Method for producing micron-resolution coloured images embedded in a very robust, very durable medium

Patent metadata

Field	Value
Publication number	US-9638847-B2
Application number	US-201013376033-A
Country	US
Kind code	B2
Filing date	Jun 4, 2010
Priority date	Jun 4, 2009
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A method for producing a colored or fluorescent substrate with a view to formation of a colored or fluorescent image including the formation. The method defines on a substrate of a colored or fluorescent matrix, pixels of at least two different colors, wherein each pixel forms a filter for a given color. At least one filter is an interferential filter or a filter obtained with colored or fluorescent particles.

First claim

The invention claimed is:

1. A method of producing a color image on or in a substrate, comprising:
producing a colored or fluorescent substrate for purposes of forming a colored or fluorescent image, and before formation of such an image, the production of the colored or fluorescent substrate including:
forming, on a substrate, a colored or fluorescent matrix, defining pixels of at least two different colors, wherein each pixel forms a filter for a given color, and
wherein at least one filter is obtained with colored or fluorescent particles, of mineral or organic type, formed using surface plasmon effect particles of Au, Ag or Pt type, or using organic molecules included in a mineral matrix; and

producing the image, fixed directly on or in the colored or fluorescent substrate by performing a lithography process to partially mask at least one color of the matrix.

2. A method according to claim 1 , wherein the particles are coated in refractory materials of alumina, or zirconia, or zirconium type.

3. A method according to claim 2 , wherein intermediate layers are produced on the particles to adjust optical indices, to reproduce an initial color or to change the initial color in controlled fashion.

4. A method according to claim 1 , wherein the substrate includes a flat surface on which a pattern may be produced to form a color image.

5. A method according to claim 1 , wherein the masking is accomplished with assistance of a metal mask.

6. A method according to claim 5 , wherein the metal mask is made from Pt, or W, or TiN, or Ti.

7. A method according to claim 1 , further comprising forming a protective substrate.

8. A method according to claim 7 , wherein the protective substrate is assembled with the colored or fluorescent matrix by molecular bonding.

9. A method according to claim 1 , wherein the substrate is transparent at at least one wavelength of at least one of the colors of the matrix.

10. A method according to claim 1 , wherein the given color for each pixel is visible on either side of the pixel.

11. A method for producing a colored or fluorescent substrate for purposes of forming a colored or fluorescent image, and before formation of such an image, the method comprising:
forming, on an upper surface of a transparent substrate, a colored or fluorescent matrix, defining pixels of at least two different colors, wherein each pixel forms a filter for a given color,
wherein each pixel forms a dielectric-dielectric or metal-dielectric interferential filter, and
wherein the pixels are formed by successive deposition steps of depositing different layers, each having different optical characteristics, over the substrate, while selectively etching a portion of at least one of the different layers between successive deposition steps,
wherein after the etching of the portion of the at least one of the different layers between successive deposition steps, and prior to a subsequent deposition of another one of the different layers, the remaining non-etched portion of the at least one of the different layers which corresponds to one of the pixel colors, overlaps at least a portion of an adjacent pixel region corresponding to a different one of the pixel colors.

12. A method according to claim 11 , wherein the filter is a dielectric-dielectric interferential filter including an alternating stack of mineral layers.

13. A method according to claim 11 , wherein the filter is a metal-dielectric interferential filter including an alternating dielectric-metal stack.

14. A method according to claim 11 , wherein the substrate includes a flat surface on which a pattern may be produced to form a color image.

15. A method of producing a color image on or in a substrate, including a method of production of a colored or fluorescent substrate according to claim 11 , followed by production of the image, directly on or in the colored or fluorescent substrate.

16. A method according to claim 11 , wherein the substrate is transparent at at least one wavelength of at least one of the colors of the matrix.

17. A method according to claim 11 , wherein the given color for each pixel is visible on either side of the pixel.

18. A method according to claim 11 , wherein the remaining non-etched portion of the at least one of the different layers overlaps only a portion of the adjacent pixel region.

19. A method according to claim 11 , wherein the remaining non-etched portion of the at least one of the different layers covers all of the adjacent pixel region.

Assignees

• Rey Alain-Marcel
• Deguet Chrystel
• Frey Laurent
• Tardif Francois
• Commissariat L Energie Atomique Et Aux Energies Alternatives

Inventors

• Rey Alain-Marcel
• Deguet Chrystel
• Frey Laurent
• Tardif Francois

Classifications

• Y10T156/10

  Methods of surface bonding and/or assembly therefor · CPC title

• C03C17/34

  with at least two coatings having different compositions (C03C17/44 takes precedence) · CPC title

• C03C2217/72

  Decorative coatings · CPC title

• Y10T428/24802

  Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] · CPC title

• G02B5/201

  in the form of arrays · CPC title