Liquid-liquid separator interface detection system and polymerization process utilizing the same

Patent metadata

Field	Value
Publication number	US-9327221-B2
Application number	US-201314391178-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	May 9, 2012
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

A system for detecting an interface between a polymer-rich phase and a solvent-rich phase comprising a liquid-liquid separator configured to receive a polymer solution as an inlet stream comprising solvent, polymer and unreacted monomer produced in a solvent-based polymerization reactor through an inlet feed, wherein a tank is configured to provide a residence time of at least 20 minutes and to permit the stream to separate into the polymer rich phase and the solvent rich phase; a first sonic transponder for sending a first sonic signal from either a top or bottom of the liquid-liquid separator and for receiving a first reflected portion of the sonic signal, the reflected portion of the sonic signal created by the passage of the sonic signal through a liquid-liquid interface between the solvent rich phase and the polymer rich phase, wherein the first sonic transponder is positioned such that it transmits the signal which travels perpendicularly to the liquid-liquid interface is provided.

First claim

We claim:

1. A polymerization process comprising: A) polymerizing one or more monomers in the presence of a solvent, to form a polymer solution; B) transferring the polymer solution to a liquid-liquid separator, without adding heat to the solution, and wherein a pressure of the polymer solution is actively reduced in a controlled manner prior to, or within, the liquid-liquid separator, to induce at least two liquid phases, a polymer-rich phase and a solvent-rich phase, and wherein a concentration of polymer in the polymer-rich phase is higher than that in the polymer solution transferred to the liquid-liquid separator; and C) detecting an interface between the polymer-rich phase and the solvent-rich phase by use of two sonic transponders positioned within the liquid-liquid separator, such that a first sonic transponder is located in a top half of the liquid-liquid separator and a second sonic transponder is located in a bottom half of the liquid-liquid separator; and D) removing the solvent-rich phase from the liquid-liquid separator and the removed solvent-rich phase comprises less than 1000 ppm polymer.

2. The polymerization process according to claim 1 , wherein step (A) occurs in a solution polymerization reactor.

3. The polymerization process according to claim 1 , wherein step (A) occurs in a continuously stirred tank reactor.

4. The polymerization process according to claim 1 , further comprising calculating a vertical position of the interface face from a reflected sonic signal received by the first or second sonic transponder.

5. The polymerization process according to claim 1 , further comprising adjusting a flow rate of removing the solvent-rich phase based upon the vertical position of the interface.

Assignees

• Dow Global Technologies Llc

Inventors

• Hypolite Curvel
• Wang Alec Y

Classifications

• B01D17/12

  Auxiliary equipment particularly adapted for use with liquid-separating apparatus, e.g. control circuits · CPC title

• B01D35/1573 Primary

  Flow control valves · CPC title

• B01D17/0214

  with removal of one of the phases · CPC title

• B01D17/0208 Primary

  by sedimentation · CPC title

• G01N29/024

  by measuring propagation velocity or propagation time of acoustic waves · CPC title