Catalyst components for the polymerization of olefins

Patent metadata

Field	Value
Publication number	US-10113013-B2
Application number	US-201515128830-A
Country	US
Kind code	B2
Filing date	Mar 24, 2015
Priority date	Mar 26, 2014
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

The present disclosure relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the formula (I):

where each Q is a group —COOR 1 , in which R 1 is selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N and O; or a group —CON(R 2 ) 2 , in which R 2 groups, equal to or different from each other, are hydrogen or R 1 groups which can be fused together to form one or more cycles, and A is a bivalent bridging group with the proviso that the Q groups cannot be simultaneously a group —COOR 1 or —CON(R 2 ) 2 .

First claim

What is claimed is:

1. A solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the formula (I):

where each Q is a group —COOR 1 in which R 1 is selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of a halogen, P, S, N, and O; or a group —CON(R 2 ) 2 in which R 2 groups, equal to or different from each other, are selected from hydrogen or R 1 groups which are optionally fused together to form one or more cycles; and A is a bivalent bridging group with the proviso that the Q groups cannot be simultaneously a group —COOR 1 or —CON(R 2 ) 2 .

2. The catalyst component of claim 1 , wherein A is a bivalent bridging group with a chain length between the two free radicals of 1-10 atoms.

3. The catalyst component of claim 1 , wherein the bridging group has the formula —(ZR 3 m ) n — in which, independently, Z is selected from the group consisting of C, Si, Ge, O, N, S and P, the R 3 groups, equal to or different from each other, are hydrogen or C 1 -C 20 hydrocarbon radicals, optionally containing a heteroatom selected from the group consisting of halogen, P, S, N, O and Si, which are optionally fused together to form one or more cycles, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10.

4. The catalyst component of claim 3 , wherein the bridging group contains an aromatic group, wherein at least two carbon atoms of the aromatic are covalently bonded to the two oxygen atoms of formula (I).

5. The catalyst component of claim 4 , wherein the bridging group is selected from phenyl groups, optionally substituted with halogens or C 1 -C 20 alkyl radicals, bridging the oxygen atoms in position 1,2 or 1,3 or 1,4 and from naphthalene groups, optionally substituted by bridging the oxygen groups in position 1,2 or 2,3 or 1,8.

6. The catalyst component of claim 1 , wherein the donor is selected from the compounds of formula (II)

in which Q is defined as in claim 1 , and R 5 , independently, is selected from the group consisting of hydrogen, the halogens and C 1 -C 15 hydrocarbon groups, optionally substituted with heteroatoms selected from the group consisting of the halogens, P, S, N, O and Si, with the proviso that at least one of R 5 is different from hydrogen.

7. The catalyst component of claim 6 , wherein at least two of the R 5 groups are different from hydrogen.

8. The catalyst component of claim 7 , wherein the aromatic ring of formula (II) is substituted in position 3,5 with R 5 groups selected from C 1 -C 5 alkyl groups.

9. The catalyst component of claim 1 , wherein the R 1 and R 2 groups are independently selected from C 1 -C 15 alkyl groups, C 6 -C 14 aryl groups, C 3 -C 15 cycloalkyl groups, and C 7 -C 15 arylalkyl or alkylaryl groups; with the proviso that the R 2 groups can also be hydrogen.

10. The catalyst component of claim 6 , wherein the donor is selected from the compounds of formula (III):

wherein Q is defined as in claim 1 , and R 5 is a branched alkyl group.

11. The catalyst component of claim 10 , wherein R 1 and R 2 are C 1 -C 5 alkyl groups, and R 5 is a t-butyl group.

12. A catalyst for the polymerization of olefins comprising the product of the reaction between:
(i) the solid catalyst component of claim 1 ,
(ii) an alkylaluminum compound and,
(iii) optionally, an external electron donor compound.

13. The catalyst of claim 12 , further comprising an external electron donor compound.

14. The catalyst of claim 13 , wherein the external donor is selected from silicon compounds of the formula (R 7 ) a (R 8 ) b Si(OR 9 ) c , where a and b are integers from 0 to 2, c is an integer from 1 to 4, the sum (a+b+c) is 4 and R 7 , R 8 , and R 9 are radicals with 1-18 carbon atoms optionally containing heteroatoms.

15. A process comprising the step of polymerizing one or more olefins of the formula CH 2 ═CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, in the presence of a catalyst system comprising the product of the reaction between:
i. the solid catalyst component according to claim 1 ;
ii. an alkylaluminum compound and,
iii. optionally, an external donor compound.

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Mignogna Alessandro
• Morini Giampiero

Classifications

• C08F10/14

  Monomers containing five or more carbon atoms · CPC title

• C08L2207/10

  Peculiar tacticity · CPC title

• C08F4/022

  Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts · CPC title

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• C08L57/00

  Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title