Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes

US9211504B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-9211504-B2
Application numberUS-201213666370-A
CountryUS
Kind codeB2
Filing dateNov 1, 2012
Priority dateDec 20, 2011
Publication dateDec 15, 2015
Grant dateDec 15, 2015

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Abstract

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Carbon molecular sieves (CMS) membranes having improved thermal and/or mechanical properties are disclosed herein. In one embodiment, a carbon molecular sieve membrane for separating a first and one or more second gases from a feed mixture of the first gas and one or more second gases comprises a hollow filamentary carbon core and a thermally stabilized polymer precursor disposed on at least an outer portion of the core. In some embodiments, the thermally stabilized polymer precursor is created by the process of placing in a reaction vessel the carbon molecular sieve membrane comprising an unmodified aromatic imide polymer, filling the reaction vessel with a modifying agent, and changing the temperature of the reaction vessel at a temperature ramp up rate and ramp down rate for a period of time so that the modifying agent alters the unmodified aromatic imide polymer to form a thermally stabilized polymer precursor.

First claim

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We claim: 1. A process for forming a carbon membrane using precursor pre-treatment comprising: providing a polymer precursor; pre-treating at least a portion of the polymer precursor with an agent that is capable of reducing substructure collapse; and subjecting the pre-treated polymer precursor to pyrolysis; wherein the step of pre-treating at least a portion of the polymer precursor provides at least a 300% increase in the CO 2 permeance of the carbon membrane in contrast…

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What does patent US9211504B2 cover?
Carbon molecular sieves (CMS) membranes having improved thermal and/or mechanical properties are disclosed herein. In one embodiment, a carbon molecular sieve membrane for separating a first and one or more second gases from a feed mixture of the first gas and one or more second gases comprises a hollow filamentary carbon core and a thermally stabilized polymer precursor disposed on at least an…
Who is the assignee on this patent?
Georgia Tech Res Inst, Shell Oil Co
What technology area does this patent fall under?
Primary CPC classification B01D67/0076. Mapped technology areas include Operations & Transport.
When was this patent published?
Publication date Tue Dec 15 2015 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 1 related publication on this page (citations in our corpus or others sharing the same primary CPC).