System and method for deterring fouling in a polymerization reactor

Patent metadata

Field	Value
Publication number	US-9353202-B2
Application number	US-201514724362-A
Country	US
Kind code	B2
Filing date	May 28, 2015
Priority date	Sep 25, 2013
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

A catalyst composition may include a precontacted mixture of an olefin polymerization catalyst and an agent including an ammonium salt. The catalyst activity of the catalyst composition in the presence of water may be greater than if no ammonium salt were present in the catalyst composition. The ammonium salt may include a tetraalkylammonium salt, and the olefin polymerization catalyst may include a metallocene compound.

First claim

What is claimed is:

1. A continuous olefin polymerization system comprising:
a reactor system comprising a loop slurry polymerization reactor comprising an olefin monomer, a catalyst composition, and a diluent, wherein the loop slurry polymerization reactor continuously subjects the olefin monomer to polymerization conditions in the presence of the catalyst composition to produce a polyolefin slurry having polyolefin particles suspended in the diluent;
a precontactor coupled to an inlet of the loop slurry polymerization reactor and configured to provide the catalyst composition to the loop slurry polymerization reactor, wherein the precontactor comprises contact components that form the catalyst composition, the contact components comprising:
an olefin polymerization catalyst; and
an agent comprising an ammonium salt such that the catalyst composition has a greater catalyst activity in the presence of water than the olefin polymerization catalyst where the ammonium salt is not present.

2. The system of claim 1 , wherein the loop slurry polymerization reactor is one reactor of multiple reactors of the reactor system operating in series.

3. The system of claim 1 , comprising a control system having one or more tangible, non-transitory, machine-readable media collectively storing instructions executable by a processor to:
monitor conditions within the loop slurry polymerization reactor;
adjust an amount of the agent relative to the olefin polymerization catalyst within the precontactor based, at least in part, on the monitored conditions; and
controllably introduce the catalyst composition into the loop slurry polymerization reactor from the precontactor.

4. The system of claim 1 , wherein the ammonium salt has the formula:
(R 1 )(R 2 )(R 3 )(R 4 )N(X), wherein:
N is Nitrogen
R 1 , R 2 , R 3 , and R 4 are independently selected from a hydrogen, an alkyl, branched alkyl, cycloalkyl, aryl, or alkenyl group having from 1 to 20 carbons; and
X is an anion.

Assignees

• Chevron Phillips Chemical Co

Inventors

• Masino Albert P
• Muninger Randall S
• Mcdaniel Max P
• Schwerdtfeger Eric D
• Yang Qing
• Lief Graham R

Classifications

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• B01J19/2455

  provoking a loop type movement of the reactants (tubular loop-type reactors B01J19/2435; loop reactors having moving elements inside B01J19/1868) · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• B01J2204/002

  the feeding side being of particular interest · CPC title