Method of making photovoltaic cell

Patent metadata

Field	Value
Publication number	US-9685580-B2
Application number	US-201615265374-A
Country	US
Kind code	B2
Filing date	Sep 14, 2016
Priority date	Nov 19, 2012
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

A photovoltaic solar cell comprises a nano-patterned substrate layer. A plurality of nano-windows are etched into an intermediate substrate layer to form the nano-patterned substrate layer. The nano-patterned substrate layer is positioned between an n-type semiconductor layer composed of an n-type semiconductor material and a p-type semiconductor layer composed of a p-type semiconductor material. Semiconductor material accumulates in the plurality of nano-windows, causing a plurality of heterojunctions to form between the n-type semiconductor layer and the p-type semiconductor layer.

First claim

We claim:

1. A method for generating a photovoltaic cell, comprising:
depositing an intermediate substrate layer on a first semiconductor layer, the first semiconductor layer comprising an n-type semiconductor material;
etching a plurality of nano-windows into the intermediate substrate layer to form a nan-patterned intermediate substrate layer, the plurality of nano-windows extending through an entirety of the intermediate substrate layer thereby exposing the first semiconductor material by way of the plurality of nano-windows; and
forming a second semiconductor layer over the nano-patterned intermediate substrate layer, wherein the second semiconductor layer comprises a p-type semiconductor material, wherein depositing the second semiconductor layer over the nano-patterned intermediate substrate layer comprises accumulating the second semiconductor material in the plurality of nano-windows to form a respective plurality of heterojunctions, wherein the p-type semiconductor layer has a pseudomorphic crystal structure.

2. The method of claim 1 , further comprising:
prior to depositing the intermediate substrate layer on the first semiconductor layer, depositing the first semiconductor layer on a base substrate layer.

3. The method of claim 1 , wherein the p-type semiconductor material is Cadmium Tellurium, and wherein the n-type semiconductor material is Cadmium Sulfide.

4. The method of claim 1 , wherein the p-type semiconductor material is of the formula Zn x Cd 1-x Te.

5. The method of claim 1 , wherein each nano-window in the plurality of nano-windows has a length of less than 350 nm and a width of less than 350 nm.

6. The method of claim 1 , wherein the photovoltaic cell has a graded band gap.

7. The method of claim 1 , further comprising:
subsequent to forming the second semiconductor layer over the nano-patterned intermediate substrate layer, depositing a third semiconductor layer on the second semiconductor layer, the third semiconductor layer composed of a third semiconductor material, wherein the second semiconductor material has a first band gap, wherein the third semiconductor material has a second band gap, and wherein the first band gap and the second band gap are unequal.

8. A method for generating a photovoltaic cell, comprising:
depositing an intermediate substrate layer on a first semiconductor layer, the first semiconductor layer comprising an n-type semiconductor material;
etching a plurality of nano-windows into the intermediate substrate layer to form a nano-patterned intermediate substrate layer, the plurality of nano-windows extending through an entirety of the intermediate substrate layer thereby exposing the first semiconductor material by way of the plurality of nano-windows; and
depositing a second semiconductor layer over the nano-patterned intermediate substrate layer, wherein depositing the second semiconductor layer over the nano-patterned intermediate substrate layer comprises accumulating the second semiconductor material in the plurality of nano-windows to form a respective plurality of heterojunctions, wherein the second semiconductor layer has a pseudomorphic crystal structure.

Assignees

• Sandia Corp
• Univ Texas
• Sandia Llc Nat Tech & Eng Solutions

Inventors

• Cruz-Campa Jose Luis
• Zhou Xiaowang
• Zubia David

Classifications

• Y02E10/543

  Solar cells from Group II-VI materials · CPC title

• H01L31/1832 Primary

  Electricity · mapped topic

• H01L31/073

  Electricity · mapped topic

• H01L31/0352

  Electricity · mapped topic

• H01L31/03529

  Electricity · mapped topic