Lubricant composition for marine engine

Patent metadata

Field	Value
Publication number	US-9637702-B2
Application number	US-201214347873-A
Country	US
Kind code	B2
Filing date	Sep 28, 2012
Priority date	Sep 29, 2011
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A lubricant composition for 4-stroke or 2-stroke marine engine includes at least one lubricant base oil for marine engine, at least one olefin copolymer, at least one hydrogenated styrene-isoprene copolymer, at least one glycerol ester and at least one detergent, whose use promotes fuel economy and has good properties regarding engine cleanliness, in particular crankcase cleanliness.

First claim

The invention claimed is:

1. A lubricant composition for 4-stroke or 2-stroke marine engine, comprising:
a) at least one lubricating base oil,
b) from 0.2 to 2% by weight of at least one olefin copolymer, wherein the olefin copolymer is a straight-chain copolymer of ethylene and propylene,
c) from 0.3 to 5% by weight of at least one copolymer of styrene and hydrogenated isoprene,
d) from 0.5 to 1.5% by weight of at least one glycerol ester, wherein the glycerol ester is a mixed ester of glycerol with at least one fatty acid having 8 to 24 carbon atoms and at least one carboxylic acid also comprising a hydroxyphenyl function, and
e) from 5 to 10% by weight of at least one detergent, based on the total weight of the lubricant composition.

2. The lubricant composition according to claim 1 wherein the hydrogenated styrene-isoprene copolymer has a quantity by weight of hydrogenated isoprene repeat units relative to the weight of the copolymer of between 50% and 95%.

3. The lubricant composition according to claim 1 wherein the detergents are chosen from among carboxylates, sulfonates and/or phenates, taken alone or in a mixture.

4. The lubricant composition according to claim 1 having a BN determined as per standard ASTM D-2896 of 5 to 100 mg KOH/g.

5. The lubricant composition according to claim 1 having a kinematic viscosity measured as per standard ASTM D7279 at 100° C. of between 5.6 and 26.1 cSt.

6. The lubricant composition according to claim 1 wherein the lubricant base oils are chosen from among the base oils of Group 1 or Group 2, taken alone or in a mixture.

7. The lubricant composition according to claim 1 further comprising an anti-wear additive including zinc dithiophosphate.

8. The use of a lubricant composition according to claim 1 for lubricating 4-stroke or 2-stroke marine engines.

9. The use of a lubricant composition according to claim 1 , wherein the composition reduces fuel consumption of 4-stroke or 2-stroke marine engines.

10. A method of using a lubricant composition, the method comprising:
using at least one glycerol ester, wherein the glycerol ester is a mixed ester of glycerol with at least one fatty acid having 8 to 24 carbon atoms and at least one carboxylic acid also comprising a hydroxyphenyl function and wherein the glycerol ester is from 0.5 to 1.5% by weight of the lubricant composition, of the lubricant composition in a 2-stroke or 4-stroke marine engine, the lubricant composition further comprising at least one lubricant base oil, from 0.2 to 2% by weight of at least one olefin copolymer wherein the olefin copolymer is a straight-chain copolymer of ethylene and propylene, from 0.3 to 5% by weight of at least one hydrogenated styrene-isoprene copolymer, and from 5 to 10% by weight of at least one detergent, based on the total weight of the lubricant composition; and
improving the engine or a crankcase cleanliness of the 4-stroke or 2-stroke marine engine.

11. A concentrate of additives comprising:
a) from 2 to 20% by weight of at least one olefin copolymer, wherein the olefin copolymer is a straight-chain copolymer of ethylene and propylene,
b) from 5 to 30% by weight of at least one copolymer of styrene and hydrogenated isoprene,
c) from 0.5 to 10% by weight of at least one glycerol ester, wherein the glycerol ester is a mixed ester of glycerol with a least one fatty acid having 8 to 24 carbon atoms and at least one carboxylic acid also comprising a hydroxyphenyl function, and
d) from 10 to 70% by weight of at least one detergent, based on the total weight of the concentrate of additives,
wherein the concentrate of additives is a 4× to 5× concentrate for dilution in a base oil or in a mixture of base oils.

12. The lubricant composition according to claim 1 wherein the detergents are chosen from among calcium carboxylates, calcium sulfonates and/or calcium phenates, taken alone or in a mixture.

13. The lubricant composition according to claim 1 having a BN determined as per standard ASTM D-2896 of 7 to 80 mg KOH/g.

14. The lubricant composition according to claim 1 having a BN determined as per standard ASTM D-2896 of 10 to 60 mg KOH/g.

15. The lubricant composition according to claim 1 having a kinematic viscosity measured as per standard ASTM D7279 at 100° C. of between 9.3 and 21.9 cSt.

16. The lubricant composition according to claim 1 having a kinematic viscosity measured as per standard ASTM D7279 at 100° C. of between 12.5 and 16.3 cSt.

17. A lubricant composition for 4-stroke or 2-stroke marine engine comprising:
51% by weight of a Group 1 base oil called Neutral Solvent 150NS of viscosity at 40° C. of 30 cSt;
27.3% by weight of a Group 1 base oil called Neutral Solvent 330NS of viscosity at 40° C. of 66 cSt;
2.5% by weight of a straight-chain olefin copolymer comprising 50 weight % of ethylene repeat units and having a weight average molecular weight Mw of 171 700, a number average molecular weight Mn of 91 120, a polydispersity index of 1.9, the olefin copolymer being diluted to 12.5 weight % in a Group 1 base oil;
5% by weight of a star-branched copolymer of styrene and hydrogenated isoprene, comprising 90 weight % of hydrogenated isoprene repeat units and 10 weight % styrene repeat units, and having a weight average molecular weight Mw of 605 000, a number average molecular weight Mn of 439 500, a polydispersity index of 1.4, the copolymer being diluted to 10.7 weight % in a Group 1 base oil;
1% by weight of a mixed ester of glycerol and C8-C18 fatty acids, and 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid, the mixed ester being diluted to 80 weight % in an aliphatic cycloparaffinic hydrocarbon;
12.7% by weight of detergents containing calcium carboxylates, calcium sulfonates and calcium phenates, the packet being diluted to 50 weight % in a Group 1 base oil.

18. The lubricant composition according to claim 1 wherein the quantity of the olefin copolymer ranges from 0.2 to 0.5% by weight, based on the total weight of the lubricant composition.

19. The lubricant composition according to claim 1 wherein the quantity of the glycerol ester ranges from 0.5 to 1% by weight, based on the total weight of the lubricant composition.

20. The lubricant composition according to claim 1 wherein the quantity of the olefin copolymer ranges from 0.2 to 0.5% by weight and the quantity of the glycerol ester ranges from 0.5 to 1% by weight, based on the total weight of the lubricant composition.

Assignees

• Total Marketing Services

Inventors

• Lancon Denis

Classifications

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2030/52

  Base number [TBN] · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2040/252

  Diesel engines · CPC title

• C10N2070/02

  Concentrating of additives · CPC title