Polyethylene compositions having high dimensional stability and excellent processability for caps and closures

Patent metadata

Field	Value
Publication number	US-9074082-B2
Application number	US-201314098634-A
Country	US
Kind code	B2
Filing date	Dec 6, 2013
Priority date	Dec 14, 2012
Publication date	Jul 7, 2015
Grant date	Jul 7, 2015

Abstract

A dual reactor solution polymerization process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have high dimensional stability, excellent processability as well as good organoleptic properties and reasonable stress cracking resistance. The polyethylene compositions are suitable for compression molding or injection molding applications and are useful, for example, in the manufacture of caps and closures for bottles, and for example, in bottles containing non-pressurized liquids.

First claim

What is claimed is:

1. A closure for bottles, the closure comprising a polyethylene composition, the polyethylene composition comprising:
(1) about 10 to about 70 wt % of a first ethylene copolymer having a melt index I 2 , of from 0.1 to 10 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density of from 0.930 to 0.960 g/cm 3 ; and
(2) about 90 to about 30 wt % of a second ethylene copolymer having a melt index I 2 , of from 50 to 10,000 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density higher than the density of the first ethylene copolymer, but less than 0.966 g/cm 3 ;
wherein the density of the second ethylene copolymer is less than
0.037 g/cm 3 higher than the density of the first ethylene copolymer; the ratio (SCB1/SCB2) of the number of short chain branches per thousand carbon atoms in the first ethylene copolymer (SCB1) to the number of short chain branches per thousand carbon atoms in the second ethylene copolymer (SCB2) is greater than 1.0; and wherein the polyethylene composition has a molecular weight distribution M w /M n , of from 2 to 7; a density of at least 0.950 g/cm 3 ; a high load melt index I 21 , of from 150 to 400 g/10 min; a Z-average molecular weight M Z , of less than about 300,000; a melt flow ratio I 21 /I 2 , of from 22 to 50; a stress exponent of less than 1.40; and an ESCR Condition B (100% IGEPAL) of at least about 3.5 hrs.

2. The closure of claim 1 wherein the polyethylene composition has a TD/MD shrinkage ratio of from about 0.90 to about 1.15 when measured according to the Dimensional Stability Test (DST).

3. The closure of claim 1 wherein the polyethylene composition has an ESCR Condition B (100% IGEPAL) of from about 3.5 to about 15 hrs.

4. The closure of claim 1 wherein the polyethylene composition has a melt index I 2 , of greater than 5.0 to less than 20 g/10 min.

5. The closure of claim 1 wherein the first and second ethylene copolymers are made by polymerizing ethylene and an alpha olefin in the presence of a single site catalyst.

6. The closure of claim 1 wherein the density of the second ethylene copolymer is less than 0.030 g/cm 3 higher than the density of the first ethylene copolymer.

7. The closure of claim 1 wherein the first ethylene copolymer has a melt index I 2 , of from 0.1 to 3.0 g/10 min.

8. The closure of claim 1 wherein the second ethylene copolymer has a melt index I 2 , of from 100 to 5000 g/10 min.

9. The closure of claim 1 wherein the polyethylene composition has a melt index I 2 , of from 6 to 12 g/10 min.

10. The closure of claim 1 wherein the polyethylene composition has a bimodal molecular weight distribution as determined by gel permeation chromatography.

11. The closure of claim 1 wherein the ratio (SCB1/SCB2) of the number of short chain branches per thousand carbon atoms in the first ethylene copolymer (SCB1) to the number of short chain branches per thousand carbon atoms in the second ethylene copolymer (SCB2) is at least 1.5.

12. The closure of claim 1 wherein the polyethylene composition has a molecular weight distribution M w /M n , of from 3.5 to 6.

13. The closure of claim 1 wherein the first ethylene copolymer has a density of from 0.936 to 0.952 g/cm 3 .

14. The closure of claim 1 wherein the second ethylene copolymer has a density of less than 0.965 g/cm 3 .

15. The closure of claim 1 wherein the polyethylene composition has a density of from 0.952 to 0.960 g/cm 3 .

16. The closure of claim 1 wherein the polyethylene composition has no long chain branching.

17. The closure of claim 1 wherein the first and second ethylene copolymers have a M w /M n of less than 2.5.

18. The closure of claim 1 wherein the polyethylene composition has a composition distribution breadth index (CDBI(50)) of greater than about 65 wt %.

19. The closure of claim 1 wherein the first and second ethylene copolymers each have a composition distribution breadth index (CDBI(50)) of greater than about 65 wt %.

20. The closure of claim 1 wherein the polyethylene composition comprises:
from about 25 to about 60 wt % of the first ethylene copolymer; and
from about 75 to about 40 wt % of the second ethylene copolymer.

21. The closure of claim 1 wherein the polyethylene composition has a comonomer content of less than about 0.5 mol % as determined by 13 C NMR.

22. The closure of claim 1 wherein the polyethylene composition further comprises a nucleating agent.

23. The closure of claim 1 wherein the first and second ethylene copolymers are copolymers of ethylene and 1-octene.

24. The closure of claim 1 wherein the closure is made by compression molding or injection molding.

25. The closure of claim 1 wherein the closure is a screw cap.

26. The closure of claim 1 wherein the polyethylene composition is prepared by contacting ethylene and an alpha-olefin with a single site polymerization catalyst under solution polymerization conditions in a least two polymerization reactors.

27. A process for preparing a closure for bottles; wherein the process comprises at least one compression molding or injection molding step and wherein the closure comprises a polyethylene composition, the polyethylene composition comprising:
(1) about 10 to about 70 wt % of a first ethylene copolymer having a melt index I 2 , of from 0.1 to 10 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density of from 0.930 to 0.960 g/cm 3 ; and
(2) about 90 to about 30 wt % of a second ethylene copolymer having a melt index I 2 , of from 50 to 10,000 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density higher than the density of the first ethylene copolymer, but less than 0.966 g/cm 3 ;
wherein the density of the second ethylene copolymer is less than
0.037 g/cm 3 higher than the density of the first ethylene copolymer; the ratio (SCB1/SCB2) of the number of short chain branches per thousand carbon atoms in the first ethylene copolymer (SCB1) to the number of short chain branches per thousand carbon atoms in the second ethylene copolymer (SCB2) is greater than 1.0; and wherein the polyethylene composition has a molecular weight distribution M w /M n , of from 2 to 7; a density of at least 0.950 g/cm 3 ; a high load melt index I 21 , of from 150 to 400 g/10 min; a Z-average molecular weight M Z , of less than about 300,000; a melt flow ratio I 21 /I 2 , of from 22 to 50; a stress exponent of less than 1.40; and an ESCR Condition B (100% IGEPAL) of at least about 3.5 hrs.

28. A process to prepare a polyethylene composition, the polyethylene composition comprising:
(1) about 10 to about 70 wt % of a first ethylene copolymer having a melt index I 2 , of from 0.1 to 10 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density of from 0.930 to 0.960 g/cm 3 ; and
(2) about 90 to about 30 wt % of a second ethylene copolymer having a melt index I 2 , of from 50 to 10,000 g/10 min; a molecular weight distribution M w /M n , of less than 3.0; and a density higher than the density of the first ethylene copolymer, but less than 0.966 g/cm 3 ;
wherein the density of the second ethylene copolymer is less than
0.037 g/cm 3 higher than the density of the first ethylene copolymer; the ratio (SCB1/SCB2) of the number of short chain branches per thousand carbon atoms in the first ethylene co

Assignees

• Nova Chem Int Sa

Inventors

• Wang Xiaochuan
• Lacombe Yves
• Checknita Douglas Walter
• Rejman Mark
• Botros Matthew Zaki
• Anseeuw Renee Laurel

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2308/00

  Chemical blending or stepwise polymerisation process with the same catalyst · CPC title

• C08L2203/10

  used for bottles · CPC title

• C08F4/6592

  containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring · CPC title

• C08L23/0815 Primary

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title