Particle size distribution control through internal donor in Ziegler-Natta catalyst

Patent metadata

Field	Value
Publication number	US-9644050-B2
Application number	US-201514794148-A
Country	US
Kind code	B2
Filing date	Jul 8, 2015
Priority date	Jul 8, 2014
Publication date	May 9, 2017
Grant date	May 9, 2017

Abstract

The present invention describes a process for controlling particle size of a catalyst composition. The process comprising the steps of contacting an internal donor with an organomagnesium precursor solution to form an intermediate solution and treating the intermediate solution with a transition metal compound to form a catalyst composition, wherein particle size of the catalyst composition is controlled by controlling a contact time of the internal donor with the precursor solution during formation of the intermediate solution.

First claim

We claim:

1. A process for controlling particle size of a catalyst composition, comprising the steps of:
(i) contacting an internal donor with an organo magnesium precursor solution to form an intermediate solution; and
(ii) treating the intermediate solution with a transition metal compound to form a catalyst composition,
wherein particle size of the catalyst composition is controlled by controlling a contact time of the internal donor with the precursor solution during formation of the intermediate solution.

2. The process as claimed in claim 1 , wherein the internal donor used is
selected from a group consisting of phthalates, benzoates, succinates, malonates, carbonates, diethers, and combinations thereof, wherein
(a) the phthalate is selected from a group consisting of di-n-butyl phthalate, di-i-butyl phthalate, di-2-ethylhexyl phthalate, di-n-octyl phthalate, di-i-octyl phthalate, di-n-nonyl phthalate;
(b) the benzoate is selected from a group consisting of methyl benzoate, ethyl benzoate, propyl benzoate, phenyl benzoate, cyclohexyl benzoate, methyl toluate, ethyl toluate, p-ethoxy ethyl benzoate, p-isopropoxy ethyl benzoate;
(c) the succinate is selected from a group consisting of diethyl succinate, dipropyl succinate, dilsooropyl succinate, dibutyl succinate, diisobutyl succinate;
(d) the malonate is selected from a group consisting of diethyl malonate, diethyl ethylmalonate, diethyl propyl malonate, diethyl isopropylmalonate, diethyl butylmalonate;
(e) the carbonate compound is selected from a group consisting of diethyl 1,2-cyclohexanedicarboxylate, di-2-ethylhexyl 1,2-cyclohexanedicarboxylate, di-2-isononyl 1,2-cyclohexanedicarboxylate, methyl anisate, ethyl anisate; and
(f) the diether compound is selected from a group consisting of 9,9-bis(methoxymethyl)fluorene, 2-isopropyl-2-isopentyl-1,3-dimethoxypropane, 2,2-diisobutyl-1,3-dimethoxypropane, 2,2-diisopentyl-1,3-dimethoxypropane, 2-isopropyl-2-cyclohexyl-1,3-dimethoxypropane.

3. The process as claimed in claim 1 , wherein, the transition metal compound represented by M(OR″′)pX4-p, where M is selected from a group consisting of Ti, V, Zr and Hf; X is a halogen atom; R″ is a hydrocarbon group and p is an integer having value equal or less than 4, the transition metal compound is selected from a group consisting of transition metal tetrahalide, alkoxy transition metal trihalide/aryloxy transition metal trihalide, dialkoxy transition metal dihalide, trialkoxy transition metal monohalide, tetraalkoxy transition metal, and mixtures thereof, wherein:
(a) the transition metal tetrahalide is selected from a group consisting of titanium tetrachloride, titanium tetrabromide and titanium tetraiodide and the likes for V, Zr and Hf;
(b) alkoxy transition metal trihalide/aryloxy transition metal trihalide is selected from a group consisting of methoxytitanium trichloride, ethoxytitanium trichloride, butoxytitanium trichloride and phenoxytitanium trichloride and the likes for V, Zr and Hf;
(c) dialkoxy transition metal dihalide is diethoxy transition metal dichloride and the likes for V, Zr and Hf;
(d) trialkoxy transition meta monohalide is triethoxy transition metal chloride and the likes for V, Zr and Hf; and
(e) tetraalkoxy transition metal is selected from a group consisting of tetrabutoxy titanium and tetraethoxy titanium and the likes for V, Zr and Hf.

4. The process as claimed in claim 1 , wherein the transition metal compound is titanium compound represented by Ti(OR″)pX4-p, where X is a halogen atom; R″ is a hydrocarbon group and p is an integer having value equal or less than 4.

5. The process as claimed in claim 1 , wherein the organomagnesium precursor is liquid or solid in nature.

6. The process as claimed in claim 1 , wherein the organomagnesium precursor is liquid in nature and is prepared by contacting magnesium source with organohalide and alcohol in presence of a solvent in a single step.

7. The process as claimed in claim 1 , wherein the organomagnesium precursor is solid in nature and is prepared by first contacting the magnesium source with organohalide in presence of solvating agent as the first step and then followed by addition of alcohol.

8. The process as claimed in claim 7 , wherein the solvating agent is selected from a group consisting of dimethyl ether, diethyl ether, dipropyl ether, diisopropyl ether, ethylmethyl ether, n-butylmethyl ether, n-butylethyl ether, di-n-butyl ether, diisobutyl ether,isobutylmethyl ether, and isobutylethyl ether, dioxane, tetrahydrofuran, 2-methyl tetrahydrofuran, tetrahydropyran and combination thereof.

9. The process as claimed in claim 7 , wherein the magnesium source is selected from a group consisting of magnesium metal, dialkyl magnesium, alkyl/aryl magnesium halides and mixtures thereof; wherein:
(a) the magnesium metal is in form of powder, ribbon, turnings, wire, granules, block, lumps, chips;
(b) the dialkylmagnesium compounds is selected from a group consisting of dimethylmagnesium, diethylmagnesium, diisopropylmagnesium, dibutylmagnesium, dihexylmagnesium, dioctylmagnesium, ethylbutylmagnesium, and butyloctylmagnesium; and
(a) alkyl/aryl magnesium halides is selected from a group consisting of methylmagnesium chloride, ethylmagnesium chloride, isopropylmagnesium chloride, isobutylmagnesium chloride, tert-butylmagnesium chloride, benzylmagnesium chloride, methylmagnesium bromide, ethylmagnesium bromide, isopropylmagnesium bromide, isobutylmagnesium bromide, tert-butylmagnesium bromide, hexylmagnesium bromide, benzylmagnesium bromide methylmagnesium iodide, ethylmagnesium iodide, isopropylmagnesium iodide, isobutylmagnesium iodide, tert-butylmagnesium iodide, and benzylmagnesium iodide.

10. The process as claimed in claim 7 , wherein the organohalide is selected from a group consisting of alkyl halides either branched or linear, halogenated alkyl benzene/benzylic halides haying an alkyl radical contains from about 10 to 15 carbon atoms and mixtures thereof; wherein:
(a) the alkyl halides is selected from a group consisting of methyl chloride, ethyl chloride, propyl chloride, isopropyl chloride, dichloromethane, chloroform, carbon tetrachloride, 1,1-dichloropropane, 1,2-dichloropropane, 1,3-dichloropropane, 2,3-dichloropropane, n-butyl chloride, iso-butyl chloride, 1,4-dichlorobutane, tert-butylchloride, amylchloride, tert-amylchloride, 2-chloropentane, 3-chioropentane, 1,5-dichloropentane, 1-chloro-8-iodoctane, 1-chloro-6-cyanohexane, cyclopentylchloride, cyclohexylchloride, chlorinated dodecane, chlorinated tetradecane, chlorinated eicosane, chlorinated pentacosane, chlorinated triacontane, iso-octylchloride, 5-chloro-5-methyl decane, 9-chloro-9-ethyl-6-methyl eiscosane; and
(b) the halogenated alkyl benzene/benzylic halides is selected from a group consisting of benzyl chloride and a,a′ dichloro xylene.

11. The process as claimed in claim 7 , wherein the alcohol is selected from a group consisting of aliphatic alcohols, alicyclic alcohols, aromatic alcohols, aliphatic alcohols containing an alkoxy group, diols and mixture thereof; wherein:
(a) the aliphatic alcohols is selected from a group consisting of methanol, ethanol, propanol, n-butanol, iso-butanol, t-butanol, n-pentanol, iso-pentanol, n-hexanol, 2-methylpentanol, 2-ethylbutanol, n-heptanol, n-octanol, 2-ethylhexanol, decanol and dodecanol,
(b) the alicyclic alcohols is selected from a group consisting of cyclohexanol and methylcyclohexanol,
(c) the aromatic alcohols is selected from a group consisting of benzyl alcohol and methylbenzyl alcohol,
(a) the aliphatic alcohols containing an alkoxy group is selected from a group consisting of ethyl glycol and butyl glycol; the diols is selected from a grou

Assignees

• Indian Oil Corp Ltd

Inventors

• Kaur Sukhdeep
• Bantu Bhasker
• Singh Gurmeet
• Kumar Naresh
• Shashikant
• Kapur Gurpreet Singh
• Basu Biswajit
• Malhotra Ravinder Kumar

Classifications

• C08F110/06 Primary

  Propene · CPC title

• C08F4/6548

  magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546 · CPC title

• C08F4/6545

  and metals of C08F4/64 or compounds thereof · CPC title

• C08F4/651

  Pretreating with non-metals or metal-free compounds · CPC title

• C08F2500/18

  Bulk density · CPC title