Enhanced superconductivity of fullerenes

Patent metadata

Field	Value
Publication number	US-9685600-B2
Application number	US-201514625219-A
Country	US
Kind code	B2
Filing date	Feb 18, 2015
Priority date	Feb 18, 2015
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

Methods for enhancing characteristics of superconductive fullerenes and devices incorporating the fullerenes are disclosed. Enhancements can include increase in the critical transition temperature at a constant magnetic field; the existence of a superconducting hysteresis over a changing magnetic field; a decrease in the stabilizing magnetic field required for the onset of superconductivity; and/or an increase in the stability of superconductivity over a large magnetic field. The enhancements can be brought about by transmitting electromagnetic radiation to the superconductive fullerene such that the electromagnetic radiation impinges on the fullerene with an energy that is greater than the band gap of the fullerene.

First claim

What is claimed is:

1. A method for enhancing one or more superconductive characteristics of superconductive fullerenes comprising transmitting electromagnetic radiation comprising ultraviolet light, visible light, or infrared light to the superconductive fullerenes, the electromagnetic radiation impinging upon the superconductive fullerenes with an energy that is greater than the band gap of the superconductive fullerenes, wherein the superconductive fullerenes are hydrogenated and intercalated and have the general structure of:
Cs a Rb b K c M y C n H x
in which M=Hg, Bi, or Tl
a, b, c=0-3,
y=0-2,
wherein at least one of a, b, y is at least 1
n is 20 or greater, and
x=about 10 or more.

2. The method of claim 1 , wherein the one or more superconductive characteristics include an increase in the critical transition temperature of the superconductive fullerenes at a constant magnetic field; the existence of a superconducting hysteresis over a changing magnetic field; a decrease in the stabilizing magnetic field required for the onset of superconductivity; and/or an increase in the stability of superconductivity over a magnetic field.

3. The method of claim 2 , wherein the critical transition temperature of the superconductive fullerenes when in photonic communication with the electromagnetic radiation increases by about 10 K or more.

4. The method of claim 2 , wherein the critical transition temperature of the superconductive fullerenes when in photonic communication with the electromagnetic radiation increases by from about 10 K to about 25 K.

5. The method of claim 2 , wherein the critical transition temperature of the superconductive fullerenes when in photonic communication with the electromagnetic radiation is 77 K or greater.

6. The method of claim 2 , wherein a stabilizing magnetic field of the superconductive fullerenes when in photonic communication with the electromagnetic radiation is about 1000 Oe or less.

7. The method of claim 1 , wherein the superconductive fullerenes are halogenated.

8. The method of claim 1 , wherein the superconductive fullerenes are derivatized.

9. The method of claim 1 , wherein the electromagnetic energy impinges on the fullerenes at an energy of about 1 electron Volt or greater.

10. The method of claim 9 , wherein the electromagnetic energy impinges on the fullerenes at an energy of from about 1.3 electron Volts to about 2 electron Volts.

11. The method of claim 1 , wherein x=n−2.

12. A method for enhancing one or more superconductive characteristics of superconductive fullerenes comprising transmitting electromagnetic radiation to the superconductive fullerenes, the electromagnetic radiation impinging upon the fullerenes with an energy that is greater than the band gap of the superconductive fullerenes, wherein the superconductive fullerenes are hydrogenated and intercalated and have the general structure of:
Cs a Rb b K c M y C n H x
in which M=Hg, Bi, or Tl
a, b, c=0-3,
y=0-2,
wherein at least one of a, b, y is at least 1
n is 20 or greater, and
x=about 10 or more.

13. The method of claim 12 , wherein the one or more superconductive characteristics include an increase in the critical transition temperature of the superconductive fullerenes at a constant magnetic field; the existence of a superconducting hysteresis over a changing magnetic field; a decrease in the stabilizing magnetic field required for the onset of superconductivity; and/or an increase in the stability of superconductivity over a magnetic field.

14. The method of claim 13 , wherein the critical transition temperature of the superconductive fullerenes when in photonic communication with the electromagnetic radiation increases by about 10 K or more.

15. The method of claim 13 , wherein the critical transition temperature of the superconductive fullerenes when in photonic communication with the electromagnetic radiation increases by about 10 K to about 25 K.

16. The method of claim 13 , wherein the critical transition temperature of the superconductive fullerenes when in photonic communication with the electromagnetic radiation is 77 K or greater.

17. The method of claim 13 , wherein a stabilizing magnetic field of the superconductive fullerenes when in photonic communication with the electromagnetic radiation is about 1000 Oe or less.

18. The method of claim 12 , wherein the superconductive fullerenes are halogenated.

19. The method of claim 12 , wherein the superconductive fullerenes are derivatized.

20. The method of claim 12 , wherein the electromagnetic energy impinges on the fullerenes at an energy of about 1 electron Volt or greater.

21. The method of claim 12 , wherein the electromagnetic energy impinges on the fullerenes at an energy of from about 1.3 electron Volts to about 2 electron Volts.

Assignees

• Savannah River Nuclear Solutions Llc

Inventors

• Washington Ii Aaron L
• Teprovich Joseph A
• Zidan Ragaiy

Classifications

• C01B31/0213

  Chemistry & Metallurgy · mapped topic

• H01L39/123 Primary

  Electricity · mapped topic

• H01L39/24

  Electricity · mapped topic

• H10N60/853 Primary

  Fullerene superconductors, e.g. soccer ball-shaped allotropes of carbon, e.g. C60 or C94 · CPC title

• C01B32/156 Primary

  After-treatment · CPC title