Process for producing fine, morphologically optimized particles using jet mill, jet mill for use in such a process and particles produced

Patent metadata

Field	Value
Publication number	US-9695047-B2
Application number	US-201414774242-A
Country	US
Kind code	B2
Filing date	Mar 11, 2014
Priority date	Mar 11, 2013
Publication date	Jul 4, 2017
Grant date	Jul 4, 2017

Abstract

A process for producing fine particles with a high aspect ratio and/or a low specific surface area includes use of a jet mill. An alkaline grinding aid is added to a grinding gas before the grinding gas is fed into a grinding chamber of the jet mill. The process includes micronization of particles of layered structure material having an interplanar distance ranging from 0.30 nm to 0.40 nm as measured by X-ray diffraction method.

First claim

The invention claimed is:

1. A process comprising:
providing a jet mill comprising a grinding chamber and at least one jetting nozzle to feed grinding gas into said grinding chamber;
providing particles of layered structure material having an interplanar distance ranging from 0.30 nm to 0.40 nm as measured by X-ray diffraction method into the grinding chamber;
feeding grinding gas under pressure to the grinding chamber through the at least one jetting nozzle to perform micronisation of the particles; and
collecting micronized particles;
wherein an alkaline grinding aid is added to the grinding gas before said grinding gas is fed into the grinding chamber.

2. The process according to claim 1 , wherein the particles of layered structure material comprise natural graphite, synthetic graphite, petroleum coke, pitch coke, anthracite, hexagonal boron nitride, or clay minerals.

3. The process according to claim 1 , wherein the alkaline grinding aid is ammonia gas.

4. The process according to claim 1 , wherein the alkaline grinding aid is added to the grinding gas in a concentration ranging from 5 to 500 mg/m 3 .

5. The process according to claim 1 , further comprising adjusting a concentration of the alkaline grinding aid added to the grinding gas to obtain an atmosphere in the grinding chamber with a pH greater than 8.

6. The process according to claim 1 , wherein the grinding gas is at temperature ranging from 150° C. to 350° C. when the alkaline grinding aid is added to the grinding gas.

7. The process according to claim 1 , wherein the grinding gas is fed to the grinding chamber with the alkaline grinding aid at a pressure of ranging from 2 to 15 bar; the grinding chamber is a circular grinding chamber and the at least one jetting nozzle is arranged at an angle of between 40 and 60° to the tangent of the circular grinding chamber; or combinations thereof.

8. The process according to claim 1 , wherein the grinding gas is air or steam.

9. The process according to claim 1 , wherein the grinding gas with the alkaline grinding aid are accelerated to a supersonic velocity when fed under pressure to the grinding chamber.

10. The process according to claim 1 , wherein the micronized particles have an average particle size d 50 less than 20 μm determined according to ISO 13320; a specific surface area according of less than 15 m 2 /g, the specific surface area being determined by BET method according to DIN 66131; an aspect ratio of greater than 2, the aspect ratio being the ratio of the largest circular diameter of the area of a micronized particle to the thickness of said particle; or combinations thereof.

11. A jet mill for grinding particles of layered structure material, the jet mill comprising:
means to feed particles for grinding;
a circular grinding chamber for the micronisation of the particles;
at least one jetting nozzle to feed grinding gas into said grinding chamber wherein the at least one jetting nozzle is arranged at an angle of between 40 and 60° to the tangent of the circular grinding chamber;
means to feed grinding gas under pressure to the at least one jetting nozzle;
means to discharge the micronized particles; and
means for adding grinding aid to the grinding gas upstream of the at least one jetting nozzle;
wherein the jet mill is a spiral jet mill.

12. The jet mill of claim 11 , wherein the spiral jet mill comprises a plurality of nozzles.

13. The jet mill according to claim 11 , wherein at least one jetting nozzle is of the Laval type.

14. The jet mill according to claim 11 , wherein the means to discharge the micronized particles is a dynamic classifier device.

15. Micronized particles, of an average particle size d 50 less than 20 μm determined according to ISO 13320, having:
a specific surface area according of less than 15 m 2 /g, the specific surface area being determined by BET method according to DIN 66131;
an aspect ratio of between 20 and 100, the aspect ratio being the ratio of the largest circular diameter of the area of the micronized particle to the thickness of said particle; or combinations thereof;
wherein the micronized particles are obtained from a layered structure material having an interplanar distance ranging from 0.30 nm to 0.40 nm as measured by X-ray diffraction method.

16. The micronized particles of claim 15 , wherein the micronized particles comprise natural graphite or synthetic graphite.

17. The micronized particles of claim 15 , wherein the micronized particles comprise petroleum coke, pitch coke, anthracite, hexagonal boron nitride, or clay minerals.

Assignees

• Total Res & Technology Feluy

Inventors

• Handl Werner

Classifications

• C01B32/21

  After-treatment · CPC title

• C01B21/0648

  After-treatment, e.g. grinding, purification (transformation of hexagonal into cubic or wurtzitic boron nitride C04B35/5831) · CPC title

• B02C19/061

  of the cylindrical type (B02C19/068 takes precedence) · CPC title

• C01B2204/32

  Size or surface area · CPC title

• C01P2004/51

  Particles with a specific particle size distribution · CPC title