Process for the (co-)polymerisation of olefins

Patent metadata

Field	Value
Publication number	US-9663590-B2
Application number	US-201414914281-A
Country	US
Kind code	B2
Filing date	Sep 3, 2014
Priority date	Sep 10, 2013
Publication date	May 30, 2017
Grant date	May 30, 2017

Abstract

Process for the polymerization or copolymerization of olefins by bringing the olefins into contact with a catalyst under polymerization or copolymerization conditions in a reactor containing a charge powder. The process includes, prior to introducing the catalyst into the reactor, introducing a scavenger into the reactor which reacts with catalyst poison present. The scavenger is added to the reactor until the charge powder contains a remaining amount of scavenger of between 0.1 and 2.5 moles per ton of charge powder.

First claim

The invention claimed is:

1. Process for the polymerisation or copolymerisation of olefins by bringing the said olefins into contact with a catalyst under polymerisation or copolymerisation conditions in a reactor comprising a charge powder, which process comprises, prior to the introduction of the catalyst into the reactor, the introduction of a scavenger into the reactor which reacts with catalyst poison present, wherein the scavenger is added to the reactor until the charge powder comprises a remaining amount of scavenger comprised between 0.1 and 2.5 moles per ton of charge powder.

2. Process for the polymerisation or copolymerisation of olefins by bringing the said olefins into contact with a catalyst under polymerisation or copolymerisation conditions in a reactor, which process comprises, prior to the introduction of the catalyst into the reactor, the introduction of a scavenger into the reactor which reacts with catalyst poison present, wherein the scavenger is added such that the level in the reactor of the product of decomposition of said scavenger and catalyst poison is controlled.

3. Process for the polymerisation or copolymerisation of olefins by bringing the said olefins into contact with a catalyst under polymerisation or copolymerisation conditions in a reactor, which process comprises, prior to the introduction of the catalyst into the reactor, the introduction of a scavenger into the reactor which reacts with catalyst poison present, wherein the addition of the scavenger is performed as a series of sequential injections of scavenger, and said injections are continued until the increase in level in the reactor of the product of decomposition of said scavenger and catalyst poison during an individual addition of the scavenger is less than the expected amount of the product of decomposition corresponding to a complete reaction of all the scavenger added with poison.

4. Process for the polymerisation or copolymerisation of olefins by bringing the said olefins into contact, under polymerisation or copolymerisation conditions in a reactor system, which process comprises, prior to the introduction of the catalytic system in the reactor system:
i) the introduction of a scavenger into the reactor system which reacts with the catalyst poison present, and
ii) subsequently introducing a catalyst poison into the reactor system'wherein the catalyst poison is water, and the scavenger addition is performed after the introduction of the charge powder into the reactor.

5. Process according to claim 1 wherein the catalyst poison is water.

6. Process according to claim 1 wherein the scavenger is selected from the group consisting of trialkylaluminium compounds, hydrides, chlorides or alcoholates of alkylaluminium, other trialkyl metal compounds, aluminoxanes and mixtures thereof.

7. Process according to claim 1 wherein the reactor is a gas phase reactor.

8. Process according to claim 1 wherein a cocatalyst is used in combination with the catalyst, the cocatalyst being an organometallic compound.

9. Process according to claim 1 wherein the principal olefin is ethylene and/or propylene.

10. Process according to claim 2 wherein the catalyst poison is water.

11. Process according to claim 2 wherein the scavenger addition is performed after the introduction of the charge powder into the reactor.

12. Process according to claim 2 wherein the remaining amount of scavenger (unreacted) is comprised between 0.1 and 2.5 moles per ton of charge powder.

13. Process according to claim 2 wherein the scavenger is selected from the group consisting of trialkylaluminium componds, hydrides, chlorides or alcoholates of alkylaluminium, other trialkyl metal compounds, aluminoxanes and mixtures thereof.

14. Process according to claim 2 wherein the reactor is a gas phase reactor.

15. Process according to claim 2 wherein a cocatalyst is used in combination with the catalyst, the cocatalyst being an organometallic compound.

16. Process according to claim 2 wherein the principal olefin is ethylene and/or propylene.

17. Process according to claim 3 wherein the catalyst poison is water.

18. Process according to claim 3 wherein the scavenger addition is performed after the introduction of the charge powder into the reactor.

19. Process according to claim 3 wherein the remaining amount of scavenger (unreacted) is comprised between 0.1 and 2.5 moles per ton of charge powder.

20. Process according to claim 3 wherein the scavenger is selected from the group consisting of trialkylaluminium compounds, hydrides, chlorides or alcoholates of alkylaluminium, other trialkyl metal compounds, aluminoxanes and mixtures thereof.

21. Process according to claim 3 wherein the reactor is a gas phase reactor.

22. Process according to claim 3 wherein a cocatalyst is used in combination with the catalyst, the cocatalyst being an organometallic compound.

23. Process according to claim 3 wherein the principal olefin is ethylene and/or propylene.

24. Process according to claim 4 wherein the remaining amount of scavenger (unreacted) is comprised between 0.1 and 2.5 moles per ton of charge powder.

25. Process according to claim 4 wherein the scavenger is selected from the group consisting of trialkylaluminium compounds, hydrides, chlorides or alcoholates of alkylaluminium, other trialkyl metal compounds, aluminoxanes and mixtures thereof.

26. Process according to claim 4 wherein the reactor is a gas phase reactor.

27. Process according to claim 4 wherein a cocatalyst is used in combination with the catalyst, the cocatalyst being an organometallic compound.

28. Process according to claim 4 wherein the principal olefin is ethylene and/or propylene.

29. Process according to claim 1 wherein the scavenger is added to the reactor until the charge powder comprises a remaining amount of scavenger comprised between 0.3 and 2 moles per ton of charge powder.

30. Process according to claim 7 wherein the reactor is a fluidised bed gas phase reactor.

31. Process according to claim 12 wherein the remaining amount of scavenger (unreacted) is comprised between 0.3 and 2 moles per ton of charge powder.

32. Process according to claim 14 wherein the reactor is a fluidised bed gas phase reactor.

33. Process according to claim 19 wherein the remaining amount of scavenger (unreacted) is comprised between 0.3 and 2 moles per ton of charge powder.

34. Process according to claim 21 wherein the reactor is a fluidised bed gas phase reactor.

35. Process according to claim 24 wherein the remaining amount of scavenger (unreacted) is comprised between 0.3 and 2 moles per ton of charge powder.

36. Process according to claim 26 wherein the reactor is a fluidised bed gas phase reactor.

Assignees

• Ineos Europe Ag

Inventors

• Desportes Serge
• Lalanne-Magne Claudine Viviane
• Viguier Renaud

Classifications

• C08F2/005 Primary

  by addition of a scale inhibitor to the polymerisation medium · CPC title

• C08F10/02

  Ethene · CPC title

• C08F2/008 Primary

  cleaning reaction vessels using chemicals (mechanical methods B08B9/08) · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• C08F10/06

  Propene · CPC title