Low temperature hot melt adhesive for high-speed coating and spiral coating

Patent metadata

Field	Value
Publication number	US-9695340-B2
Application number	US-201414211329-A
Country	US
Kind code	B2
Filing date	Mar 14, 2014
Priority date	Sep 16, 2011
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

The present invention provides a hot melt adhesive for high-speed coating and spiral coating at low temperature. The hot melt adhesive has excellent adhesion to polyethylene and nonwoven fabric, and is suitable for disposable products. The hot melt adhesive comprises: (A) a propylene homopolymer having a melting point of 100° C. or lower which is obtainable by polymerizing propylene using a metallocene catalyst; and (B) an ethylene-based copolymer.

First claim

The invention claimed is:

1. A hot melt adhesive comprising:
(A) a propylene homopolymer having a melting point of 100° C. or lower which is prepared by polymerizing propylene using a metallocene catalyst; and
(B) an ethylene/α-olefin copolymer prepared with a metallocene catalyst,
wherein the ethylene/α-olefin copolymer is ethylene/propylene copolymer and/or ethylene/octene copolymer.

2. The hot melt adhesive of claim 1 , wherein the propylene homopolymer has a melting point of 65° C. to 85° C.

3. The hot melt adhesive of claim 1 , wherein the propylene homopolymer is a mixture of a (A1) propylene homopolymer having a weight average molecular weight of 60,000 or less and a (A2) propylene homopolymer having a weight average molecular weight greater than 60,000.

4. The hot melt adhesive of claim 3 , wherein the propylene homopolymer is a mixture of a (A1) propylene homopolymer having a weight average molecular weight of 30,000 to 55,000 and a (A2) propylene homopolymer having a weight average molecular weight of 60,000 to 80,000.

5. The hot melt adhesive of claim 4 , wherein the propylene homopolymer comprises a mixture of a (A1) propylene homopolymer and a (A2) propylene homopolymer in a ratio of 1:3 to 3:2.

6. The hot melt adhesive of claim 1 , wherein the propylene homopolymer is present at 60 to 95 parts by weight based on the 100 parts by weight of the total weight of the propylene homopolymer (A) and the ethylene/α-olefin copolymer (B).

7. The hot melt adhesive of claim 1 , wherein the ethylene/α-olefin copolymer has a melt index of 10 to 50 g/10 minutes at 230° C.

8. The hot melt adhesive of claim 7 , wherein the ethylene/α-olefin copolymer has a melt index of 20 to 30 g/10 minutes at 230° C.

9. The hot melt adhesive of claim 1 , further comprising 60 to 150 parts by weight, based on 100 parts by weight of the total weight of the propylene homopolymer and ethylene/α-olefin copolymer, of (C) a tackifier resin.

10. The hot melt adhesive of claim 1 , wherein the tackifier is a hydrogenated dicyclopentadiene-based resin.

11. The hot melt adhesive of claim 1 , further comprising a (D) oil.

12. The hot melt adhesive of claim 1 , further comprising a (E) wax.

13. The hot melt adhesive of claim 12 wherein the wax is an olefin wax modified with carboxylic acid or carboxylic anhydride.

14. The hot melt adhesive of claim 13 , wherein the olefin wax is selected from the group consisting of polyethylene wax, polypropylene wax, polyethylene/polypropylene wax, polyethylene/polybutylene wax, polyethylene/polybutene wax, and mixtures thereof.

15. The hot melt adhesive of claim 13 , wherein the wax has an acid value of 20 to 160 mgKOH/g.

16. The hot melt adhesive of claim 1 , further comprising a stabilizing agent, ultraviolet absorber, filler and/or antioxidant.

17. The hot melt adhesive of claim 1 wherein the adhesive has a melt viscosity of 7,000 mPa·s or less at 150° C.

18. An article comprising the hot melt adhesive of claim 1 .

19. The article of claim 18 further comprising a substrate selected from tissue, cotton, nonwoven fabric or polyolefin film.

20. The article of claim 18 , which is a diaper, sanitary napkin, pet sheet, hospital gown or surgical garment.

21. The hot melt adhesive of claim 1 , wherein the ethylene/α-olefin copolymer is ethylene/propylene copolymer.

22. The hot melt adhesive of claim 1 , wherein the ethylene/α-olefin copolymer is ethylene/octene copolymer.

23. The hot melt adhesive of claim 1 , wherein the ethylene/α-olefin copolymer is ethylene/propylene copolymer and ethylene/octene copolymer.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Moriguchi Masahiro
• Saito Shigekazu

Classifications

• Y10T428/2826

  Synthetic resin or polymer · CPC title

• C09J11/08

  Macromolecular additives · CPC title

• C09J11/06

  organic · CPC title

• C09J7/35

  Heat-activated · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title