Flexible tubing material and method of forming the material

Patent metadata

Field	Value
Publication number	US-9670351-B2
Application number	US-201514818971-A
Country	US
Kind code	B2
Filing date	Aug 5, 2015
Priority date	Dec 29, 2009
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

A flexible tubing material includes a radiation crosslinked blend of a first elastomeric polymer including a styrenic thermoplastic elastomer, an ethylene vinyl acetate elastomer, a polylefin elastomer with a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different. In an embodiment, a method of making a material includes providing the first elastomeric polymer, providing the second elastomeric polymer, blending the first elastomeric polymer and the second elastomeric polymer, extruding or injection molding the blend, and crosslinking the blend with radiation.

First claim

What is claimed is:

1. A flexible tubing material comprising a radiation crosslinked blend of:
a) a first elastomeric polymer including an ethylene vinyl acetate elastomer having a vinyl acetate content of at least about 50% by weight of the total weight of the ethylene vinyl acetate elastomer, wherein the ethylene vinyl acetate elastomer has a shore A hardness in a range of about 30 to about 40; and
b) a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different.

2. The flexible tubing material of claim 1 , wherein the ethylene vinyl acetate elastomer is present in an amount of at least about 5% by weight of the total weight of the blend.

3. The flexible tubing material of claim 1 , wherein the ethylene vinyl acetate elastomer has a glass transition temperature of less than about −25° C.

4. The flexible tubing material of claim 1 , wherein the ethylene vinyl acetate elastomer has a number average molecular weight (Mn) of about 70,000 to about 90,000.

5. The flexible tubing material of claim 1 , wherein the ethylene vinyl acetate elastomer has a weight average molecular weight (Mw) of about 250,000 to about 400,000.

6. The flexible tubing material of claim 1 , wherein the blend includes a lubricant in an amount of less than about 0.1% by weight of the total weight of the blend.

7. The flexible tubing material of claim 1 , further comprising a plasticizer in an amount of no greater than about 70.0% by weight of the total weight of the blend.

8. The flexible tubing material of claim 1 , wherein the polyolefin elastomer includes polypropylene, polyethylene, copolymers of ethylene with propylene, copolymers of ethylene with alpha-olefins, copolymers of ethylene with polar vinyl monomers, terpolymers of ethylene, maleic anhydride, and acrylates, ionomers of ethylene and acrylic acid, ionomers of ethylene and methacrylic acid, or combinations thereof.

9. The flexible tubing material of claim 1 , wherein the polyolefin elastomer has a flexural modulus lower than about 200 MPa.

10. The flexible tubing material of claim 1 , wherein the diene elastomer is ethylene propylene diene monomer (EPDM).

11. The flexible tubing material of claim 1 , wherein the radiation crosslinked blend is heat resistant to steam sterilization temperatures of at least about 121° C.

12. The flexible tubing material of claim 11 , wherein the radiation crosslinked blend is heat resistant to steam sterilization temperatures of at least about 135° C.

13. The flexible tubing material of claim 1 , wherein the flexible tubing material has transparency.

14. A biopharmaceutical tube comprising a radiation crosslinked blend of:
a) a first elastomeric polymer including an ethylene vinyl acetate elastomer having a vinyl acetate content of at least about 50% by weight of the total weight of the ethylene vinyl acetate elastomer, wherein the ethylene vinyl acetate elastomer has a shore A hardness in a range of about 30 to about 40; and
b) a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or a combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different.

15. The biopharmaceutical tube of claim 14 , further comprising a plasticizer in an amount in a range of 0% by weight to 70.0% by weight of the total weight of the blend.

16. The biopharmaceutical tube of claim 14 , wherein the first elastomeric polymer is free of an extending oil or plasticizer.

17. A method of making a material comprising:
providing a first elastomeric polymer including an ethylene vinyl acetate elastomer having a vinyl acetate content of at least about 50% by weight of the total weight of the ethylene vinyl acetate elastomer, wherein the ethylene vinyl acetate elastomer has a shore A hardness in a range of about 30 to about 40;
providing a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different;
blending the first elastomeric polymer and the second elastomeric polymer;
extruding or injection molding the blend; and
crosslinking the blend with radiation.

Assignees

• Saint Gobain Performance Plastics Corp

Inventors

• Siddhamalli Sridhar K
• Liu Zhizhong
• Simon Mark W
• Golub Charles S
• Lennon Heidi
• Garver Wayne E
• Colton Mark F
• Wells Robert L
• Tzivanis Michael J
• Risen William
• Klettlinger Nathan

Classifications

• B29C45/0001

  characterised by the choice of material · CPC title

• B29C2035/085

  using gamma-ray · CPC title

• C08L2203/18

  used for pipes · CPC title

• C08L9/06 Primary

  Copolymers with styrene · CPC title

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title