Cobalt-containing compounds, their synthesis, and use in cobalt-containing film deposition
US-2015368282-A1 · Dec 24, 2015 · US
US9637395B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9637395-B2 |
| Application number | US-201314431116-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 26, 2013 |
| Priority date | Sep 28, 2012 |
| Publication date | May 2, 2017 |
| Grant date | May 2, 2017 |
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A tungsten precursor useful for forming tungsten-containing material on a substrate, e.g., in the manufacture of microelectronic devices. The tungsten precursor is devoid of fluorine content, and may be utilized in a solid delivery process or other vapor deposition technique, to form films such as elemental tungsten for metallization of integrated circuits, or tungsten nitride films or other tungsten compound films that are useful as base layers for subsequent elemental tungsten metallization.
Opening claim text (preview).
What is claimed is: 1. A method of forming a tungsten or a tungsten-containing film on a substrate comprising: providing a tungsten precursor, volatilizing the tungsten precursor to form a tungsten precursor vapor, and contacting the tungsten precursor vapor with a substrate under vapor deposition conditions to form the tungsten or tungsten-containing film on the substrate, wherein the tungsten precursor comprises a tungsten precursor of the formula 2. The method of claim 1 , wherein the tungsten precursor further comprises WCl 6 or WCl 4 . 3. The method of claim 1 , wherein the tungsten precursor is provided in a solid form. 4. The method of claim 3 , wherein the tungsten precursor is in particulate form. 5. The method of claim 3 , wherein the tungsten precursor is coated on an interior surface in the vessel. 6. The method of claim 1 , wherein the tungsten precursor is provided in a solvent medium. 7. The method of claim 6 , wherein the tungsten precursor is provided in a solution. 8. The method of claim 6 , wherein the tungsten precursor is provided in a suspension. 9. The method of claim 1 , wherein the substrate comprises a glue layer of a material compatible with the tungsten or tungsten-containing film.
mainly consisting of metals or alloys · CPC title
from metallo-organic compounds · CPC title
from metal carbonyl compounds · CPC title
Compounds containing tungsten, with or without oxygen or hydrogen, and containing two or more other elements · CPC title
Complex cyanides · CPC title
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