Pyrolytic binder

Patent metadata

Field	Value
Publication number	US-10640643-B2
Application number	US-201716089839-A
Country	US
Kind code	B2
Filing date	Mar 23, 2017
Priority date	Apr 1, 2016
Publication date	May 5, 2020
Grant date	May 5, 2020

Abstract

The present invention provides a thermally decomposable binder for which dewaxing can be performed at low temperatures, and an inorganic fine particle-dispersed paste composition comprising this binder. Specifically, the present invention provides a thermally decomposable binder comprising an aliphatic polycarbonate resin comprising a constituent unit represented by formula (1):

wherein R 1 , R 2 , and R 3 are identical or different, and each represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, or an aryl group having 6 to 20 carbon atoms, and n is 1 or 2, and provides an inorganic fine particle-dispersed paste composition comprising this binder.

First claim

The invention claimed is:

1. A thermally decomposable binder comprising an aliphatic polycarbonate resin comprising a constituent unit represented by formula (1):

wherein
R 1 , R 2 , and R 3 are identical or different, and each represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, and
n is 1 or 2.

2. The thermally decomposable binder according to claim 1 , wherein the content of the constituent unit represented by formula (1) is 0.001 to 30 mol %, based on the entire constituent units constituting the aliphatic polycarbonate resin.

3. The thermally decomposable binder according to claim 1 or 2 , wherein the aliphatic polycarbonate resin further comprises a constituent unit represented by formula (2):

wherein
R 4 , R 5 , and R 6 are identical or different, and each represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, wherein two groups from among R 4 to R 6 , taken together with the carbon atom or carbon atoms to which these groups are attached, may form a substituted or unsubstituted, saturated or unsaturated aliphatic ring, and
X represents a hydrogen atom, a linear or branched alkyl group having 1 to 10 carbon atoms, a haloalkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, an ether bond-containing group, an ester bond-containing group, or an allyl group.

4. The thermally decomposable binder according to claim 1 , having a mass loss percentage of 90% or more after being maintained at 160° C. for 1 hour in a thermogravimetric analysis measurement.

5. An inorganic fine particle-dispersed paste composition comprising:
an aliphatic polycarbonate resin comprising a constituent unit represented by formula (1):

wherein
R 1 , R 2 , and R 3 are identical or different, and each represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, and
n is 1 or 2;
inorganic fine particles; and
a solvent.

6. The inorganic fine particle-dispersed paste composition according to claim 5 , wherein the aliphatic polycarbonate resin is present in an amount of 0.001 to 20 parts by mass, based on 100 parts by mass of the inorganic fine particles.

7. The inorganic fine particle-dispersed paste composition according to claim 5 or 6 , wherein the inorganic fine particles comprise at least one member selected from the group consisting of electroconductive particles, ceramic powders, glass powders, and inorganic phosphor fine particles.

Assignees

• National Univ Corporation Tokyo Univ Of Agriculture And Technology
• Sumitomo Seika Chemicals

Inventors

• Nakano Koji
• Nishioka Kiyoshi

Classifications

• C09K11/778

  Borates · CPC title

• C08K3/00

  Use of inorganic substances as compounding ingredients · CPC title

• C08K2201/001

  Conductive additives · CPC title

• C08K3/013

  Fillers, pigments or reinforcing additives · CPC title

• C08G64/02 Primary

  Aliphatic polycarbonates · CPC title