Liquid-liquid separator interface detection system and polymerization process utilizing the same

Patent metadata

Field	Value
Publication number	US-9700814-B2
Application number	US-201615086166-A
Country	US
Kind code	B2
Filing date	Mar 31, 2016
Priority date	May 9, 2012
Publication date	Jul 11, 2017
Grant date	Jul 11, 2017

Abstract

A system for detecting an interface between a polymer-rich phase and a solvent-rich phase comprising a liquid-liquid separator configured to receive a polymer solution as an inlet stream comprising solvent, polymer and unreacted monomer produced in a solvent-based polymerization reactor through an inlet feed, wherein a tank is configured to provide a residence time of at least 20 minutes and to permit the stream to separate into the polymer rich phase and the solvent rich phase; a first sonic transponder for sending a first sonic signal from either a top or bottom of the liquid-liquid separator and for receiving a first reflected portion of the sonic signal, the reflected portion of the sonic signal created by the passage of the sonic signal through a liquid-liquid interface between the solvent rich phase and the polymer rich phase, wherein the first sonic transponder is positioned such that it transmits the signal which travels perpendicularly to the liquid-liquid interface is provided.

First claim

We claim:

1. A system including a liquid-liquid separator vessel, a vessel inlet, and a sonic transponder for detecting an interface between a polymer-rich phase and a solvent-rich phase, in the liquid-liquid separator vessel, the system characterized by:
the liquid-liquid separator vessel configured to receive through the vessel inlet a polymer solution inlet stream comprising solvent, polymer and monomer produced in a solvent-based polymerization reactor, wherein the liquid-liquid separator vessel is configured to provide a residence time of at least 20 minutes and to permit the polymer solution inlet stream to separate into the polymer rich phase and the solvent rich phase;
a first sonic transponder for sending a first sonic signal from a top of the liquid-liquid separator vessel and for receiving a first reflected portion of the sonic signal; and
a second sonic transponder for sending a second sonic signal from a bottom of the liquid-liquid separator vessel and for receiving a second reflected portion of the sonic signal; where the first reflected portion of the first sonic signal is created by reflecting a first portion of the first sonic signal from a liquid-liquid interface between the solvent rich phase and the polymer rich phase; and wherein the second reflected portion of the second sonic signal is created by reflecting a second portion of the second sonic signal from the liquid-liquid interface between the solvent rich phase and the polymer rich phase; wherein the first sonic transponder is positioned such that it transmits the first sonic signal perpendicularly to the liquid-liquid interface and wherein the second sonic transponder is positioned such that it transmits the second sonic signal perpendicularly to the liquid-liquid interface, and wherein the vessel inlet feeds the polymer solution inlet stream into a bottom portion of the liquid-liquid separator vessel.

2. The system according to claim 1 , further comprising a sleeve partially or wholly enclosing the first sonic transponder.

3. The system according to claim 1 , wherein the liquid-liquid separator vessel is jacketed.

4. The system according to claim 1 , wherein the liquid-liquid separator vessel is a gravity separator.

5. The system according to claim 1 , further comprising a polymer rich phase vessel outlet valve comprising a flow meter and a differential pressure transmitter located on either side of the flow meter.

6. The system according to claim 1 , further comprising an automated control vessel valve to control a level of polymer rich phase in the liquid-liquid separator vessel.

7. The system according to claim 1 , further comprising a control system to receive and analyze data recovered from the first, and optionally from the second, sonic transponders.

Assignees

• Dow Global Technologies Llc

Inventors

• Hypolite Curvel
• Wang Alec Y

Classifications

• B01D17/12

  Auxiliary equipment particularly adapted for use with liquid-separating apparatus, e.g. control circuits · CPC title

• B01D35/1573

  Flow control valves · CPC title

• G01N2291/0251

  Solidification, icing, curing composites, polymerisation · CPC title

• C08F210/18

  with non-conjugated dienes, e.g. EPT rubbers · CPC title

• G01F23/296

  Acoustic waves · CPC title