Catalyst components for the polymerization of olefins

Patent metadata

Field	Value
Publication number	US-9714303-B2
Application number	US-201414891632-A
Country	US
Kind code	B2
Filing date	May 13, 2014
Priority date	May 14, 2013
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.

First claim

What is claimed is:

1. A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound wherein the solid catalyst component is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from derivatives of formula (I):

where X is selected from R 1 , —OR and —NR 2 , Y is selected from hydrogen, R 1 , —COR 1 , —CONR 2 , and —MZ( n−1 ); the R groups, equal to or different from each other, are selected from hydrogen, halogen and C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles and at least one of the R groups is different from hydrogen and selected from halogen or C 1 -C 15 hydrocarbon groups; M is an element belonging to Groups 2 or 4-13 of the Periodic Table of Elements; n is the valence of M; Z is halogen or OR 1 and the R 1 group is a C 1 -C 15 aliphatic or aromatic hydrocarbon group; with the proviso that when X is a substituted or unsubstituted phenyl group, and Y is a substituted or unsubstituted benzoyl group, at least one of the R groups on the phenyl rings of the structure of formula (I) is not hydrogen.

2. The catalyst component of claim 1 , in which at least two of the R groups are different from hydrogen.

3. The catalyst component of claim 2 , in which at least 3 of the R groups are different from hydrogen.

4. The catalyst component of claim 1 , in which the two phenyl rings of formula (I) have the same substitution pattern.

5. The catalyst component of claim 4 , in which the R groups are selected from C 1 -C 10 alkyl groups.

6. The catalyst component of claim 1 , in which the R 1 groups are selected from C 1 -C 10 alkyl groups, C 6 -C 15 aryl groups and alkylaryl groups.

7. The catalyst component of claim 1 , in which R radicals in the —NR 2 and —CONR 2 groups are selected from C 1 -C 10 alkyl groups.

8. The catalyst component of claim 1 , in which X is R 1 and Y is selected from hydrogen, R 1 , —COR 1 , and —CONR 2 .

9. The catalyst component of claim 1 , in which Y is selected from —COR 1 and —CONR 2 .

10. The solid catalyst component of claim 8 , in which X is a C 6 -C 15 aryl or alkylaryl group and Y is methyl.

11. The solid catalyst component of claim 1 , in which X is —NR 2 and Y is selected from hydrogen and —COR 1 .

12. The solid catalyst component of claim 11 , in which R 1 is a C 6 -C 15 aryl or alkylaryl group and R is a linear C 1 -C 5 alkyl group.

13. A catalyst for the polymerization of olefins comprising the product of the reaction between:
(i) the solid catalyst component according to claim 1 and
(ii) an alkylaluminum compound and optionally,
(iii) an external electron donor compound.

14. A process for the (co)polymerization of olefins of the formula CH 2 ═CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, carried out in the presence of a catalyst system comprising the product of the reaction between:
i. the solid catalyst component according to claim 1 ;
ii. an alkylaluminum compound; and
iii. optionally an external donor compound;
wherein the catalyst system is contacted with olefins of the formula CH 2 ═CHR under conditions capable of polymerizing the olefins.

Assignees

• Basell Polyolefine Italia S R L
• Basell Poliolefine Italia Srl

Inventors

• Mignogna Alessandro
• Chevalier Reynald
• Guidotti Simona
• Liguori Dario
• Morini Giampiero
• Schneider Martin

Classifications

• C07C271/44 Primary

  to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals · CPC title

• C07C2601/14

  The ring being saturated · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C07C2602/08

  the other ring being five-membered, e.g. indane · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title