Polyethylene compositions and closures made from them

Patent metadata

Field	Value
Publication number	US-9637628-B2
Application number	US-201615152601-A
Country	US
Kind code	B2
Filing date	May 12, 2016
Priority date	Sep 19, 2011
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, stiffness, and environmental stress crack resistance. The polyethylene compositions are suitable for compression molding or injection molding applications and are particularly useful in the manufacture of caps and closures for bottles.

First claim

What is claimed is:

1. A closure, said closure comprising a bimodal polyethylene composition comprising:
(1) 10 to 70 weight percent of a first ethylene copolymer having a melt index 12, of less than 0.4 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density of from 0.920 to 0.955 g/cm 3 ; and
(2) 90 to 30 weight percent of a second ethylene copolymer having a melt index I 2 , of from 100 to 10,000 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density higher than the density of said first ethylene copolymer, but less than 0.965 g/cm 3 ;
wherein the density of said second ethylene copolymer is less than
0.037 g/cm 3 higher than the density of said first ethylene copolymer; the ratio (SCB1/SCB2) of the number of short chain branches per thousand carbon atoms in said first ethylene copolymer (SCB1) to the number of short chain branches per thousand carbon atoms in said second ethylene copolymer (SCB2) is greater than 1.0; and wherein said bimodal polyethylene composition has a molecular weight distribution M w /M n , of from 3 to 11; a density of at least 0.949 g/cm 3 ; and a melt index 12, of 0.5 to 2.0 g/10 min.

2. The closure of claim 1 wherein said first ethylene copolymer has a density of from 0.925 to 0.950 g/cm 3 .

3. The closure of claim 1 wherein said bimodal polyethylene composition has a density of from 0.951 to 0.957 g/cm 3 .

4. The closure of claim 1 wherein the density of said second ethylene copolymer is less than 0.035 g/cm 3 higher than the density of said first ethylene copolymer.

5. The closure of claim 1 wherein said bimodal polyethylene composition comprises: from 30 to 60 weight percent of said first ethylene copolymer; and from 70 to 40 weight percent of said second ethylene copolymer.

6. The closure of claim 1 wherein said bimodal polyethylene composition further comprises a nucleating agent.

7. The closure of claim 1 wherein said closure is made by compression molding or injection molding.

8. A process to prepare a polyethylene composition, said polyethylene composition comprising:
(1) 10 to 70 weight percent of a first ethylene copolymer having a melt index 12, of less than 0.4 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density of from 0.920 to 0.955 g/cm 3 ; and
(2) 90 to 30 weight percent of a second ethylene copolymer having a melt index 12, of from 100 to 10,000 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density higher than the density of said first ethylene copolymer, but less than 0.965 g/cm 3 ;
wherein the density of said second ethylene copolymer is less than 0.037 g/cm 3 higher than the density of said first ethylene copolymer; the ratio (SCB1/SCB2) of the number of short chain branches per thousand carbon atoms in said first ethylene copolymer (SCB1) to the number of short chain branches per thousand carbon atoms in said second ethylene copolymer (SCB2) is greater than 1.0; and wherein said bimodal polyethylene composition has a molecular weight distribution M w /M n , of from 3 to 11; a density of at least 0.949 g/cm 3 ; and a melt index 12, of from 0.4 to 5.0 g/10 min;
said process comprising contacting at least one single site polymerization catalyst system with ethylene and at least one alpha-olefin under solution polymerization conditions in at least two polymerization reactors.

9. The process of claim 8 wherein said at least two polymerization reactors comprise a first reactor and a second reactor configured in series.

10. The process of claim 8 wherein said at least two polymerization reactors comprise a first reactor and a second reactor configured in parallel.

11. The process of claim 9 wherein said at least one alpha-olefin is fed exclusively to said first reactor.

12. The closure of claim 1 wherein said bimodal polyethylene composition has a molecular weight distribution, M w /M n , of from 4.5 to 9.5.

13. The closure of claim 1 wherein said bimodal polyethylene composition has a M z of less than 400,000.

14. The closure of claim 1 wherein said first ethylene copolymer and said second ethylene copolymer have a molecular weight distribution M w /M n of less than 2.5.

Assignees

• Nova Chemicals International Sa
• Nova Chemicals (International S A

Inventors

• Wang Xiaochuan

Classifications

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• C08F4/65908

  in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+ · CPC title

• C08F4/6592

  containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring · CPC title

• C08L23/08

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title

• B29C45/0001

  characterised by the choice of material · CPC title