Manufacturing method for enhancing ordered structure of block copolymers

Patent metadata

Field	Value
Publication number	US-9650495-B2
Application number	US-201414167326-A
Country	US
Kind code	B2
Filing date	Jan 29, 2014
Priority date	Oct 9, 2013
Publication date	May 16, 2017
Grant date	May 16, 2017

Abstract

The invention is related to a manufacturing method for enhancing an ordered structure of block copolymers, and more particularly to a thermal annealing process for block copolymers having conducting polymers and rod segments. The manufacturing method includes the following steps: (A) providing a block copolymer and a small molecule additive, wherein the block copolymer is formed of first monomers containing at least one aromatic ring and second monomers optionally containing at least one aromatic ring; and the small molecule additive is a aliphatic molecule, an aromatic molecule or a combination thereof; (B) blending the block copolymer and the small molecule additive to form a mixture; and (C) treating the mixture with a thermal annealing process to manufacture and facilitate the ordered structure of the block copolymers.

First claim

What is claimed is:

1. A manufacturing method for enhancing an ordered structure of block copolymers, sequentially comprising the following steps:
(A) providing a block copolymer and a molecule additive, wherein the block copolymer is formed of a first monomer containing at least one aromatic ring, and a second monomer optionally containing at least one aromatic ring, the first monomer and the second monomer are different; the molecule additive is a aliphatic molecule, an aromatic molecule or a combination thereof; and the aromatic rings of the first monomer, the second monomer, and the molecule additive are each independently selected from the group consisting of: a substituted or unsubstituted heterocyclic aromatic ring, a substituted or unsubstituted homocyclic aromatic ring, and a substituted or unsubstituted polycyclic aromatic ring
(B) blending the block copolymer and the molecule additive to form a mixture; and
(C) treating the mixture with a thermal annealing process to manufacture and facilitate the ordered structure of the block copolymers.

2. The manufacturing method of claim 1 , wherein the aromatic rings of the first monomer, the second monomer and the molecule additive are similar to, the same as, or different from each other.

3. The manufacturing method of claim 1 , wherein the aromatic rings of the first monomer, the second monomer, and the molecule additive are each independently selected from the group consisting of: a substituted or unsubstituted thiophene, a substituted or unsubstituted furan, a substituted or unsubstituted pyrrole, a substituted or unsubstituted imidazole, a substituted or unsubstituted oxazole, a substituted or unsubstituted thiazole, a substituted or unsubstituted benzene, a substituted or unsubstituted pyridine, a substituted or unsubstituted pyrimidine, and a substituted or unsubstituted pyrazine.

4. The manufacturing method of claim 1 , wherein the substituents are each independently selected from the group consisting of: a C 1-30 alkyl group, a C 3-30 cycloalkyl group, a C 3-30 heterocycloalkyl group, a C 6-30 aryl group, a C 5-30 heteroaryl group, —R 1 COOR 1 ′, —R 2 COR 2 ′, and —R 3 —O—R 3 ′, wherein R 1 , R 2 and R 3 are each independently a bond or a C 1-30 alkyl group, and R 1 ′, R 2 ′ and R 3 ′ are each independently hydrogen or a C 1-30 alkyl group.

5. The manufacturing method of claim 3 , wherein the substituents are each independently selected from the group consisting of: a C 1-30 alkyl group, a C 3-30 cycloalkyl group, a C 3-30 heterocycloalkyl group, a C 6-30 aryl group, a C 5-30 heteroaryl group, —R 1 COOR 1 ′, —R 2 COR 2 ′, and —R 3 —O—R 3 ′, wherein R 1 , R 2 and R 3 are each independently a bond or a C 1-30 alkyl group, and R 1 ′, R 2 ′ and R 3 ′ are each independently hydrogen or a C 1-30 alkyl group.

6. The manufacturing method of claim 1 , wherein the block copolymer is formed of the first monomer and the second monomer, and a first monomer segment formed of the first monomer is selected from the group consisting of: polythiophene, C1-30 alkyl-containing poly(3-alkylthiophene), polyfluorene, and poly(phenylvinylene); and a second monomer segment formed of the second monomer is selected from the group consisting of: poly(methyl methacrylate) (PMMA), polycarbonate (PC), polypropylene (PP), polyimide (PA), polydimethylsiloxane (PDMS), polyethylene terephthalate (PET), polyethylene (PE), polystyrene (PS) and polyethylene glycol (PEG).

7. The manufacturing method of claim 1 , wherein the molecule additive is selected from the group consisting of: polythiophene, C 1-30 alkyl-containing 3-alkylthiophene, dialkylphthalate, butyl benzyl phthalate (BBzP), and di(2-ethylhexyl) phthalate (DEHP).

8. The manufacturing method of claim 1 , wherein the molecule additive has a boiling point of 45° C. or more.

9. The manufacturing method of claim 1 , wherein the thermal annealing process is performed at a temperature of 25-400° C.

10. The manufacturing method of claim 1 , wherein the thermal annealing process is performed for 1-30 hours.

11. The manufacturing method of claim 1 , wherein the block copolymer and the molecule additive are blended in a weight ratio of 1 to 40.

Assignees

• Univ Nat Taiwan

Inventors

• Su Wei-Fang
• Wu Shang-Jung
• Ho Chun-Chih

Classifications

• C08F8/34

  Introducing sulfur atoms or sulfur-containing groups · CPC title

• C08K5/45 Primary

  Heterocyclic compounds having sulfur in the ring · CPC title