Farm tractor lubricating composition with good water tolerance

Patent metadata

Field	Value
Publication number	US-9528072-B2
Application number	US-201013393615-A
Country	US
Kind code	B2
Filing date	Sep 7, 2010
Priority date	Sep 14, 2009
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

A lubricant of (a) an oil of lubricating viscosity; (b) a block copolymer of (i) a hydrophobic first block of C 1-30 alkyl (meth)acrylic units having an average total number of carbon atoms of at least 8; and (ii) a second block of (meth)acrylic units, at least some units of which comprise a heteroatom imparting polar character to the block; (c) an overbased calcium detergent; (d) a phosphorus-containing anti-wear agent that does not contribute to the metal content of the lubricant; and (e) a friction modifier suitable to reduce the static coefficient of friction at a metal-composition interface, is suitable for lubricating a farm tractor.

First claim

What is claimed is:

1. A method for lubricating a metal-composition interface of a wet-brake component of a farm tractor, comprising supplying thereto a lubricant comprising:
(a) an oil of lubricating viscosity;
(b) about 0.01 to about 0.3 weight percent of a block copolymer comprising:
(i) at least one hydrophobic block having C 1-30 alkyl (meth)acrylic units, with the proviso that C 1-30 alkyl groups of the C 1-30 alkyl (meth)acrylic units have a number-average number of carbon atoms of at least about 8; and
(ii) at least one additional block having (meth)acrylic units, at least some units of which comprise a heteroatom in the non-acid portion of the (meth)acrylic unit, imparting polar character to said block in excess of the polar character of the hydrophobic block;

(c) at least one overbased calcium or magnesium detergent in an amount to provide a total calcium plus magnesium concentration in the lubricant of about 0.015 to about 0.35 percent by weight;
(d) at least one phosphorus-containing anti-wear agent that does not contribute to the metal content of the lubricant; and
(e) at least one friction modifier suitable to reduce the static coefficient of friction between the surfaces of the metal-composition interface;
wherein said lubricant contains less than about 0.5 percent by weight of a zinc dialkyl dithiophosphate.

2. The method of claim 1 wherein, in the hydrophobic block of the block copolymer, at least 50 wt % of the C 1-30 alkyl (meth)acrylic units are C 12-15 alkyl (meth)acrylic units, and up to 50 wt % of the C 1-30 alkyl (meth)acrylic units are C 16-20 alkyl (meth)acrylic units, the weight percent being calculated based on the weight of the entire alkyl (meth)acrylic monomer units.

3. The method of claim 1 wherein the heteroatom-containing units in the block copolymer comprise an oxygen atom, a nitrogen atom, or a sulfur atom in the non-acid portion of the monomer units.

4. The method of claim 1 wherein the heteroatom-containing units in the block copolymer are derived from a nitrogen containing monomer selected from the group consisting of dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, dimethylaminopropyl methacrylate, dimethylaminopropyl acrylate, dimethylaminopropylacrylamide, dimethylaminopropylmethacrylamide, and mixtures thereof, or from an oxygen-containing monomer selected from the group consisting of 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, and mixtures thereof.

5. The method of claim 1 wherein the weight average molecular weight of the block copolymer is about 1000 to about 400,000 and the weight ratio of the hydrophobic block or blocks to the additional block or blocks is about 2:1 to about 100:1.

6. The method of claim 1 wherein the one or more overbased calcium or magnesium detergents comprise an overbased calcium sulfonate detergent.

7. The method of claim 1 wherein the amount of the one or more overbased calcium or magnesium detergents is about 0.05 to about 1.5 weight percent.

8. The method of claim 1 wherein the overbased calcium or magnesium detergent comprises an overbased calcium sulfonate detergent and is present in an amount to provide at least 0.03 percent by weight of calcium to the lubricant.

9. The method of claim 1 , being substantially free of a zinc dialkyl dithiophosphate.

10. The method of claim 1 wherein the phosphorus-containing antiwear agent comprises: a phosphorus acid ester; a phosphorus-containing carboxylic acid, ester, or amide; a phosphorus-containing ether; or a phosphite.

11. The method of claim 1 wherein the phosphorus-containing antiwear agent is present in an amount to provide about 0.01 to about 0.25 percent by weight phosphorus to the lubricant.

12. The method of claim 1 wherein the phosphorus-containing antiwear agent comprises dibutyl phosphite which is present in an amount to provide at least about 410 ppm by weight of phosphorus to the lubricant.

13. The method of claim 1 wherein the friction modifier comprises a metal salt of a fatty acid of about 6 to about 24 carbon atoms, or a condensation product of a fatty acid of about 6 to about 24 carbon atoms with a polyalkylene polyamine, an alkoxylated fatty amine, a fatty phosphite, or mixtures thereof.

14. The method of claim 1 wherein the amount of the friction modifier is about 0.2 to about 2 weight percent.

Assignees

• Abraham William D
• Baum Marina
• Qin Haihu
• Wang Ying
• Lubrizol Corp

Inventors

• Abraham William D
• Baum Marina
• Qin Haihu
• Wang Ying

Classifications

• C10N2020/09

  Characteristics associated with water · CPC title

• C10M2223/049

  Phosphite · CPC title

• C10M2215/28

  Amides; Imides · CPC title

• C10N2040/044

  for manual transmissions · CPC title

• C10M167/00 Primary

  Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential · CPC title