Process for forming a photocatalyst and oxidizing a cycloalkane
US-10906854-B2 · Feb 2, 2021 · US
US9643908B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9643908-B2 |
| Application number | US-201414914026-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 8, 2014 |
| Priority date | Sep 6, 2013 |
| Publication date | May 9, 2017 |
| Grant date | May 9, 2017 |
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The present invention provides a compound represented by the following general formula (A) wherein 1′-position is optically active; and one of R1 and R2 represents a methyl group and the other represents an ethyl group, or both R1 and R2 represent a methyl group.
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The invention claimed is: 1. A compound of the following formula (A): wherein 1′-position is optically active; and one of R 1 and R 2 is a methyl group and the other represents an ethyl group, or both R 1 and R 2 are a methyl group; wherein the optical purity regarding a configuration at 1′-position is in a range from 20% e.e. to 99% e.e; and wherein an R-isomer is in excess regarding the optical activity at 1′-position in the formula (A). 2. The compound according to claim 1 , wherein R 1 and R 2 are methyl groups. 3. A fragrance composition, comprising the compound of formula (A) according to claim 2 . 4. A method for augmenting or modifying an odor of a fragrance composition, the method comprising adding the compound according to claim 2 . 5. The compound according to claim 1 , wherein one of R 1 and R 2 is a methyl group, and the other is an ethyl group. 6. A fragrance composition, comprising the compound of formula (A) according to claim 5 . 7. A method for augmenting or modifying an odor of a fragrance composition, the method comprising adding the compound according to claim 5 . 8. An optically active (1′R)-3-methyl-5-(2,2,3-trimethylcyclopentan-1-yl)-2-pentanone, wherein the optical purity regarding a configuration at 1′-position is in a range from 60% e.e. to 99% e.e. 9. A fragrance composition, comprising the compound of formula (A) according to claim 8 . 10. A method for augmenting or modifying an odor of a fragrance composition, the method comprising adding the compound according to claim 8 . 11. (1′R)-3-Methyl-5-(2,2,3-trimethylcyclopentan-1-yl)-2-pentanone. 12. A fragrance composition, comprising the compound of formula (A) according to claim 1 . 13. A product scented with the fragrance composition according to claim 12 . 14. The scented product according to claim 13 , which is one selected from fragrance products, cosmetics, basic skin care cosmetics, make-up cosmetics, hair cosmetics, sunscreen cosmetics, medicated cosmetics, hair-care products, soaps, body cleaning agents, bath agents, laundry detergents, finishing softeners for clothes, cleaning agents, kitchen detergents, bleaching agents, aerosols, air fresheners, repellents, and groceries. 15. The fragrance composition according to claim 12 , wherein the content of the compound of formula (A) is 0.01 to 60% by weight. 16. The fragrance composition according to claim 12 , wherein the chemical purity of the compound is 80% or higher. 17. A method for augmenting or modifying an odor of a fragrance composition, the method comprising adding the compound according to claim 1 .
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