Process for upgrading heavy and highly waxy crude oil without supply of hydrogen

Patent metadata

Field	Value
Publication number	US-9656230-B2
Application number	US-201414338749-A
Country	US
Kind code	B2
Filing date	Jul 23, 2014
Priority date	Nov 28, 2007
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

A continuous process to upgrade heavy crude oil for producing more valuable crude feedstock having high API gravity, low asphaltene content, and high middle distillate yield, low sulfur content, low nitrogen content, and low metal content without external supply of hydrogen and/or catalyst. Heavy crude oil having substantial amount of asphaltene and heavy components is mixed with highly waxy crude oil having large amount of paraffinic components and water to decompose asphaltene compounds and remove sulfur, nitrogen, and metal containing substances under supercritical conditions. Product has higher API gravity, lower asphaltene content, high middle distillate yield, lower sulfur content, lower nitrogen content, and lower metal content to be suitable for conventional petroleum refining process.

First claim

I claim:

1. An apparatus for upgrading heavy crude oil and highly waxy crude oil in an environment free of an externally supplied catalyst or externally supplied hydrogen source, the apparatus comprising:
a mixing zone operable to combine a heavy crude oil, which has an API gravity of less than 30°, and a highly waxy crude oil, which has a pour point temperature greater than room temperature and has an API gravity of greater than 30°, with a water feed at a slightly elevated temperature to create a modified oil/water mixture, wherein the modified oil/water mixture is in the absence of externally supplied hydrogen;
a heater and tube in a pre-heating zone that is fluidly connected with the mixing zone, the pre-heating zone operable to heat the modified oil/water mixture to a temperature up to 350° C.;
a high pressure pumping means, the high pressure pumping means operable to increase pressure of the modified oil/water mixture to at least the critical pressure of water to produce a pre-heated mixture;
a reaction zone comprising an inner portion of a main reactor, wherein the reaction zone is fluidly connected with the pre-heating zone; the main reactor being operable to withstand a temperature that is at least as high as the critical temperature of water; the main reactor being operable to withstand pressure in excess of the critical pressure of water, the reaction zone being essentially free of an externally-provided catalyst and essentially free of an externally-provided hydrogen source;
a pressure regulating device;
a liquid-gas separator fluidly connected to the pressure regulating device, the liquid-gas separator operable to create a liquid stream and a gas stream; and
a water-oil separator fluidly connected to the liquid-gas separator via the liquid stream, the water-oil separator operable to create a recovered water stream and an upgraded hydrocarbon stream.

2. The apparatus of claim 1 where the pressure regulating device comprises a plurality of back pressure regulators connected in a parallel fashion.

3. The apparatus of claim 1 where the recovered water stream can be recycled and combined with the water feed.

4. The apparatus of claim 3 further comprising an oxidation reactor fluidly connected with the recovered water stream, the oxidation reactor operable to clean the recovered water stream via oxidation.

5. The apparatus of claim 1 , where the residence time of the pre-heated mixture within the reaction zone is between 0.1 and 10 minutes.

Assignees

• Saudi Arabian Oil Co

Inventors

• Choi Ki-Hyouk

Classifications

• C10G2300/1033

  Oil well production fluids · CPC title

• C10G2300/805

  Water · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• B01J3/008 Primary

  Processes carried out under supercritical conditions · CPC title

• C10G45/26

  Steam or water · CPC title