Separation membrane including graphene

Patent metadata

Field	Value
Publication number	US-9713794-B2
Application number	US-201213443489-A
Country	US
Kind code	B2
Filing date	Apr 10, 2012
Priority date	Apr 11, 2011
Publication date	Jul 25, 2017
Grant date	Jul 25, 2017

Abstract

According to example embodiments, a separation membrane includes a graphene on at least one surface of a polymer support. The graphene may include a plurality of grains defined by grain boundaries.

First claim

What is claimed is:

1. A separation membrane comprising:
a polymer support; and
at least one graphene monolayer on at least one surface of the polymer support, the graphene monolayer being 2-dimensional and planar-structured,
wherein the graphene monolayer includes a plurality of grains defined by grain boundaries,
the grain boundaries provide gaps present along the grain boundaries between the grains in the graphene monolayer, and
the gaps between the grains in the graphene are configured to pass a target substance to separate the target substance from a mixture containing the target substance,
wherein the at least one graphene monolayer on the polymer support has a first fluid permeability in a range of about 400 Barrer to about 1200 Barrer, and
wherein the at least one graphene monolayer on the polymer support has an first fluid/second fluid selectivity of at least about 1.5.

2. The separation membrane of claim 1 , wherein the separation membrane has a multi-layer structure including at least two graphene monolayers.

3. The separation membrane of claim 1 , further comprising:
a sheet connected to at least one of the polymer support and the graphene, the sheet including at least one of,
a transition metal dichalcogenide (MY 2 ),
a transition metal phosphorus trisulfide (MPY 3 ),

a transition metal oxyhalide (MOX),
(MCl)LaNb 2 O 7 ,
one of BCN, B 2 CN, BC 6 N, layered silicate, mica, talc, Al 2 Si 2 O 5 (OH) 4 , layered titanate (TiO x , x<2), α-Zr(HPO 4 ) 2 H 2 O, γ-FeO(OH), and Al(OH) 3 , and
a transition metal dihalide (MX 2 ), wherein
M indicates at least one transition metal,
Y indicates one of S and Se, and
X indicates a halogen.

4. The separation membrane of claim 3 , wherein
the transition metal dichalcogenide (MY 2 ) includes at least one of TiS 2 , TiSe 2 , NbS 2 , NbSe 2 , TaS 2 , TaSe 2 ,
the transition metal phosphorus trisulfide (MPY 3 ) includes FePS 3 , and
the transition metal dihalide (MX 2 ) includes one of CuBr 2 , CdBr 2 , CdI 2 , and CuCl 2 .

5. The separation membrane of claim 1 , wherein the polymer support includes one of a dense membrane structure and a microporous structure.

6. The separation membrane of claim 1 , wherein the polymer support includes at least one of polysulfone, polyethersulfone, polyimide, polyamide, polyetherimide, polyacrylonitrile, poly(methyl methacrylate), cellulose acetate, polyethylene, polycarbonate, polytetrafluoroethylene, polypropylene, and polyvinylidene fluoride.

7. A sea-water desalination apparatus including the separation membrane according to claim 1 , wherein
the graphene monolayer includes pores defined by grain boundaries, and at least one of a width of the pores in the graphene monolayer and a width the gaps present along the grain boundaries between the grains in the graphene monolayer allows selective passage of water molecules and blocks hydrated salt ions from a solution containing the water molecules and the hydrated salt ions.

8. A gas separation apparatus including the separation membrane according to claim 1 .

9. The separation membrane of claim 1 , further comprising:
at least one of channels and pores defined by the plurality of grains, wherein
the at least one of channel and pores are through the grains.

10. The separation membrane of claim 9 , wherein
the graphene monolayer has molecular defects therein, and
the molecular defects provide pores dimensioned to allow target ions, liquids, or gases to pass through the graphene monolayer.

11. The separation membrane of claim 9 , wherein the pores have a width of about 0.335 nm to about 100 nm.

12. The separation membrane of claim 9 , wherein
a width of the at least one of pores and channels in the graphene monoloayer allows selective separation of a first gas from a gas mixture containing at least the first gas and a second gas,
the first gas is one of hydrogen and nitrogen, and
the second gas is oxygen.

13. A separation membrane comprising:
a polymer support; and
at least one graphene monolayer on the polymer support, the graphene monolayer having at least one of pores and channels defined by grain boundaries,
wherein the at least one of pores and channels are present along the grain boundaries, and the at least one of pores and channels are configured to pass a target substance to separate the target substance from a mixture containing the target substance,
wherein the at least one graphene monolayer on the polymer support has a first fluid permeability in a range of about 400 Barrer to about 1200 Barrer, and
wherein the at least one graphene monolayer on the polymer support has a first fluid/second fluid selectivity of at least about 1.5.

14. The separation membrane of claim 1 , wherein the graphene monolayer directly contacts the polymer support.

15. The separation membrane of claim 1 , further comprising:
an intermediate layer between the polymer support and the graphene monolayer.

16. The separation membrane of claim 15 , wherein the intermediate layer includes at least one of an acrylic, urethane, silicon, and poly(ethylene oxide)-based polymer resin.

17. The separation membrane of claim 1 , wherein the separation membrane has a multilayer structure including at least three graphene monolayers separated by an interlayer distance of about 0.34 nm to about 0.50 nm.

18. The separation membrane of claim 1 , wherein the separation membrane has a multilayer structure including 2 to 50 graphene monolayers.

19. A desalination apparatus including the separation membrane according to claim 13 ,
wherein a width of the at least one of pores and channels in the graphene monolayer allows selective passage of water molecules and blocks hydrated salt ions from a solution containing the water molecules and the hydrated salt ions.

20. A gas separation apparatus including the separation membrane according to claim 13 ,
wherein a width of the at least one of pores and channels in the graphene monolayer allows selective separation of a first gas from a gas mixture containing the first gas and a second gas.

21. The gas separation apparatus of claim 20 , wherein the first gas is hydrogen and the second gas is oxygen.

22. A separation membrane comprising:
a polymer support; and
a graphene including at least one monolayer on at least one surface of the polymer support, the graphene being 2-dimensional and planar-structured,
wherein the graphene includes a plurality of grains defined by grain boundaries, and
the grain boundaries provide gaps present along the grain boundaries between the grains in the graphene,
the gaps between the grains in the graphene are configured to pass a target substance to separate the target substance from a mixture containing the target substance,
the grains include molecular defects that define pores in the grains,
the pores are dimensioned to allow target ions, liquid, or gases to pass through the graphene, and
the pores are defined in the grains and spaced apart from the gaps between the grains,
wherein the at least one graphene monolayer on the polymer support has a first fluid permeability in a range of about 400 Barrer to about 1200 Barrer, and
wherein the at least one graphene monolayer on the polymer support has an first fluid/second fluid selectivity of at least about 1.5.

23. The separation membrane of claim 22 , wherein
the graphene includes a plurality of monolayers stacked on top of each other on the polymer support,
the graphene in

Assignees

• Choi Jae-Young
• Park Ho-Bum
• Samsung Electronics Co Ltd

Inventors

• Choi Jae-Young
• Park Ho-Bum

Classifications

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• B01D71/021 Primary

  Carbon · CPC title

• B01D2325/04

  Characteristic thickness · CPC title

• B01D69/10

  Supported membranes; Membrane supports · CPC title

• B01D2325/20

  Specific permeability or cut-off range · CPC title