Compositions for joining and assembling parts made of SiC-based materials

Patent metadata

Field	Value
Publication number	US-9713860-B2
Application number	US-201414201487-A
Country	US
Kind code	B2
Filing date	Mar 7, 2014
Priority date	Mar 16, 2010
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

A method for joining, assembling, at least two parts made of silicon carbide-based materials by non-reactive brazing is provided. According to the method, the parts are contacted with a non-reactive brazing composition, the assembly formed by the parts and the brazing composition is heated to a brazing temperature sufficient to melt the brazing composition totally or at least partly, and the parts and brazing composition are cooled to that, after solidification of the brazing composition, a moderately refractory joint is formed; wherein the non-reactive brazing composition is an alloy comprising, in atomic percentages, 45% to 65% silicon, 28% to 45% nickel and 5% to 15% aluminum. A brazing composition as defined above is provided. A brazing paste, suspension comprising a powder of said brazing composition and an organic binder as well as a joint and assembly obtained the foregoing method are also provided.

First claim

What is claimed is:

1. A refractory joint joining parts comprising silicon carbide-based materials and formed by non-reactive brazing of a non-reactive brazing composition which is a ternary alloy consisting of, in atomic percentages, 45% to 65% silicon, 28% to 45% nickel and 5% to 15% aluminium, the joint having substantially the same composition as the non-reactive brazing composition.

2. The refractory joint according to claim 1 , wherein said non-reactive brazing composition consists of, in atomic percentages, 55% to 60% silicon, 30% to 34% nickel and 9% to 11% aluminium.

3. The refractory joint according to claim 1 , wherein said non-reactive brazing composition consists of, in atomic percentages, 57.5±1% silicon, 32.5±1% nickel and 10±0.5% aluminium.

4. The refractory joint according to claim 1 , wherein the refractory joint further comprises a reinforcement.

5. The refractory joint according to claim 4 , wherein the reinforcement comprises ceramics.

6. The refractory joint according to claim 4 , wherein the reinforcement is in form of particles, of fibres, of a non-woven fabric of fibres, of a woven fabric of fibres, of a felt, or of a foam.

7. The refractory joint according to claim 4 , wherein the reinforcement is at most 50% by volume relative to a total volume of the non-reactive brazing composition.

8. The refractory joint according to claim 1 , wherein said refractory joint is capable of withstanding a temperature up to 980° C.

9. The refractory joint according to claim 1 , wherein the refractory joint is formed by capillary brazing of the non-reactive brazing composition and therefore substantially fills pores present on the parts.

10. An assembly comprising:
at least two parts comprising silicon carbide-based materials; and
the refractory joint according to claim 1 joining said at least two parts.

11. The assembly according to claim 10 , wherein the silicon carbide-based materials are selected from the group consisting of pure silicon carbide and composite SiC-based materials.

12. The assembly according to claim 10 , wherein the silicon carbide-based materials are selected from the group consisting of sintered pressureless silicon carbide (“PLS SiC”), Si infiltrated silicon carbide (“SiSiC” or “RBSC”), porous recrystallized silicon carbide (“RSiC”), graphite silicon (“C SiC”) composed of graphite coated with a SiC layer, SiC/SiC composites, SiC/SiC composites with self-healing matrix, C/SiC composites, SiC monocrystals, and SiC composites with another ceramic.

13. The assembly according to claim 10 , wherein the silicon carbide-based materials comprise a silicon carbide content of at least 50% by mass relative to a total mass of the silicon carbide-based materials.

14. The assembly according to claim 10 , wherein said non-reactive brazing composition consists of, in atomic percentages, 55% to 60% silicon, 30% to 34% nickel and 9% to 11% aluminium.

15. The assembly according to claim 10 , wherein said brazing composition consists of, in atomic percentages, 57.5±1% silicon, 32.5±1% nickel and 10±0.5% aluminium.

16. The assembly according to claim 10 , wherein the assembly further comprises a reinforcement.

17. The assembly according to claim 16 , wherein the reinforcement comprises ceramics.

18. The assembly according to claim 16 , wherein the reinforcement is in form of particles, of fibres, of a non-woven fabric of fibres, of a woven fabric of fibres, of a felt, or of a foam.

19. The assembly according to claim 16 , wherein the reinforcement is at most 50% by volume relative to a total volume of the non-reactive brazing composition.

20. The refractory joint according to claim 1 , wherein said refractory joint comprises, in atomic percentages, 55% to 60% silicon, 30% to 34% nickel and 9% to 11% aluminium.

21. The refractory joint according to claim 1 , wherein said refractory joint comprises, in atomic percentages, 57.5±1% silicon, 32.5±1% nickel and 10±0.5% aluminium.

22. The assembly according to claim 10 , wherein said refractory joint comprises, in atomic percentages, 55% to 60% silicon, 30% to 34% nickel and 9% to 11% aluminium.

23. The assembly according to claim 10 , wherein said refractory joint comprises, in atomic percentages, 57.5±1% silicon, 32.5±1% nickel and 10±0.5% aluminium.

24. An assembly comprising at least two substrates made of silicon carbide-based material and a the non-reactive brazing composition which is a ternary alloy consisting of, in atomic percentages, 45% to 65% silicon, 28% to 45% nickel and 5% to 15% aluminium, wherein the at least two substrates respectively comprises silicon carbide by at least 50% relative to total amount of the substrate by mass.

25. The assembly of claim 24 , wherein the at least two substrates respectively comprises silicon carbide by at least 80% relative to total amount of the substrate by mass.

26. The assembly of claim 24 , wherein the non-reactive brazing composition consists of, in atomic percentages, 55% to 60% silicon, 30% to 34% nickel and 9% to 11% aluminium.

27. A method of producing an assembly comprising at least two substrates made of silicon carbide-based material and a non-reactive brazing composition which is a ternary alloy consisting of, in atomic percentages, 45% to 65% silicon, 28% to 45% nickel and 5% to 15% aluminium comprising,
heating the assembly at temperature of 1150° C. or lower, and
forming a refractory joint between the two substrates by cooling the assembly.

28. The method of producing the assembly of claim 27 , further comprising;
disposing the non-reactive brazing composition between the two substrates before heating the assembly.

29. The method of producing the assembly of claim 27 , wherein the temperature of heating the assembly is in a range from 1040 to 1150° C.

30. The method of producing the assembly of claim 27 , wherein the temperature of heating the assembly is in a range from 1080 to 1100° C.

31. The method of producing the assembly of claim 27 , wherein time period of the heating is from 30 to 150 minutes.

32. The method of producing the assembly of claim 27 , further comprising;
heating the assembly at temperature of 950 to 1000° C. before heating the assembly at temperature of 1150° C. or lower.

33. The method of producing the assembly of claim 32 , wherein time period of the heating at temperature of 950 to 1000° C. is from 30 to 180 minutes.

34. The method of producing the assembly of claim 27 , wherein the substrate comprises silicon carbide by at least 50% relative to total amount of the substrate by mass.

35. The method of producing the assembly of claim 27 , wherein the substrate comprises silicon carbide by at least 80% relative to total amount of the substrate by mass.

36. The refractory joint joining parts of claim 1 , wherein a temperature for brazing the non-reactive brazing composition is equal to or lower than 1150° C.

37. The assembly of claim 10 , wherein a temperature for brazing the non-reactive brazing composition is equal to or lower than 1150° C.

38. The assembly of claim 24 , wherein a temperature for brazing the non-reactive brazing composition is equal to or lower than 1150° C.

Assignees

• Commissariat Energie Atomique

Inventors

• Chaumat Valérie
• Henne Jean-Francois
• Miloud-Ali Nadia

Classifications

• C04B2237/38

  Fiber or whisker reinforced · CPC title

• C04B37/006

  consisting of metals or metal salts · CPC title

• B23K35/36 Primary

  Selection of non-metallic compositions, e.g. coatings or fluxes (B23K35/34 takes precedence); Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest · CPC title

• B23K35/02

  characterised by mechanical features, e.g. shape · CPC title

• C04B2235/3826

  Silicon carbides · CPC title