Superhydrophobic compositions and coating process for the internal surface of tubular structures

Patent metadata

Field	Value
Publication number	US-9701869-B2
Application number	US-201514819129-A
Country	US
Kind code	B2
Filing date	Aug 5, 2015
Priority date	Nov 21, 2012
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A method for depositing a coating includes creating a vacuum within an interior volume of a tubular structure, wherein the tubular structure also includes an internal surface. Gas is supplied to the interior volume of the tubular structure, wherein the gas includes a plasma precursor in the gas phase. The tubular structure is biased relative to ground. Plasma having a density is formed and cyclically positioned along the length of the tubular structure. Positive ions of the plasma precursor gas are generated and are deposited on the internal surface forming a coating on the internal surface, wherein the coating exhibits a water contact angle of greater than 120°.

First claim

What is claimed is:

1. A conformal coating disposed on a tubular structure, comprising:
a tubular structure having an internal surface and an interior volume; and
a carbo-siloxane coating disposed on said internal surface, wherein said coating has a water contact angle of greater than 120°, wherein said coating comprises 50 to 60 atomic percent carbon, 20 to 30 atomic percent oxygen, and 15 to 25 atomic percent silicon, wherein said coating, at a depth of up to 300 Angstrom, comprises:
(a) Si—O at a relative concentration of 38.5(±12) %;
(b) Si—C at a relative concentration of 25.6(±5) %;
(c) C—O at a relative concentration of 4.5(±3) %;
(d) C—C at a relative concentration of 31.4(±2) %.

2. The conformal coating disposed on the tubular structure of claim 1 , wherein said coating has a water contact angle of greater than 120° to 155°.

3. The conformal coating disposed on the tubular structure of claim 1 , wherein said coating exhibits a water-ice shear pressure of less than or equal to 0.2 MPa to dislodge a water-ice droplet from the coating surface.

4. The conformal coating disposed on the tubular structure of claim 1 , wherein said coating exhibits an asphaltene shear pressure of less than or equal to 0.010 MPa to dislodge a drop of asphaltene from the coating surface.

5. The conformal coating disposed on the tubular structure of claim 1 , wherein said coatings exhibits an inorganic scale shear pressure of less than or equal to 0.040 MPa to dislodge inorganic scale from the coating surface.

6. The conformal coating disposed on the tubular structure of claim 1 , wherein said tubular structure is a pipeline configured to transport gas or oil.

7. The conformal coating of claim 1 , wherein said coating is present at a thickness of up to 2.0 microns.

Assignees

• Southwest Res Inst
• Shell Oil Co

Inventors

• Miller Michael A
• Wei Ronghua
• Hatton Gregory J

Classifications

• B05D7/222

  of pipes · CPC title

• E21B17/00

  Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; {Cables;} Casings; Tubings · CPC title

• H01J37/32128

  using particular waveforms, e.g. polarised waves · CPC title

• C23C16/507

  using external electrodes, e.g. in tunnel type reactors · CPC title

• Y10T428/139

  Open-ended, self-supporting conduit, cylinder, or tube-type article · CPC title