Mechanoluminescent devices, articles, and methods
US-11486774-B2 · Nov 1, 2022 · US
US9719012B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9719012-B2 |
| Application number | US-72978810-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 23, 2010 |
| Priority date | Feb 1, 2010 |
| Publication date | Aug 1, 2017 |
| Grant date | Aug 1, 2017 |
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A tube lamp has a tubular portion that serves both as a light guide for energy from a solid state source and as a container for a material bearing a nanophosphor that is pumped by the energy from the source as the energy traverses the light guide. However, the tubular portion of the light guide also allows emission of light produced by the phosphor when excited. The material with the nanophosphor dispersed therein may appear either clear or translucent when the lamp is off and the nanophosphor is not excited by energy from the source.
Opening claim text (preview).
What is claimed is: 1. A tubular lamp for producing visible light, comprising: a solid state source for producing electromagnetic energy, the solid state source comprising a semiconductor chip and an enclosure about the semiconductor chip; a tubular container positioned outside the enclosure, the tubular container formed of optically transmissive material having an interior volume, the tubular container having a first end section with an external surface coupled to receive electromagnetic energy from the solid state source, a second end section opposite the first end section, and an elongated tubular longitudinal section between the first and second end sections, wherein the elongated tubular longitudinal section is configured to act as a light guide with respect to the electromagnetic energy received from the solid state source; a reflector at the second end section of the tubular container, configured to longitudinally reflect electromagnetic energy from the solid state source back through the light guide of the elongated tubular longitudinal section; a reflector at the first end section of the tubular container, configured to longitudinally reflect at least some electromagnetic energy back through the light guide of the elongated tubular longitudinal section; a bearer material at least substantially filling an interior volume of the tubular container; and a plurality of doped semiconductor nanophosphors dispersed in the bearer material in the container, the tubular container and bearer material being configured to provide deployment of the doped semiconductor nanophosphors outside the enclosure of the solid state source and remotely from the semiconductor chip of the solid state source, each doped semiconductor nanophosphor being of a type excited in response to the electromagnetic energy received from the solid state source for re-emitting visible light, wherein the longitudinal section of the tubular container is also configured to allow lateral emission of light produced by excitation of the doped semiconductor nanophosphors when excited by the electromagnetic energy received from the solid state source, and wherein: (a) the visible light output produced by excitation of the doped semiconductor nanophosphors is at least substantially white; (b) the visible light output produced by excitation of the doped semiconductor nanophosphors has a color rendering index (CRI) of 75 or higher; and (c) the visible light output produced by excitation of the doped semiconductor nanophosphors has a color temperature in one of the following ranges: 2,725±145° Kelvin; 3,045±175° Kelvin; 3,465±245° Kelvin; and 3,985±275° Kelvin. 2. The tubular lamp of claim 1 , each of the doped semiconductor nanophosphors in the plurality being of a type excited in response to the electromagnetic energy from the solid state source for re-emitting visible light of a different spectrum having substantially no overlap with absorption spectra of the doped semiconductor nanophosphors, the doped semiconductor nanophosphors together producing a visible light output for the tubular lamp through the longitudinal section when excited by the electromagnetic energy received from the solid state source. 3. The tubular lamp of claim 1 , wherein the bearer material is selected from either a gas or a liquid and fills the interior volume of the tubular container in its gas or liquid state. 4. The tubular lamp of claim 1 , wherein the bearer material with the one or more semiconductor nanophosphors dispersed therein appears at least substantially clear when the solid state source is off. 5. The tubular lamp of claim 1 , wherein the bearer material with the one or more semiconductor nanophosphors dispersed therein appears at least substantially translucent when the solid state source is off. 6. The tubular lamp of claim 1 , wherein the solid state source has an emission rating wavelength A in the range of around 460 nm and below (λ≦460 nm). 7. The tubular lamp of claim 1 , wherein: the solid state source comprises a plurality of light emitting diodes (LEDs), and the tubular lamp further comprises an index matching gel between the LEDs and a surface of the tubular container for optically coupling electromagnetic energy from the LEDs into the container. 8. The tubular lamp of claim 1 in combination with circuitry for driving the solid state source, wherein: the circuitry is configured for driving the solid state source in response to alternating current electricity, or the circuitry is configured for converting alternating current electricity to direct current electricity and driving the solid state source with the direct current electricity. 9. The tubular lamp of claim 1 , wherein the tubular container comprises: an inner surface of the longitudinal section configured to provide total internal reflection with respect to electromagnetic energy from the solid state source and to allow the emission of light produced by excitation of the one or more doped semiconductor nanophosphors. 10. The tubular lamp of claim 1 , wherein the tubular container comprises: a partially transmissive partially reflective reflector on an inner surface of the longitudinal section configured to provide reflection with respect to electromagnetic energy from the solid state source and to allow the emission of light produced by excitation of the one or more doped semiconductor nanophosphors. 11. The tubular lamp of claim 1 , wherein each doped semiconductor nanophosphor includes nanocrystals formed of semiconductor materials which are doped with an impurity. 12. The tubular lamp of claim 1 , wherein the elongated tubular longitudinal section of the container is generally cylindrical. 13. The tubular lamp of claim 1 , wherein the elongated tubular longitudinal section of the container has a lateral cross section that is at least substantially circular. 14. The tubular lamp of claim 2 , wherein one or more of the doped semiconductor nanophosphors comprises zinc selenide quantum dots doped with manganese or copper. 15. The tubular lamp of claim 3 , wherein the bearer material is the gas and the gas comprises one gas or a combination of gases each selected from the group consisting of: hydrogen gas, inert gases and hydrocarbon based gases. 16. The tubular lamp of claim 3 , wherein each doped semiconductor nanophosphor includes nanocrystals formed of semiconductor materials which are doped with an impurity. 17. The tubular lamp of claim 5 , wherein the solid state source is a near ultraviolet (UV) solid state source for producing near UV electromagnetic energy in a range of 380-420 nm. 18. The tubular lamp of claim 6 , wherein the solid state source comprises a plurality of light emitting diodes (LEDs) each for emitting near UV electromagnetic energy in a range of 380-420 nm. 19. The tubular lamp of claim 17 , wherein each LED has an emission rating wavelength A around 405 nm. 20. A tubular lamp for producing visible white light, comprising: a solid state source for producing electromagnetic energy, the solid state source comprising a semiconductor chip and an enclosure about the semiconductor chip; a tubular container positioned outside the enclosure, the tubular container formed of optically transmissive material having an interior volume, the tubular container having a first end section with an external surface coupled to receive electromagnetic energy from the solid state source, a second end section opposite the first end section, and an elongated tubular longitudinal
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