Flexible tubing material and method of forming the material

Patent metadata

Field	Value
Publication number	US-8956706-B2
Application number	US-98134810-A
Country	US
Kind code	B2
Filing date	Dec 29, 2010
Priority date	Dec 29, 2009
Publication date	Feb 17, 2015
Grant date	Feb 17, 2015

Abstract

A flexible tubing material includes a radiation crosslinked blend of a first elastomeric polymer including a styrenic thermoplastic elastomer, an ethylene vinyl acetate elastomer, a polyolefin elastomer with a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different. In an embodiment, a method of making a material includes providing the first elastomeric polymer, providing the second elastomeric polymer, blending the first elastomeric polymer and the second elastomeric polymer, extruding or injection molding the blend, and crosslinking the blend with radiation.

First claim

What is claimed is:

1. A flexible biopharmaceutical thermoplastic elastomer tubing material comprising a gamma and/or e-beam radiation crosslinked blend of:
a) a first elastomeric polymer including a styrenic thermoplastic elastomer comprising a styrene-butadiene-styrene (SBS), a styrene-isoprene- styrene (SIS),a styrene-ethylene butylene-styrene (SEBS), a styrene-ethylene propylene- styrene (SEPS), a styrene-ethylene-ethylene-butadiene-styrene (SEEBS), a styrene-ethylene-ethylene-propylene-styrene (SEEPS), a styrene-isoprene-butadiene-styrene (SIBS), or any combination thereof;
b) a second elastomeric polymer including a polyolefin elastomer, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different; and
c) a plasticizer comprising a mineral oil,
wherein the first elastomeric polymer is present in an amount of at least 10% by weight of the blend and the tubing material has a compression set of 18% or less at a temperature of about 121 ° C.

2. The flexible tubing material of claim 1 , wherein the styrenic thermoplastic elastomer includes at least one free olefinic double bond.

3. The flexible tubing material of claim 1 , wherein the polyolefin elastomer includes polypropylene, polyethylene, copolymers of ethylene with propylene, copolymers of ethylene with alpha-olefins, copolymers of ethylene with polar vinyl monomers, terpolymers of ethylene, maleic anhydride, and acrylates, ionomers of ethylene and acrylic acid, ionomers of ethylene and methacrylic acid, or combinations thereof.

4. The flexible tubing material of claim 1 , further comprising a lubricant present at less than about 1.0% by weight of the total weight of the blend.

5. The flexible tubing material of claim 1 , wherein the mineral oil is present at no greater than about 70.0% by weight of the total weight of the blend.

6. The flexible tubing material of claim 1 , further comprising a radiation sensitizer, a crosslinking promoter, or combinations thereof.

7. The flexible tubing material of claim 1 , wherein the radiation crosslinked blend has a shore A durometer of about 40 to about 90.

8. The flexible tubing material of claim 1 , wherein the radiation crosslinked blend is heat resistant to steam sterilization temperatures of at least about 121 ° C.

9. The flexible tubing material of claim 1 , wherein the radiation crosslinked blend is formed into a single layer tube or a multi-layer tube.

10. The flexible tubing material of claim 1 , wherein the radiation crosslinked blend has a pump life of greater than about 50 hours as measured at 600RPM using a standard head.

11. The flexible tubing material of claim 1 , wherein the first elastomeric polymer is present in an amount of at least 20 % by weight of the blend.

12. The flexible tubing material of claim 1 , wherein the first elastomeric polymer is present in an amount of at least 30 % by weight of the blend.

Assignees

• Siddhamalli Sridhar Krishnamurthi
• Liu Zhizhong
• Simon Mark W
• Golub Charles S
• Sardinha Heidi
• Garver Wayne Edward
• Colton Mark F
• Wells Robert L
• Stadt Gerald L
• Tzivanis Michael J
• Risen William
• Klettlinger Nathan
• Saint Gobain Performance Plast

Inventors

• Siddhamalli Sridhar Krishnamurthi
• Liu Zhizhong
• Simon Mark W
• Golub Charles S
• Sardinha Heidi
• Garver Wayne Edward
• Colton Mark F
• Wells Robert L
• Stadt Gerald L
• Tzivanis Michael J
• Risen William
• Klettlinger Nathan

Classifications

• C08J3/246

  Intercrosslinking of at least two polymers · CPC title

• Y10T428/1386

  Natural or synthetic rubber or rubber-like compound containing · CPC title

• C08L31/04 Primary

  Homopolymers or copolymers of vinyl acetate · CPC title

• B29C2035/085

  using gamma-ray · CPC title

• C08L23/06

  Polyethylene · CPC title