12 ) preferably includes silver, palladium and copper, and a silver content is preferably 50% by mass or over.

First claim

The invention claimed is:

1. An organic electroluminescence device, comprising:
an anode that includes silver, the anode generally extending in a horizontal direction, parallel to a substrate and perpendicular to a thickness direction of the anode;
a first hole injection layer provided over the anode, the first hole injection layer generally extending in the horizontal direction and includes ITO (Indium Tin Oxide);
organic layers including a luminescent layer; and
a cathode provided over the organic layers, wherein
the organic electroluminescence device is configured to emit light generated in the luminescent layer from a side of the cathode,
the cathode extends generally in the horizontal direction in a light emission region,
the cathode includes a first surface that faces the organic layers and a second surface opposite the first surface,
an end portion of the anode and an end portion of the first hole injection layer are covered by an insulating layer, an upper surface of the insulating layer extending along a first angled upward direction between the horizontal direction and the thickness direction of the anode, and the upper surface of the insulating layer has a curved portion,
outer regions of the organic layers and the cathode over the end portion of the anode extend at the curved portion along a second angled upward direction between the horizontal direction and the first angled upward direction, and
in the curved portion over the end portion of the anode, the first surface of the cathode and the second surface of the cathode both extend along the second angled upward direction.

2. The organic electroluminescence device according to claim 1 , wherein the anode includes an alloy including silver, the silver constituting 50% or greater but less than 100% by mass of the alloy.

3. The organic electroluminescence device according to claim 1 , wherein the anode includes 50% by mass or greater of silver.

4. The organic electroluminescence device according to claim 1 , wherein the first hole injection layer is made of a material with a higher work function than that of the anode.

5. The organic electroluminescence device according to claim 1 , wherein the first hole injection layer is disposed directly on an upper surface of the anode.

6. The organic electroluminescence device according to claim 1 , further wherein an insulating layer is formed surrounding the sides of the anode and partially covering end portions of the top surface of the anode.

7. The organic electroluminescence device according to claim 1 , wherein a thickness of the first hole injection layer is from a few nm to a few tens of nm.

8. The organic electroluminescence device according to claim 2 , wherein the anode further includes palladium (Pd).

9. The organic electroluminescence device according to claim 2 , wherein the anode further includes copper (Cu).

10. The organic electroluminescence device according to claim 8 , wherein the anode includes from 0.3% by mass to 1% by mass of palladium (Pd).

11. The organic electroluminescence device according to claim 9 , wherein the anode includes from 0.3% by mass to 1% by mass of copper (Cu).

12. A display device, comprising an organic electroluminescence device, the organic electroluminescence device including:
an anode that includes silver, the anode generally extending in a horizontal direction, parallel to a substrate and perpendicular to a thickness direction of the anode;
an ITO (Indium Tin Oxide) layer provided over the anode, the ITO layer generally extending in the horizontal direction;
organic layers including a luminescent layer; and
a cathode provided over the organic layers, wherein
the organic electroluminescence device is configured to emit light generated in the luminescent layer from a side of the cathode,
the cathode extends generally in the horizontal direction in a light emission region,
the cathode includes a first surface that faces the organic layers and a second surface opposite the first surface,
an end portion of the anode and an end portion the ITO layer are covered by an insulating layer, an upper surface of the insulating layer extending along a first angled upward direction between the horizontal direction and the thickness direction of the anode, and the upper surface of the insulating layer has a curved portion,
outer regions of the organic layers and the cathode over the end portion of the anode extend at the curved portion along a second angled upward direction between the horizontal direction and the first angled upward direction, and
in the curved portion over the end portion of the anode, the first surface of the cathode and the second surface of the cathode both extend along the second angled upward direction.

13. The display device according to claim 12 , wherein the anode includes an alloy including silver, the silver constituting 50% or greater but less than 100% by mass of the alloy.

14. The display device according to claim 12 , wherein the anode includes from 0.3% by mass to 1% by mass of palladium (Pd).

15. The display device according to claim 12 , wherein the anode includes from 0.3% by mass to 1% by mass of copper (Cu).

16. The display device according to claim 12 , wherein the anode includes 50% by mass or greater of silver.

17. The display device according to claim 12 , wherein a work function of the ITO is higher than that of the anode.

18. The display device according to claim 12 , further wherein the ITO layer is disposed directly on an upper surface of the anode.

19. The display device according to claim 12 , further wherein an insulating layer is formed surrounding the sides of the anode and partially covering end portions of the top surface of the anode.

20. The display device according to claim 12 , wherein a thickness of the ITO layer is from a few nm to a few tens of nm.

21. The display device according to claim 12 , wherein a total thickness of the organic layers is dependent on a peak wavelength of a spectrum of light emitted from the luminescent layer.

22. The display device according to claim 12 , wherein the cathode includes silver.

23. The display device according to claim 21 , wherein the cathode comprises a semi-transparent electrode being semi-transparent to light generated in the luminescent layer, and the semi-transparent electrode and the anode constitute a resonant portion in a resonator resonating light generated in the luminescent layer.

24. The display device according to claim 23 , wherein a phase shift of reflected light generated in the anode and the semi-transparent electrode is Φ, an optical distance between the anode and the semi-transparent electrode is L, and the peak wavelength is λ, the optical distance L is a positive minimum value satisfying a mathematical formula:
2 L/λ+Φ/ 2π= q

where q is an integer.

Assignees

• Sony Corp

Inventors

• Hanawa Koji
• Yamada Jiro
• Hirano Takashi

Classifications

• C22C5/08

  with copper as the next major constituent · CPC title

• H01L51/5231

  Electricity · mapped topic

• H01L51/5262

  Electricity · mapped topic

• C22C5/06 Primary

  Alloys based on silver · CPC title

• H01L51/5221

  Electricity · mapped topic