Methods of forming graphene-coated diamond particles and polycrystalline compacts

Patent metadata

Field	Value
Publication number	US-9670065-B2
Application number	US-201514819031-A
Country	US
Kind code	B2
Filing date	Aug 5, 2015
Priority date	Oct 29, 2010
Publication date	Jun 6, 2017
Grant date	Jun 6, 2017

Abstract

Coated diamond particles have solid diamond cores and at least one graphene layer. Methods of forming coated diamond particles include coating diamond particles with a charged species and coating the diamond particles with a graphene layer. A composition includes a substance and a plurality of coated diamond particles dispersed within the substance. An intermediate structure includes a hard polycrystalline material comprising a first plurality of diamond particles and a second plurality of diamond particles. The first plurality of diamond particles and the second plurality of diamond particles are interspersed. A method of forming a polycrystalline compact includes catalyzing the formation of inter-granular bonds between adjacent particles of a plurality of diamond particles having at least one graphene layer.

First claim

What is claimed is:

1. A method of forming a graphene-coated diamond particle, comprising:
coating a diamond particle with a charged species; and
coating the diamond particle with a graphene layer.

2. The method of claim 1 , further comprising coating the diamond particle with a material selected from the group consisting of group VIII-A elements and alloys thereof.

3. The method of claim 1 , further comprising immersing the diamond particle in a solution comprising an oppositely charged species before coating the diamond particle with a graphene layer.

4. The method of claim 1 , further comprising coating the diamond particle with at least one graphite layer, wherein coating the diamond particle with a charged species comprises coating the at least one graphite layer with the charged species.

5. The method of claim 4 , wherein coating the diamond particle with a graphene layer comprises providing the graphene layer over at least a portion of the at least one graphite layer.

6. The method of claim 1 , wherein coating the diamond particle with a charged species comprises coating the diamond particle with a positively charged amine-terminated group.

7. A method of forming a polycrystalline compact, comprising:
coating each of a first plurality of diamond particles with a charged species;
coating each of the first plurality of diamond particles with at least one graphene layer; and
catalyzing the formation of inter-granular bonds between adjacent particles of the first plurality of diamond particles.

8. The method of claim 7 , further comprising coating each of the first plurality of diamond particles with a material selected from the group consisting of group VIII-A elements and alloys thereof.

9. The method of claim 7 , further comprising interspersing the first plurality of diamond particles with a second plurality of diamond particles, wherein the first plurality of diamond particles has a first average diameter and the second plurality of diamond particles has a second average diameter different from the first average diameter.

10. The method of claim 7 , further comprising coating each of the first plurality of diamond particles with at least one graphite layer before coating each of the first plurality of diamond particles with a charged species, wherein coating each of the first plurality of diamond particles with at least one graphene layer comprises providing the at least one graphene layer over at least a portion of the at least one graphite layer.

Assignees

• Baker Hughes Inc

Inventors

• Chakraborty Soma
• Digiovanni Anthony A
• Agrawal Gaurav
• Scott Danny E
• Mathur Vipul

Classifications

• B22F1/18

  Non-metallic particles coated with metal · CPC title

• B22F2998/00

  Supplementary information concerning processes or compositions relating to powder metallurgy · CPC title

• C04B35/00

  Shaped ceramic products characterised by their composition {(porous ceramic products C04B38/00; ceramic articles characterised by particular shape, see the relevant classes, e.g. linings for casting ladles, tundishes, cups or the like B22D41/02; ceramic substrates for microelectronic semi-conductors H10W70/692)}; Ceramics compositions ({shaping of ceramics B28B;} containing free metal bonded to carbides, diamond, oxides, borides, nitrides, silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides or sulfides other than as macroscopic reinforcing agents C22C); Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products {(infiltration of sintered ceramic preforms with molten metal C04B41/51; chemical preparation of powders of inorganic compounds C01)} · CPC title

• C04B35/52

  based on carbon, e.g. graphite · CPC title

• C04B35/62839

  Carbon · CPC title