Composition, adhesive and layered body

Patent metadata

Field	Value
Publication number	US-9637666-B2
Application number	US-201414580475-A
Country	US
Kind code	B2
Filing date	Dec 23, 2014
Priority date	Dec 24, 2013
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A composition includes: a polythiol compound; a compound having plural epoxy groups; a radical generator; and an amine-based catalyst. In the composition, the ratio (Ep/SH (epoxy groups/thiol groups)) of the total molar number (Ep) of epoxy groups contained in the compound having plural epoxy groups to the total molar number (SH) of thiol groups contained in the polythiol compound is 0.50 or higher but lower than 2.00.

First claim

The invention claimed is:

1. A composition comprising:
a polythiol compound;
a compound having plural epoxy groups;
a radical generator; and
an amine-based catalyst,
wherein a ratio (Ep/SH (epoxy groups/thiol groups)) of a total molar number (Ep) of epoxy groups contained in the compound having plural epoxy groups to a total molar number (SH) of thiol groups contained in the polythiol compound is 0.50 or higher but lower than 2.00; and
wherein a ratio of a total molar number of the radical generator to a total molar number of thiol groups contained in the polythiol compound (radical generator/thiol groups) in from 0.025 to 0.5.

2. The composition according to claim 1 , wherein the radical generator is a thermal radical generator comprising a peroxide.

3. The composition according to claim 1 , wherein the polythiol compound is a primary thiol.

4. The composition according to claim 1 , wherein the polythiol compound has three or more thiol groups in one molecule thereof.

5. The composition according to claim 1 , wherein the polythiol compound has a molecular weight of from 200 to 3000.

6. The composition according to claim 1 , wherein the polythiol compound is selected from the group consisting of: a polythiol in which the portion other than the thiol groups is an aliphatic hydrocarbon; a polythiol obtainable by replacing halogen atoms of a halohydrin adduct of an alcohol with thiol groups; a polythiol that is a hydrogen sulfide reaction product of a polyepoxide compound; a thioglycolic acid ester obtainable by an ester-forming reaction between a polyhydric alcohol having from 2 to 6 hydroxyl groups in a molecule thereof and thioglycolic acid; a mercapto fatty acid ester obtainable by an ester-forming reaction between a polyhydric alcohol having from 2 to 6 hydroxyl groups in a molecule thereof and a mercapto fatty acid; a thiol isocyanurate compound obtainable by a reaction between an isocyanurate compound and a thiol; a thiol that includes a polysulfide group; a silicone modified with thiol groups; and silsesquioxane modified with thiol groups.

7. The composition according to claim 1 , wherein the compound having plural epoxy groups has an epoxy equivalent weight of 3000 or less.

8. The composition according to claim 1 , wherein the compound having plural epoxy groups is selected from the group consisting of an aromatic epoxide having a ring structure other than a glycidyl group, an alicyclic epoxide having a ring structure other than a glycidyl group, and modified products thereof.

9. The composition according to claim 1 , wherein the compound having plural epoxy groups is an aromatic epoxide having two or more aromatic rings.

10. The composition according to claim 1 , wherein the amine-based catalyst is a diamine.

11. The composition according to claim 1 , wherein the ratio (Ep/SH (epoxy groups/thiol groups)) of the total molar number (Ep) of epoxy groups contained in the compound having plural epoxy groups to the total molar number (SH) of thiol groups contained in the polythiol compound is from 0.50 to 1.80.

12. The composition according to claim 1 , further comprising a surface controller.

13. An adhesive comprising the composition according to claim 1 .

14. A layered body comprising, in this order, a rubber layer, an adhesion layer comprising the composition according to claim 1 , and another layer, wherein the rubber layer is in contact with the adhesion layer, and wherein the adhesion layer is in contact with the another layer.

15. The layered body according to claim 14 , wherein the rubber layer comprises vulcanized rubber.

16. The layered body according to claim 15 , wherein the rubber layer is not subjected to surface roughening treatment prior to being contacted with the adhesion layer.

Assignees

• Bridgestone Corp

Inventors

• Kitano Hajime

Classifications

• C08G59/66

  Mercaptans · CPC title

• C09J163/00

  Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins · CPC title

• B32B25/04

  comprising rubber as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a layer of a particular substance B32B9/043; next to a bituminous or tarry layer B32B11/044; next to a water setting substance layer B32B13/042; next to a metal layer B32B15/06; next to a glass layer B32B17/063; next to a layer formed of natural mineral fibres or particles B32B19/043; next to a wood layer B32B21/045; next to a cellulosic plastic layer B32B23/046)} · CPC title

• B32B2405/00

  Adhesive articles, e.g. adhesive tapes · CPC title

• B32B2319/00

  Synthetic rubber · CPC title