Method for detecting phase change temperatures of molten metal

Patent metadata

Field	Value
Publication number	US-9719976-B2
Application number	US-201514797413-A
Country	US
Kind code	B2
Filing date	Jul 13, 2015
Priority date	Nov 15, 2012
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

A detection device for molten metal is provided. The detection device includes a sample cup having a cavity configured to receive a sample of molten metal and a blob arranged in the cavity. The blob includes a carbide stabilizing element and a hydrogen releasing material including a hydroxide of an alkaline earth metal. The blob is provided for use in detecting phase change temperatures during solidification of a sample of molten cast iron. The blob is also resistant to moisture gain and moisture loss during transport and storage. A method of detecting phase change temperatures of the molten iron or molten cast iron sample using the blob and a method of manufacturing the blob are also provided.

First claim

I claim:

1. A method of detecting phase change temperatures of a sample of molten iron or molten cast iron, the method comprising the steps of:
providing a detection device including a temperature sensor and a sample cup with a cavity configured to receive a sample of molten iron or molten cast iron and allow the sample of molten iron or cast iron to solidify therein in a white structure;
arranging a blob in the cavity, wherein the blob is configured to contact the sample of molten iron or cast iron as it solidifies within the cavity, the blob comprising a tellurium carbide stabilizer and magnesium hydroxide as a hydrogen releasing material;
depositing a sample of molten iron or molten cast iron into the cavity, the blob reacting with the molten iron or molten cast iron sample upon contact therewith, such that hydrogen is released from the magnesium hydroxide into the molten iron or molten cast iron sample and the released hydrogen and tellurium promote the solidification of the molten iron or molten cast iron sample in a white structure; and
allowing the molten iron or molten cast iron sample to solidify while simultaneously measuring phase change temperatures of the solidifying sample.

2. The method according to claim 1 , wherein the blob constitutes 0.35% to 0.45% by weight based on a total weight of a sample of molten metal.

3. The method according to claim 1 , wherein the blob is resistant to changes in its hydration level during transport and storage of the blob.

4. The method according to claim 1 , wherein the blob further comprises a retardant which resists reaction of the blob upon contact with molten metal.

5. The method according to claim 1 , wherein the carbide stabilizer comprises 7% to 37% by weight based on a total weight of the blob.

6. The method according to claim 1 , wherein the blob comprises the tellurium in an amount of 15% to 60% by weight based on a total weight of the blob and the magnesium hydroxide in an amount of 40% to 85% by weight based on the total weight of the blob, the blob being resistant to moisture gain and moisture loss during transport and storage.

7. The method according to claim 1 , wherein the tellurium is present in an amount of 0.05% to 0.10% by weight based on a total weight of a molten iron sample and the magnesium hydroxide is present in an amount of 0.11% to 0.22% by weight based on the total weight of the molten iron sample.

8. The method according to claim 1 , wherein the magnesium hydroxide comprises 15% to 54% by weight based on a total weight of the blob.

9. The method according to claim 1 , wherein the blob further comprises a binder.

10. The method according to claim 9 , wherein the binder is a 3% polyvinyl alcohol-water solution.

11. The method according to claim 10 , wherein the 3% polyvinyl alcohol-water solution comprises 1% to 4% by weight based on a total weight of the blob.

12. A method of manufacturing a blob for use in detecting phase change temperatures of a sample of molten metal, the method comprising:
forming a fluid blob mixture comprising a tellurium carbide stabilizer and magnesium hydroxide as a hydrogen releasing material;
providing a detection device including a sample cup with a cavity configured to receive a sample of molten metal;
depositing the fluid blob mixture into the cavity; and
drying the fluid blob mixture to form a blob, the blob being configured to react with the molten metal sample upon contact therewith, such that hydrogen is released from the magnesium hydroxide into the molten metal sample and the released hydrogen and tellurium promote solidification of the molten metal sample in a white structure.

13. The method of claim 12 , wherein the carbide stabilizer comprises 5% to 25% by weight based on a total weight of the fluid blob mixture and comprises 7% to 37% by weight based on a total weight of the blob.

14. The method of claim 12 , wherein the magnesium hydroxide comprises 10% to 37% by weight based on a total weight of the fluid blob mixture and comprises 15% to 54% by weight based on a total weight of the blob.

Assignees

• Heraeus Electro Nite Int

Inventors

• Black Jason

Classifications

• B01L3/04

  Crucibles · CPC title

• G01N1/125

  adapted for sampling molten metals · CPC title

• B01L2200/16

  Reagents, handling or storing thereof · CPC title

• G01N33/206 Primary

  Physics · mapped topic

• G01N25/04

  of melting point; of freezing point; of softening point · CPC title