Portable rapid detection device for heavy metal ions and methods of use

Patent metadata

Field	Value
Publication number	US-9696278-B2
Application number	US-201614994479-A
Country	US
Kind code	B2
Filing date	Jan 13, 2016
Priority date	Sep 29, 2015
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

A portable rapid detection device for heavy metal ions includes a card electrode and a thin-layer flow cell, wherein a three-electrode system of the card electrode is inserted in a micro-channel of the thin-layer flow cell; and heavy metal ions are detected by using an anodic stripping voltammetry (ASV), a solution to be detected flows by the surface of a working electrode in the micro-channel, and heavy metals are enriched and stripped on the surface thereof.

First claim

What is claimed is:

1. A portable rapid detection device for heavy metal ions, comprising: a card electrode ( 1 ) and a thin-layer flow cell ( 2 ), wherein:
the card electrode ( 1 ) comprises a substrate ( 11 ) and a three-electrode system; the three-electrode system comprises a working electrode ( 121 ), a counter electrode ( 122 ) and a reference electrode ( 123 ) which are planar all-solid-state electrodes distributed on the substrate ( 11 ); one end of the substrate ( 11 ) is an interface end ( 14 ), contact pins ( 13 ) are distributed on the interface end ( 14 ), and the three contact pins are respectively connected with the three electrodes of the three-electrode system;
the thin-layer flow cell ( 2 ) is of an integrally formed structure and comprises a cell wall ( 21 ), a micro-channel ( 22 ) and an electrode socket ( 23 ); the micro-channel ( 22 ) is a thin-layer-shaped cavity enclosed by the cell wall ( 21 ), and the micro-channel ( 22 ) is connected with a liquid inlet pipeline ( 221 ) and a liquid outlet pipeline ( 222 ) which lead outwards; the electrode socket ( 23 ) is an opening of the micro-channel ( 22 ) on the cell wall ( 21 ), and the card electrode ( 1 ) can be inserted in and pulled out from the electrode socket ( 23 ); and
the card electrode ( 1 ) is inserted in the thin-layer flow cell ( 2 ) from the electrode socket ( 23 ), the three-electrode system stretches into the micro-channel ( 22 ), and the interface end ( 14 ) extends out of the cell wall ( 21 );
wherein the material of the thin-layer flow cell ( 2 ) is photosensitive resin and the thin-layer flow cell ( 2 ) is made by using a stereo lithography.

2. The portable rapid detection device for heavy metal ions according to claim 1 , characterized in that the printing of the card electrode ( 1 ) is by using a silk-screen printing method.

3. The portable rapid detection device for heavy metal ions according to claim 1 , characterized in that the contact pins ( 13 ) are arranged at the interface end ( 14 ) in parallel, and the sizes of the contact pins ( 13 ) are consistent with that of a standard USB interface.

4. The portable rapid detection device for heavy metal ions according to claim 1 , characterized in that the working electrode ( 121 ) is a silver-carbon electrode, the counter electrode ( 122 ) is a silver electrode, and the reference electrode ( 123 ) is a silver-silver chloride electrode.

5. The portable rapid detection device for heavy metal ions according to claim 1 , characterized in that the shape of the cavity of the micro-channel ( 22 ) is a rectangular shape, a saddle shape, an oval shape or a circular shape.

6. The portable rapid detection device for heavy metal ions according to claim 5 , characterized in that the shape of the cavity of the micro-channel ( 22 ) is a saddle, and the liquid inlet pipeline ( 221 ) and the liquid outlet pipeline ( 222 ) are respectively connected with the micro-channel ( 22 ) at two top ends of the saddle-shaped cavity along the tangential direction.

7. The portable rapid detection device for heavy metal ions according to claim 1 , characterized in that the liquid inlet pipeline ( 221 ) and the liquid outlet pipeline ( 222 ) are provided with pipeline orifices protruding from the outer wall of the cell wall ( 21 ).

8. The portable rapid detection device for heavy metal ions according to claim 1 , characterized in that the thickness of the micro-channel ( 22 ) is 0.8 mm to 1.2 mm, and the inside diameters of the liquid inlet pipeline ( 221 ) and the liquid outlet pipeline ( 222 ) are smaller than or equal to the thickness of the micro-channel ( 22 ).

9. The portable rapid detection device for heavy metal ions according to claim 8 , characterized in that the thickness of the micro-channel ( 22 ) is 0.9 mm, and the inside diameters of the liquid inlet pipeline ( 221 ) and the liquid outlet pipeline ( 222 ) are 0.83 mm.

10. The portable rapid detection device for heavy metal ions according to claim 9 , characterized in that the three electrodes of the three-electrode system are distributed on the substrate ( 11 ) along the flow field shape of a solution to be detected in the micro-channel ( 22 ).

11. The portable rapid detection device for heavy metal ions according to claim 10 , characterized in that the widths of the working electrode ( 121 ) and the reference electrode ( 123 ) are greater than that of the counter electrode ( 122 ).

12. The portable rapid detection device for heavy metal ions according to claim 6 , characterized in that the flow field of the solution to be detected in the saddle-shaped micro-channel ( 22 ) is S-shaped at a flow rate between 0.02 and 0.05 m/s, and the three electrodes of the three-electrode system are distributed on the substrate ( 11 ) along the S-shaped flow field.

13. A method for utilizing the portable rapid detection device of claim 1 , comprising the following specific steps:
(1) assembly of a detection system: connecting the liquid inlet pipeline and the liquid outlet pipeline of the thin-layer flow cell to a liquid inlet hose and a liquid outlet hose, respectively, wherein the liquid inlet hose extends into the solution to be detected and is provided with a peristaltic pump, and connecting the interface end of the card electrode with a corresponding interface of an electrochemical analysis workstation;
(2) an enrichment process: adjusting the electrochemical analysis workstation, and applying an enrichment voltage between the working electrode and the reference electrode; starting the peristaltic pump, driving the solution to be detected to flow into the thin-layer flow cell from the liquid inlet pipeline for pre-electrolysis, and discharging waste liquid from the liquid outlet pipeline; after the pre-electrolysis, shutting down the peristaltic pump, and standing the solution to be detected;
(3) a stripping process: adjusting the electrochemical analysis workstation to positively scan the voltage between the working electrode and the reference electrode from a negative direction, so that heavy metals to be detected and enriched on the working electrode are stripped again; and
(4) detection data collection: recording the current in the working electrode and an auxiliary electrode circuit and the potential of the working electrode in the stripping process to obtain a stripping voltammetry curve.

14. The method according to claim 13 , characterized in that a Bi 3+ solution and an acid base solution are added in the solution to be detected and containing heavy metal ions before detection.

15. The method according to claim 14 , characterized in that the concentration of Bi 3+ in the solution to be detected is 500 μg/L.

16. The application method according to claim 14 , characterized in that the acid base solution is a 0.1 mol/L NaAc—HAc solution, and the pH of the solution to be detected is adjusted to be 4.6.

17. The method according to claim 13 , characterized in that in the enrichment process, the flow rate of the solution to be detected in the liquid inlet pipeline is set as 0.02 m/s to 0.05 m/s.

18. The method according to claim 13 , characterized in that the enrichment voltage is −1.2V, the enrichment time for finishing the enrichment process is 180 s, and the enrichment time contains a standing time of 60 s.

19. The method according to claim 13 , characterized in that in the stripping process, the voltage is scanned by square waves, and the potential increment is 0.005V.

Assignees

• Nanjing University Of Technology

Inventors

• Chen Guosong
• Hong Ying
• Lu Xiaohua
• Liu Chang
• He Xiaoyun
• Lv Dandan
• Wang Jikui
• Tang Meihua
• Zhang Zhiyi
• Dong Xiaochen

Classifications

• G01N27/42

  Measuring deposition or liberation of materials from an electrolyte; Coulometry, i.e. measuring coulomb-equivalent of material in an electrolyte · CPC title

• G01N27/48 Primary

  using polarography, i.e. measuring changes in current under a slowly-varying voltage · CPC title