Co-current mixer, apparatus, reactor and method for precipitating nanoparticles

Patent metadata

Field	Value
Publication number	US-9192901-B2
Application number	US-201113699774-A
Country	US
Kind code	B2
Filing date	May 17, 2011
Priority date	May 25, 2010
Publication date	Nov 24, 2015
Grant date	Nov 24, 2015

Abstract

A high pressure tubular reactor for production of nanoparticles by precipitation has unidirectional fluid flows of precursor and supercritical water directed from inner and outer coaxial inlets to an outlet via a reaction zone immediately downstream of the inlets. The inner inlet is for supercritical fluid, and the outer inlet is for a precursor.

First claim

The invention claimed is:

1. A method of precipitating nanoparticles in a continuous hydrothermal or solvothermal process by the mixing of a precursor, which consists essentially of an aqueous solution or suspension of solid particles for the production of nanoparticles, with a fluid for the production of nanoparticles, the fluid containing water or a mixture of water and solvents other than water and being substantially at or above the critical point of the fluid in a co-current mixer having unidirectional flow from coaxial inner and outer inlets to an outlet via a mixing zone immediately downstream of said inlets, the method comprising the steps of:
providing a fluid flow of the precursor to the outer inlet,
providing a fluid flow of the fluid to the inner inlet, and
precipitating nanoparticles by mixing of the precursor with the fluid in said mixing zone.

2. The method of claim 1 , wherein the fluid flow of precursor is introduced substantially radially just upstream of said mixing zone, the fluid flow of precursor turning to the unidirectional flow direction upstream of said inner inlet.

3. The method of claim 2 , wherein the fluid flow of precursor is introduced via opposed inlets.

4. A method according to claim 1 , wherein the net cross-sectional area of the inner and outer inlets is approximately equal to the cross-sectional area of the outlet.

5. A method according to claim 4 , wherein the outer inlet and the outlet of the co-current mixer are defined by a tube of substantially constant diameter into which is introduced a second tube defining a single inner inlet and terminating at an open mouth facing the flow direction.

6. A method according to claim 5 , wherein the inner inlet comprises a tube end orthogonal to the flow direction.

7. A method according to claim 5 , wherein said second tube has an insulated wall to restrict heat transfer therethrough.

8. A method according to claim 1 , wherein the inner inlet is straight upstream of the mouth thereof.

9. A method according to claim 1 , wherein the outer inlet has an inlet duct at the side thereof.

10. A method according to claim 9 wherein a plurality of inlet ducts is provided orthogonal to said outer inlet.

11. A method according to claim 10 , wherein two opposed inlet ducts are provided.

12. A method according to claim 1 , wherein the inner and outer inlets have co-extensive fluid flow in the flow direction for a distance equal to or less than the greatest transverse dimension of the outer inlet.

13. A method according to claim 12 , wherein the inner and outer inlets are defined by co-axial tubes of circular cross-section.

14. A method according to claim 1 , wherein the direction of fluid flow is upward.

15. A method according to claim 1 , wherein the co-current mixer is adapted to withstand an internal pressure of 25 MPa in said mixing zone.

16. A method according to claim 1 , wherein the co-current mixer comprises a tubular ‘Tee’ having opposed inlets for the precursor and wherein said ‘Tee’ is defined by tubes of substantially constant diameter, and said inlet for the fluid is defined by a circular tube terminating in an open mouth facing the direction of said uni-direction flow.

17. A method according to claim 16 , wherein the direction of unidirectional flow is upward in use, opposing the effect of gravity.

18. A method according to claim 16 , and adapted to withstand an internal pressure of 25 MPa in the mixing zone.

Assignees

• Darr Jawwad
• Tighe Christopher James
• Gruar Robert
• Ucl Business Plc

Inventors

• Darr Jawwad
• Tighe Christopher James
• Gruar Robert

Classifications

• B01D11/0411 Primary

  the supercritical fluid acting as solvent for the solvent and as anti-solvent for the solute, e.g. formation of particles from solutions · CPC title

• B01F5/045

  Operations & Transport · mapped topic

• B82Y99/00

  Subject matter not provided for in other groups of this subclass · CPC title

• B01F2005/0034

  Operations & Transport · mapped topic

• B01J3/008

  Processes carried out under supercritical conditions · CPC title